supercritical benson boiler
DESCRIPTION
Supercritical Benson BoilerTRANSCRIPT
LATEST EXPERIENCE OF COAL FIRED SUPERCRITICAL SLIDING PRESSURE
OPERATION BOILER AND APPLICATION FOR OVERSEAS UTILITY
Hajime Kimura Junichiro Matsuda
Kazuhito Sakai Babcock-Hitachi K.K.
ABSTRACT
In the fossil power utility field, a supercritical sliding pressure operation type unit has been developed
as the most advanced generating system combining higher efficiency, with low emissions technology.
Globally, this type of system has been the major trend for recent thermal plants. The use of low grade
coals i.e. low volatile, high ash content, for economic reasons provides additional challenges to meet
the international demands for improved efficiency and low emissions.
Babcock-Hitachi K.K. (BHK) has supplied a number of coal-fired boilers for thermal power plants in
Japan. The contribution to the improvement of power plant efficiency and the success of reduction in
NOx emission has been favourably received by all utilities.
Our most recent boiler experience relates to 1050MW power plant (Electric Power Development Co.
Japan, Tachibana-Wan Thermal Power Station No.2 boiler; 3000t/h steam output at Maximum
continuous rating) combining advanced steam conditions; pressure 25.0MPa, temperature
600oC/610oC and achieved the guaranteed boiler efficiency and strict requirements for NOx
emissions and unburned carbon in ash throughout the performance test. Subsequently, a 1000MW
power plant (The Tokyo Electric Power Co. Inc. Japan, Hitachi-Naka Thermal Power Station No.1
boiler, 2870t/h steam output at Maximum continuous rating) is now under commissioning, to provide
similar advanced steam conditions, pressure 25.4MPa and temperature 604oC/602oC. The boiler
was designed to meet challenging technical improvements and will be a benchmark for the boilers
with High Capacity Coal Fired Supercritical Sliding Pressure.
BHK have established a standardised design concept for coal fired supercritical sliding pressure
operation boilers for worldwide utilities based on our experience of designing and constructing
similar units over the previous decade.
This paper describes the principal characteristics of a coal fired supercritical sliding pressure
operation boiler and suitable design parameters to utilise various grades of coal, considering
economics and reliable operation in accordance with our experiences in Japan and in the export
maker for this technology.
1. Introduction
In the late 1950s, in Japan, the number of large capacity supercritical pressure oil fossil fired power
plants increased as an alternative to former smaller capacities sub critical pressure fossil fired plants
using domestic coal for fuel. In the early 1970s, energy dependence on imported oil reached
approximately 80%. Significant oil price increases and subsequently occurred twice, in 1973 and
1978, initiating a total review of domestic electricity economics triggered a need for fuel
diversification and energy saving. At that time, the demand for LNG increased as the most immediate
effective substitute fuel. After the 1980s, imported coal became the main energy resource to coping
with a stable supply and the mixing of electric power resources. With the increase of nuclear power
plants to accommodate base load operations, the associated variations of electric load demands mean
that the most new power units tended to be designed for cyclic duties.
Fig. 1 shows the general trends of utility boiler supplied by BHK in Japan. Various capacities of BHK
Benson Boilers have been supplied to cope with aforementioned utility power plants demands.
Subsequently, improvement in performance and technology has been the subject of BHK resource,
which will be incorporated into future project as they become available.
Fig. 1 General Trends of Utility Boilers Supplied by BHK in Japan
2. Improvement of Steam Conditions
Higher steam conditions were initiated through global environmental issues, i.e. to reduce greenhouse
gases, especially CO2 emissions and by improving plant efficiency. Fig. 2 shows a record of steam
parameter improvements established by BHK in Japan. The first ‘USC (Ultra Super Critical)’ plant
in Japan was built in 1989 employing gas fired boilers with steam conditions of
31MPa/566oC/566oC/566oC. At that time, the newly installed coal fired plants had a typical live
steam pressure of 24.1MPa, though steam temperatures increased gradually. The most advanced
steam condition currently in commercial operation in Japan is 25.0MPa/600oC/610oC, at the
Tachibana-Wan No. 2 boiler of Electric Power Development Co. Ltd. supplied by BHK in 2000.
This trend is being maintained with plants currently under commissioning, and with Hitachi-Naka No.
2 Unit of The Tokyo Electric Power Co. Inc., the steam parameters of which are 25.4MPa/
604oC/602oC.
Fig. 2 and 3 show typical improvements of steam condition and plant efficiency for the latest plant.
C/O Year
Goi 2u
Anegasaki 1u
Kashima 6uSodegaura 3u
Hirono 2u
FuelSteam Temp.
Boiler Type Super./ O.T(V.P.)Sub./ Super. / O.T.(C.P.)Sub. / N.C.538/566(538)538/538,(℃) 566/566 593/593,600/600566/566
Import CoalOilDomestic Coal Gas
Chiba4u
Takehara 3uChita 2-1u
Shinchi 1u
Hekinan 2u
Coal
Gas
Oil
Matsuura 1u
Nanao-Ohta 1u(USC)
Matsuura 2u(USC)
Higashi-Ohgishima 1u (USC)
LegendN.C. : Nutural CirculationO.T. : Once-Through TypeSub. : Sub. Critical PressureSuper.: Super-Critical PressureV.P. : Variable PressureC.P. : Constant PressureUSC : Ultra Super-Critical Plant
(USC)
(USC)
Ow ase- Mita 3u
Gobo 2u Nanko 2uNoshiro 1u
566/593
(USC)
1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 20050
200
400
600
800
1,000
Unit
capa
city
(MW
)
Haramachi 2uHitachi-Naka 1u
Tachibanawan 2u
Tachibanaw an 1u
C/O Year
Goi 2u
Anegasaki 1u
Kashima 6uSodegaura 3u
Hirono 2u
FuelSteam Temp.
Boiler Type Super./ O.T(V.P.)Sub./ Super. / O.T.(C.P.)Sub. / N.C.538/566(538)538/538,(℃) 566/566 593/593,600/600566/566
Import CoalOilDomestic Coal Gas
Chiba4u
Takehara 3uChita 2-1u
Shinchi 1u
Hekinan 2u
Coal
Gas
Oil
Matsuura 1u
Nanao-Ohta 1u(USC)
Matsuura 2u(USC)
Higashi-Ohgishima 1u (USC)
LegendN.C. : Nutural CirculationO.T. : Once-Through TypeSub. : Sub. Critical PressureSuper.: Super-Critical PressureV.P. : Variable PressureC.P. : Constant PressureUSC : Ultra Super-Critical Plant
(USC)
(USC)
Ow ase- Mita 3u
Gobo 2u Nanko 2uNoshiro 1u
566/593
(USC)
1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 20050
200
400
600
800
1,000
Unit
capa
city
(MW
)
Haramachi 2uHitachi-Naka 1u
Tachibanawan 2u
Tachibanaw an 1u
C/O Year
Goi 2u
Anegasaki 1u
Kashima 6uSodegaura 3u
Hirono 2u
FuelSteam Temp.
Boiler Type Super./ O.T(V.P.)Sub./ Super. / O.T.(C.P.)Sub. / N.C.538/566(538)538/538,(℃) 566/566 593/593,600/600566/566
Import CoalOilDomestic Coal Gas
Chiba4u
Takehara 3uChita 2-1u
Shinchi 1u
Hekinan 2u
Coal
Gas
Oil
Matsuura 1u
Nanao-Ohta 1u(USC)
Matsuura 2u(USC)
Higashi-Ohgishima 1u (USC)
LegendN.C. : Nutural CirculationO.T. : Once-Through TypeSub. : Sub. Critical PressureSuper.: Super-Critical PressureV.P. : Variable PressureC.P. : Constant PressureUSC : Ultra Super-Critical Plant
(USC)
(USC)
Ow ase- Mita 3u
Gobo 2u Nanko 2uNoshiro 1u
566/593
(USC)
1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 20050
200
400
600
800
1,000
Unit
capa
city
(MW
)
1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 20050
200
400
600
800
1,000
Unit
capa
city
(MW
)
Haramachi 2uHitachi-Naka 1u
Tachibanawan 2u
Tachibanaw an 1u
Fig. 2 Improvement of Steam Condition in Japan Fig. 3 Improvement of Plant Efficiency
3. Boiler Design Feature
3.1 Once-through Boiler (BENSON boiler for sliding pressure operation)
Benson type boilers have been developed and designed for variable sliding pressure operation plants
of high efficiency at all loads, which is suitable for both base and middle load operations. The start-up
system consists of a steam/water separator, a boiler circulation pump and associated piping, which
ensure a quick, smooth start-up and shutdown of the plant and easy operability. Table 1 summarises
the design future of the BENSON boiler in comparison with other boiler types.
A spirally wound water wall construction with ribbed tubing is applied to the furnace to enable have
sufficient mass flow velocity in the water wall tubes under variable loads to prevent departure from
nucleate boiling (DNB) and to achieve uniform water temperature distribution at the furnace outlet
when operating below critical pressure and without pseudo DNB when operating above critical
pressure (Fig. 4). All heated water walls are arranged with upward fluid flows.
Fig.4 Comparison of Mass Velocity in Furnace Wall Tube in Sliding Operation Mode
Tachibanawan No.2 (1050MW)
Haramachi No.2 (1000MW)
Matsuura No.2 (1000MW)
Nanao-Ohta No.1 (500MW)
Shinchi No.1 (1000MW)
Noshiro No.1 (600MW)
24.1MPa/538/566℃
24.1MPa/566/593℃
24.5MPa/600/600℃
24.1MPa/593/593℃
Hekinan No.2 (700MW)
1990 20001995 2005
Year
25.0MPa/600/610℃
1985 2010
Matsuura No.1 (1000MW)
40
41
42
43
44
16.6MPa 16.6MPa 24.1MPa 24.1MPa 24.1MPa 24.1MPa 24.5MPa
Plan
t effi
cien
cy (%
)
00 1,000 2,000 3,000 4,000 6,000
30 %MCR 50 %MCR 75%MCR MCR BMCR
Multi Ribbed TubeSmooth Tube
5,000
3,000
00 1,000 2,000 3,000 4,000 6,000
Multi Ribbed TubeSmooth
Mean Design Mass Velocity
5,000
3,0002.0
2.5
1.5
1.0
0.5
MPag
Mean Critical Mass velocity
Main Steam Flow (Mlb )
0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
Pressu
reat
Furnac
e Inlet
Pressureat SH Outle
t
X 103 kg/m2s
00 1,000 2,000 3,000 4,000 6,000
30 %MCR 50 %MCR 75%MCR MCR BMCR
Multi Ribbed TubeSmooth Tube
5,000
3,000
00 1,000 2,000 3,000 4,000 6,000
Multi Ribbed TubeSmooth
Mean Design Mass Velocity
5,000
3,0002.0
2.5
1.5
1.0
0.5
MPag
Mean Critical Mass velocity
Main Steam Flow (Mlb )
0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
Pressu
reat
Furnac
e Inlet
Pressureat SH Outle
t
X 103 kg/m2s
Ribbed Tube
Table 1 Boiler Type and Furnace Construction
FurnaceConstruction
Mixing Bottles
OperatingPressure
Sub-Critical(Constant or Sliding)
UP Boiler Benson BoilerNC Boiler
Dow
n Co
mer
DRUM
Steam FeedWater
Vertical TypeVertical Type(UP-UP Type)
Feed Water
Mix
ing
Bott
les
Spiral Type
Sub-Critical or Supercritical
(Constant Pressure)
Sub-Critical to Supercritical Region(Sliding Pressure)
Mixing Bottles arenot Necessary
Mixing Bottles are Necessary to Reduce Effect of Heat Flux
Unbalance
Mixing Bottles arenot Necessary By Spiral Type Water
Wall
Feed Water
ApplicableSteam PressureThrough FurnaceEnclosure TubesFluid StabilityTemperature UniformityMass Flow RateVariable Pressure ?
Max. Unit Capacityin Operation
Furnace EnclosureConstructionTube O/D (mm)
Start-up Time (min.)(Hot start)
Allowable Min. Load (%)
Load Change Rate
Subcritical Supercritical &Subcritical
Supercritical &Subcritical
Self BalanceBetter
Approx. 13%YES
BaseBase100%NO
Much BetterMuch Better
100%Wide Range
15 35 - 45 25 - 35 (OT Mode)15 (Circ. Mode)
Base Slightly Higher Higher
120 - 150with TB By-pass 250 120 - 150
with TB By-pass
57.0 - 63.5 22.5 - 31.8 31.8 - 38.1
800 MW 1,300 MW 1,000 MW
Start-upBypass System
Heat Lossduring Start Up
•Not installed•Operation of drain valves and vent valves is necessary
•Main valve is installed inthe main steam line
•Shift operation of start-up valves is necessary
•Operation of drain valves and vent valves is necessary
•Simplified start-up bypasssystem
•Shift operation of start-upvalves is not necessary
•Operation of drain valves and vent valves is necessary
•Continuous blowing(in case of bad water quality)
•Warming of start-up bypass system
•Warming of start-up bypass system•Heat recovery of circulated water by BCP
1SH 2SHCAGE
DRUM
W/WECO
HP-HTR BFP
DEAER
COND
TURBINE
1SH 2SH
CAGE
FLASHTANK
W/W
ECO
HP-HTR BFP
DEAER
COND
TURBINE
1SH 2SH
CAGE
W/W
ECO
HP-HTR BFP
DEAER
COND
3SH
TURBINE
BCP
DRAINTANK
SEPARATOR
Furnace Construction
Vertical Vertical Spiral
Notes NC:Natural Circulation OT:Once-Through Cric.:Circulation O/D:Outside Diameter
FurnaceConstruction
Mixing Bottles
OperatingPressure
Sub-Critical(Constant or Sliding)
UP Boiler Benson BoilerNC Boiler
Dow
n Co
mer
DRUM
Steam FeedWater
Dow
n Co
mer
DRUM
Steam FeedWater
Vertical TypeVertical Type(UP-UP Type)
Feed Water
Mix
ing
Bott
les
Feed Water
Mix
ing
Bott
les
Spiral Type
Sub-Critical or Supercritical
(Constant Pressure)
Sub-Critical to Supercritical Region(Sliding Pressure)
Mixing Bottles arenot Necessary
Mixing Bottles are Necessary to Reduce Effect of Heat Flux
Unbalance
Mixing Bottles arenot Necessary By Spiral Type Water
Wall
Feed WaterFeed Water
ApplicableSteam PressureThrough FurnaceEnclosure TubesFluid StabilityTemperature UniformityMass Flow RateVariable Pressure ?
Max. Unit Capacityin Operation
Furnace EnclosureConstructionTube O/D (mm)
Start-up Time (min.)(Hot start)
Allowable Min. Load (%)
Load Change Rate
Subcritical Supercritical &Subcritical
Supercritical &Subcritical
Self BalanceBetter
Approx. 13%YES
BaseBase100%NO
Much BetterMuch Better
100%Wide Range
15 35 - 45 25 - 35 (OT Mode)15 (Circ. Mode)
Base Slightly Higher Higher
120 - 150with TB By-pass 250 120 - 150
with TB By-pass
57.0 - 63.5 22.5 - 31.8 31.8 - 38.1
800 MW 1,300 MW 1,000 MW
Start-upBypass System
Heat Lossduring Start Up
•Not installed•Operation of drain valves and vent valves is necessary
•Main valve is installed inthe main steam line
•Shift operation of start-up valves is necessary
•Operation of drain valves and vent valves is necessary
•Simplified start-up bypasssystem
•Shift operation of start-upvalves is not necessary
•Operation of drain valves and vent valves is necessary
•Continuous blowing(in case of bad water quality)
•Warming of start-up bypass system
•Warming of start-up bypass system•Heat recovery of circulated water by BCP
1SH 2SHCAGE
DRUM
W/WECO
HP-HTR BFP
DEAER
COND
TURBINE
1SH 2SH
CAGE
FLASHTANK
W/W
ECO
HP-HTR BFP
DEAER
COND
TURBINE
1SH 2SH
CAGE
W/W
ECO
HP-HTR BFP
DEAER
COND
3SH
TURBINE
BCP
DRAINTANK
SEPARATOR
Furnace Construction
Vertical Vertical Spiral
Notes NC:Natural Circulation OT:Once-Through Cric.:Circulation O/D:Outside Diameter
800MW 1,300MW 1,050MW
3.2 Sliding Pressure Operation
The sliding pressure operation is a control system in which the main steam is controlled by sliding
pressure in proportion to the generation output. Steam quality at the turbine inlet can be changed at
constant volume flows while keeping the turbine governing valve open. Utilising sliding pressure, the
thermal efficiency of the steam turbine is improved at partial operating loads through decreasing
thermodynamic efficiency as follows, by comparison with constant pressure type operation:
(1) A smaller governing value loss enables improvement of high pressure turbine internal efficiency
(2) Decrease of feed water pump throughput
(3) Boiler reheat steam temperature can be maintained at higher levels because of higher
temperatures in high-pressure turbine exhaust steam.
Fig. 5 Feature of Coal Firing Supercritical Sliding Pressure Operation Boil
4. Pressure Parts Material
4.1 Materials for conventional super critical boilers
Table 2 lists the typical materials used for conventional super critical boilers with steam conditions of
24.1MPa/538oC/566oC, and Fig. 6 shows allowable stresses of the boiler materials. The selection of
appropriate and economical material for boiler pressure parts depends on a number of factors such as
SLIDING PRESSURE OPERATION
0 20 40 60 80 100-3
-2-1012345
0 20 40 60 80 10005
1015202530
Turbine Load (%)
Turbine Load (%)
Mai
n St
eam
Pre
ss. (
Mpa
)de
grad
atio
n
A
B
C
Improvement of Turbine Heat Rate dueto Sliding Pressure Operation
A slight governing valve loss enables improvementin the HP turbine internal efficiency : A
Decrease of feed water pump input : B
In comparison to constant pressure operations, a slidingtype enables much improvement in plant efficiencyunder partial load operations.
Rel
ativ
e co
mpa
rison
of
Hea
t Rat
e (%
)im
prov
emen
t
Unit output control method by sliding pressureis as follows.By the sliding pressure in proportion to the generatoroutput, steam quantity at turbine inlet can bechanged at a constant volume flow while keepinggoverning valve open.
Boiler reheat steam temperature can be maintainedhigh because of high temperature of HP turbineexhaust steam : C
Thermodynamic loss byfalling in pressure
SLIDING PRESSURE OPERATION
0 20 40 60 80 100-3
-2-1012345
0 20 40 60 80 10005
1015202530
Turbine Load (%)
Turbine Load (%)
Mai
n St
eam
Pre
ss. (
Mpa
)de
grad
atio
n
A
B
C
Improvement of Turbine Heat Rate dueto Sliding Pressure Operation
A slight governing valve loss enables improvementin the HP turbine internal efficiency : A
Decrease of feed water pump input : B
In comparison to constant pressure operations, a slidingtype enables much improvement in plant efficiencyunder partial load operations.
Rel
ativ
e co
mpa
rison
of
Hea
t Rat
e (%
)im
prov
emen
t
Unit output control method by sliding pressureis as follows.By the sliding pressure in proportion to the generatoroutput, steam quantity at turbine inlet can bechanged at a constant volume flow while keepinggoverning valve open.
SLIDING PRESSURE OPERATION
0 20 40 60 80 100-3
-2-1012345
0 20 40 60 80 10005
1015202530
Turbine Load (%)
Turbine Load (%)
Mai
n St
eam
Pre
ss. (
Mpa
)de
grad
atio
n
A
B
C
Improvement of Turbine Heat Rate dueto Sliding Pressure Operation
A slight governing valve loss enables improvementin the HP turbine internal efficiency : A
Decrease of feed water pump input : B
In comparison to constant pressure operations, a slidingtype enables much improvement in plant efficiencyunder partial load operations.
Rel
ativ
e co
mpa
rison
of
Hea
t Rat
e (%
)im
prov
emen
t
Unit output control method by sliding pressureis as follows.By the sliding pressure in proportion to the generatoroutput, steam quantity at turbine inlet can bechanged at a constant volume flow while keepinggoverning valve open.
Boiler reheat steam temperature can be maintainedhigh because of high temperature of HP turbineexhaust steam : C
Thermodynamic loss byfalling in pressure
strength properties, corrosion resistance, metallurgical stability and so on. It is therefore necessary to
select the optimum steel, considering all relevant factors at anticipated metal temperatures.
Steam conditions:24.1MPa/538C/566CPressure part Metal
Temperature Materials
Economizer 300~350C Carbon steel(STB510)
Furnace wall 350~500C0.5Mo(STBA13)0.5Cr0.5Mo(STBA20)1Cr0.5Mo(STBA22)
Superheater 450~590C
0.5Mo(STBA13)0.5Cr0.5Mo(STBA20)1Cr0.5Mo(STBA22)2.25Cr1Mo(STBA24)18Cr10NiTi(SUS321HTB)
Tubing
Reheater 350~610C
Carbon steel(STB340) 0.5Mo(STBA13)1Cr0.5Mo(STBA22)2.25Cr1Mo(STBA24)18Cr10NiTi(SUS321HTB)
Superheater headerMain steam pipe
550C2.25Cr1Mo(STPA24)
HeaderPiping
Reheater header Hot reheat pipe 570C 2.25Cr1Mo
(STPA24,SCMV4)
To establish adequate safety margins and service life, the characteristics of the steel must be given
due consideration during the design phase. Economy dictates that the lowest alloy with properties
suitable to the conditions should be used, stepping up from carbon steel to molybdenum steel and to
chromium-molybdenum steel as temperatures increase. For metal temperatures approaching about
550oC, lower-alloy ferritic steels up to and including 2.25% chromium are usually considered
adequate. Stainless steels are used at higher temperatures, where conditions require an increase in
resistance to corrosion and oxidation. However, stainless steel tubes usually have a higher carbon
content in order to increase creep rupture strength. In spite of the sensitisation due to the higher
carbon content during the usage in elevated temperature service, no stress corrosion cracking has
been experienced in stainless tubes. This may be related to the fact that the inside surface of tubes
contacts with dry steam.
The steam headers and pipes connecting the boiler and turbine are highly important components of
the power plant. Such piping must be carefully designed and erected to absorb thermal expansion and
vibratory stresses. Some stainless steel piping previously used in the power plant industry exhibited
300 400 500 600 7000
50
100
150
Temperature (C)
Allo
wab
le s
tres
s (M
Pa)
2.25Cr1Mo steel(STBA24)
Carbon steel(STB510)
Stainless steel(SUS321HTB)
0.5Mo steel(STBA13)
Table 2 Typical Materials for Conventional Super Critical Boiler
Fig. 6 Allowable Stresses of Boiler Materials
[A213TP321H]
[A209T1a]
[A213T22]
serious cracking problems caused by high thermal stresses due to higher thermal expansion
coefficients, as experienced under service conditions1). Therefore, such thick walled components
should be constructed using ferritic type steel pipes whose thermal expansion coefficient is relatively
low.
4.2 Materials for advanced super critical boiler
Fig. 7 shows a comparison of allowable stresses between conventional and advanced chromium
molybdenum steel pipe material. For high temperature headers and pipes associated with superheaters
and reheaters, STPA28 (Mod.9Cr1Mo) developed by Oak Ridge National Laboratories is suitable due
to its high temperature strength and excellent resistance to oxidation. Since the late 1980’s the steel
[STPA29] has been widely used for advanced power plants with the steam conditions of
approximately 25MPa/600oC/600oC in Japan and Europe. STPA29 (NF616) subsequently developed
by Nippon Steel and SUS410J3TP (HCM12A) developed by Sumitomo Metal have higher creep
strengths than that of STPA28 (T91), and these steels have been used for an advanced power plant
with steam conditions of 25MPa/600oC/610oC.
Fig. 7 Comparison of Allowable Stresses between Conventional and
Advanced CrMo Steel Pipes
Fig. 8 shows a comparison of allowable stresses between conventional and advanced stainless steel
tubes. Newly developed austenitic stainless steels such as SUS304J1HTB (SUPER304H) developed
by Sumitomo Metal and SUS310J2TB (NF709) developed by Nippon Steel have extremely high
creep rupture strength and the allowable stresses are twice as high value compared to SUS321HTB at
500 550 600 650 7000
50
100
150
Temperature (C)
Allo
wab
le s
tres
s (M
Pa)
STPA24(2.25%Cr)
STPA28(9%Cr)
STPA29(9%Cr)
SUS410J3TP(11%Cr)
STPA24J1(2.25%Cr)
[A335P91]
[A336P92]
[A335P122] [A335P23]
[A335P22]
650oC. These steels have been applied to high temperature superheater tubes. For severe corrosion
loads SUS310J3TB (HR3C) developed by Sumitomo Metal can be used because of its higher
chromium content.
Fig. 8 Comparison of Allowable Stresses between Conventional and Advanced Stainless Steel Tubes
Another issue that must be considered when selecting material for high temperature tubing is the
resistance to coal ash corrosion caused by coal sulphur content. Fig. 9 shows the effect of SO2
content on corrosion loss. At SO2 content of 0.1% or less (corresponding to about 1% sulphur in
coal) or less, corrosion loss is negligible for austenitic stainless steels containing 18% chromium2).
When the sulphur content of coal is around 5% (corresponding to about 0.5% SO2 in fuel gas), it will
be necessary to use a high-chromium austenitic stainless steels such as SUS310J1TB (HR3C).
Fig. 10 shows the effect of steam temperatures on steam oxide scale thickness. With increasing steam
temperatures, materials with an improved steam oxidation resistance require to be used for
superheater and reheater tubes. Spalled steam oxide scales have the potential to plug steam flows and
erode turbine components. The use of high chromium content or fine-grained stainless steel tubes is
effective in minimizing steam oxidation troubles. Fig. 10 also shows that internally shotblasted
stainless steel tube containing 18% chromium has similar resistance to steam oxidation as high
chromium stainless steel at temperatures up to 700oC2).
0
Allo
wab
le S
tress
SUS321HTB[A213TP321H](18Cr-10Ni-Ti)
SUS304J1HTB[A213UNS S30432](18Cr-9Ni-3Cu-Cb-N)
SUS310J1TB[A213TP310HCbN] (25Cr-20Ni-Cb-V)
SUS310J2TB[NF709] (20Cr-25Ni-1.5Mo)
18Cr-10Ni-Ti-Cb(Tempaloy A1)
550 600 650 700 750
50
100
150
1000 1100 1200 1300 1400
(MPa) (1000psi)20
15
10
5
(oF)
(oC)0
Allo
wab
le S
tress
SUS321HTB[A213TP321H](18Cr-10Ni-Ti)
SUS304J1HTB[A213UNS S30432](18Cr-9Ni-3Cu-Cb-N)
SUS310J1TB[A213TP310HCbN] (25Cr-20Ni-Cb-V)
SUS310J2TB[NF709] (20Cr-25Ni-1.5Mo)
18Cr-10Ni-Ti-Cb(Tempaloy A1)
550 600 650 700 750550 600 650 700 750
50
100
150
1000 1100 1200 1300 1400
(MPa) (1000psi)20
15
10
5
(oF)
(oC)
5. Combustion System
For environmental protection, the Hitachi NR2 burner has been applied to achieve low levels of
emission of NOx (oxides of nitrogen) and high levels of combustion efficiency. Following on from
the development of Hitachi’s NR burner in which an innovative concept of in-flame NOx reduction is
applied, BHK further developed the NR2 and NR3 burners progressively. These burners features a
stable and strengthened flame in terms of high-temperature reduction and achieved extremely low
levels of NOx emission and high levels of combustion efficiency 3). The Hitachi NR burner series is
based on an improved in flame NOx-reduction technology, which incorporates two innovative
devices: a pulverised-coal (PC) concentrator and a space creator. The configuration of the burners is
shown in Fig. 11.
Fig, 11 Configuration of NR Series Burners together with Improvement Trend
0.01 0.02 0.05 0.1 0.2 0.5 10
50
100
150
200
SO2 content in fuel gas (%)
Temperature:650C Time:20h Ash:1.5MNa2SO4-1.5MK2SO4-1MFe2O3
Corr
osio
n lo
ss (m
g/cm
)2
SUS310J2TB(20%Cr)
SUS310J1TB(25%Cr)
SUS304J1HTB(18%Cr)
Temperature (C)
Inne
r sc
ale
thic
knes
s (μ
m)
0
10
20
30
40
50
550 600 650 700 750 800
Time:1,000h
SUS304J1HTB(18%Cr)
SUS310J1TB(25%Cr)
SUS310J2TB(20%Cr)
ShotblastedSUS304J1HTB
(18%Cr)
Fig. 9 Effect of SO2 Content on Coal AshCorrosion Loss of Stainless Steel Tubes
Fig. 10 Effect of Temperature on Steam Oxide Scale of Stainless Steel Tubes
1980 1985 1990 1995 20000
100
200
300
400
NO
x (6
%O
2,pp
m)
300 ppm(100%)Coal propertyFuel Ratio:2.2Nitrogen:1.8%Two Stage Combustion
Dual Burner(Conventional)
NR2 BurnerNR Burner NR3 Burner
175 ppm(60%)150 ppm(50%) 125 ppm(40%)
NR2 BurnerDual Burner NR3 BurnerNR BurnerDelayed Combustion Rapid ignition(In Flame NOx Reduction)
Guide sleeveFlame StabilizingRing
Swirler
Space CreatorFlame StabilizingRing
P.C. Concentrator
Flame StabilizingRing
+Baffle Plate
Guide sleeve
P.C. ConcentratorSpin Vane
Air register
(100 ppm(33%))Coal propertyFuel Ratio:1.8Nitrogen:1.5%Two Stage Combustion
1980 1985 1990 1995 20000
100
200
300
400
NO
x (6
%O
2,pp
m)
300 ppm(100%)Coal propertyFuel Ratio:2.2Nitrogen:1.8%Two Stage Combustion
Dual Burner(Conventional)
NR2 BurnerNR Burner NR3 Burner
175 ppm(60%)150 ppm(50%) 125 ppm(40%)
NR2 BurnerDual Burner NR3 BurnerNR BurnerDelayed Combustion Rapid ignition(In Flame NOx Reduction)
Guide sleeveGuide sleeveFlame StabilizingRingFlame StabilizingRing
SwirlerSwirler
Space CreatorSpace CreatorFlame StabilizingRingFlame StabilizingRing
P.C. ConcentratorP.C. Concentrator
Flame StabilizingRing
+Baffle Plate
Guide sleeveGuide sleeve
P.C. ConcentratorP.C. ConcentratorSpin Vane
Air register
(100 ppm(33%))Coal propertyFuel Ratio:1.8Nitrogen:1.5%Two Stage Combustion
Coal propertyFuel Ratio:1.8Nitrogen:1.5%Two Stage Combustion
These burners enable a low level of excess air at only 15% at economiser’s outlet. This is important
when firing any various kinds of imported coals.
6. Latest Boiler Experience
The Tachibana-Wan Thermal Power Station No. 2 Unit (1,050MW) was completed for the Electric
Power Development Co. Ltd. (EPDC) in December of 2000. It applies advanced steam temperatures
of 25.0MPa and 600oC/ 610oC. The 3,000-t/h coal fired USC boiler for the generating plant was
supplied by BHK, and during the commissioning and test period, it was confirmed the boiler attained
all of its design performance specifications. To achieve these high-level steam parameters, newly
developed high-strength materials were utilised in the high-temperature areas, and the latest
combustion technology was used for environmental protection and also ensure a high level of
efficiency, operating reliability and plant availability.
Subsequently, a 1000MW power plant (The Tokyo Electric Power Co. Inc. Japan, Hitachi-Naka
Thermal Power Station No.1 boiler, 2870t/h steam output at Maximum continuous rating) is now
under commissioning, and will provide the advanced steam condition, pressure 25.4MPa and
temperatures 604oC/602oC.
6.1 Main Design Features of the Boilers
Fig. 12 is a cross-sectional schematic views of the Tachibana-Wan No.2 boiler and Hitachi-Naka
No.1 boiler. As both boilers are medium-load plants burning coals with a wide range of grades,
various factors were considered in designing the sliding-pressure boiler operation with advanced
steam parameters. All these advanced plants burn a wide variety of world traded coals from Australia,
Indonesia, South Africa etc. The main specification of the boilers is summarised in Table 3.
During the design engineering process of the Hitachi-Naka No.1 boiler, many special considerations
were implemented to ensure improvement of operability, maintainability and reliability together with
plant performance development. These efforts were synonymous with the activity for standardisation
of the BHK BENSON Boiler such that targets are considered with the demands of power plant users.
As more types of coals are imported from overseas, achievement of this standardization can be easily
transferred to meet world-wide operating requirements.
Hitachi-Naka No.1 Boiler Tachibana-Wan No.2 Boiler
Fig. 12 Cross-Sectional Schematic Views
Table 3 Main Specification of Boilers
Item Specification Hitachi-Naka No.1 Tachibana-Wan No.2 Boiler Type Babcock-Hitachi Supercritical Sliding Pressure
Operation Benson Boiler Main 2,870 t/h 3,000 t/h Steam Flow Reheat 2,407 t/h 2,490 t/h
Steam Pressure Main 25.4 MPa(g) 25.0 MPa(g) Main 604 oC 600 oCSteam Temperature Reheat 602 oC 610 oC
MCR
Economiser Inlet: Feedwater Temperature 286.9 oC 288 oC
Combustion System Pulverised Coal Fired Draught System Balanced Draught System
Main Water-Fuel Ratio Control and Stage AttemperationSteam Temperature Control System Reheat Parallel Gas Dampering and Spray Attemperation Main 30% ECR to MCR 35% ECR to MCR Steam Temperature Control Range Reheat 50% ECR to MCR 35% ECR to MCR
MCR: Maximum Continuous Rating, ECR: Economical Continuous Rating
The principal design features are as follows:
a) One of the best features of this Benson type boiler is the spirally wound water wall
No Installation of GRF
気水分離器
二次過熱器 三次過熱器
再熱器
一次過熱器
節炭器
脱硝装置
空気予熱器
ボイラ循環ポンプ微粉炭器
バンカ
AAポート
バーナ
一次通風機押込通風機
Steam Separator
Mills FDFBRP PAF
Secondary Superheater
Tertiary Superheater
Primary Supergeater
ハ ゙ー ナ
Reheater
AAホ ゚ー ト
EconomiserBunkers
SCR
AH
Mills FDFBRP
PAF
SecondarySuperheater
Tertiary Superheater
Evaporator
Secondary Reheater
Economiser
Multi-Cyclone GRF
AH
SCR
Final Superheater
Primary Reheater
Primary Superheater
Steam Separator
Horizontal Reheater Coils
Steam Cooled Roof
Bunkers
No Installation of GRF
気水分離器
二次過熱器 三次過熱器
再熱器
一次過熱器
節炭器
脱硝装置
空気予熱器
ボイラ循環ポンプ微粉炭器
バンカ
AAポート
バーナ
一次通風機押込通風機
Steam Separator
Mills FDFBRP PAF
Secondary Superheater
Tertiary Superheater
Primary Supergeater
ハ ゙ー ナ
Reheater
AAホ ゚ー ト
EconomiserBunkers
SCR
AH
Mills FDFBRP
PAF
SecondarySuperheater
Tertiary Superheater
Evaporator
Secondary Reheater
Economiser
Multi-Cyclone GRF
AH
SCR
Final Superheater
Primary Reheater
Primary Superheater
Steam Separator
Horizontal Reheater Coils
Steam Cooled Roof
Bunkers
気水分離器
二次過熱器 三次過熱器
再熱器
一次過熱器
節炭器
脱硝装置
空気予熱器
ボイラ循環ポンプ微粉炭器
バンカ
AAポート
バーナ
一次通風機押込通風機
Steam Separator
Mills FDFBRP PAF
Secondary Superheater
Tertiary Superheater
Primary Supergeater
ハ ゙ー ナ
Reheater
AAホ ゚ー ト
EconomiserBunkers
SCR
AH
Mills FDFBRP
PAF
SecondarySuperheater
Tertiary Superheater
Evaporator
Secondary Reheater
Economiser
Multi-Cyclone GRF
AH
SCR
Final Superheater
Primary Reheater
Primary Superheater
Steam Separator
Horizontal Reheater Coils
Steam Cooled Roof
Bunkers
arrangement at the lower furnace wall. In particular, Hitachi-Naka No.1 boiler equipped the
mixing manifolds at the outlet of spiral water wall to ensure a more uniform metal
temperature particularly at lower load conditions.
b) The boiler and furnace walls are suspended from overhead steel work such that the
progressive expansion of pressure parts is in a downward direction and there are no relative
expansion effects experienced between the furnace wall sections. The furnace walls compose
an all-welded membrane construction, which ensures complete gas tightness, and less in
erection time at site.
c) The combustion gas flows upward from the furnace area then turns into the pendant
convection pass section where pendant surfaces are located to efficiently absorb heat from
the hot gas. The gas then continues to flow down through the rear horizontal convection pass
area.
d) The primary superheaters and reheaters are located in a parallel and horizontal convection
pass arrangement together with the economizers. This also enables a sufficient amount of
reheater heating surface to be installed in this zone to permit allow quick responses for steam
temperature control by a gas biasing system. To improve this effect, all reheater-heating
surfaces are positioned in the horizontal convection.
e) A steam/water separator is used during the start-up and shutdown, and at loads lower than
minimum once-through load for smooth and reliable operation. In the case of Hitachi-Naka
No.1 boiler, the steam separator is positioned at the boiler front side. With this arrangement,
the all roof and cage walls are of steam-cooled surface and designed to mitigate the potential
of excessive temperature deviations within panels.
6.2 Achievements in the Commissioning
Hitachi-Naka No.1 boiler is currently at the commissioning stage [early 2003], however,
Tachibana-Wan No.2 boiler successfully entered commercial operation in December 2000. Stable and
reliable operation with the advanced steam conditions has been confirmed in both static and dynamic
modes. The main features of boiler performance have also been confirmed and are described below.
Boiler Performance
Fig. 13 shows the steam-water characteristics at each turbine load. The main steam and reheat steam
temperatures achieved anticipated values without causing any concerns. The backend gas temperature
and amounts of excess air and unburned carbon in ash (UBC) were significantly below the design
values. The boiler efficiency was found satisfactory across the load range.
Fig. 13 Steam and Water Temperature and Main Steam Pressure Characteristics
Combustion Performance
The results of combustion testing are summarised in Fig. 14. The A-type coal has a high fuel ratio
500 1,000 1,500 2,000 2,500 3,0000
10
20
30
200
300
400
500
600
Steam & Water Temperature (℃)
788M W525M W315M W 1050M W M C R
M ain Steam Flow (t/h)
Superheater O utlet
Superheater Intlet
Econom izer Intlet
Econom izer Outntlet
● : M easured (SH) , ■ : M easured (RH), : Anticipated
Reheater O utlet
Reheater Inlet
Main Steam Pressure
(MPa(g))
●
●
●
●
●
●●
●■
●
■ ■●
●
●
●
●●
●●
■
● ● ● ●■
■ ■ ■
(fixed carbon to volatile matter = 2:1) and nitrogen content, which means that the simultaneous
reduction of NOx and UBC is extremely difficult. In burning the A-type coal, the reduction in UBC
was confirmed, as were lower NOx emission levels. The same trend held when burning the B-type
coal, with its higher fuel ratio (=2.4) and nitrogen. Fig. 15 shows the flame during burning of B-type
coal at a load of 35% ECR (368MW). A very bright and stable flame was maintained at the tip of the
fuel nozzle at the low coal-firing load of 35% of ECR, along with stable boiler performance.
Fig. 14 Combustion Test Results at Rated Load Fig. 15 Flame of Hitachi NR2 Burner
7. Application to Overseas Projects
There are several coal fired generating plant projects proceeding overseas with more projects entering
the final contact stage. The current precedent project is the Genesee Power Generating Station Phase
3 boiler being provided for EPCOR in Canada (for 495MW Power Plant) and this project is now
entering the peak of construction stage [spring 2003].
For the Genesee Power Generating Station Phase 3 boiler, the same design of BHK reference boiler,
Nanao-Ohta No.1 boiler of Hokuriku Electric Power Co. (for 500MW Power Plant), was adopted.
This was due to not only the similar design steam condition required but also that Nanao-Ohta No.1
boiler has achieved excellent availability records. To be able to apply the same proven design
characteristics from the Nanao-Ohta No.1 boiler with modification was greatly appreciated by the
client.
0
5
120 160 200
NOx Emission (p p m, at 6%O2)
Unb
urne
d C
arbo
n in
Ash
(%
)
A coa l
B coa l
The reference plant, Nanao-Ohta No.1 boiler, is summarised in Fig. 16 and its specification is
described in Table 4. Fig, together with the specification of Genesee Power Generation Station Phase
3 boiler. Fig. 17 indicating which design considerations were applied from the design of Nanao-Ohta
No.1 boiler to Genesee Power Generating Station Phase 3 boiler.
Fig. 16 Main Future of Nanao-Ohta No.1 boiler
Table 4 Main Specifications of Nanao-Ohta No.1 and Genesee No. 3 Boiler
Item Specification Nanao-Ota No.1 Genesee No. 3 Boiler Type Babcock-Hitachi Supercritical Sliding Pressure
Operation Benson Boiler Main 1,510 t/h 1,450 t/h Steam Flow Reheat 1,158 t/h 1,192 t/h
Steam Pressure Main 25.0 MPa(g) 25.0 MPa(g) Main 570 oC 570 oCSteam Temperature Reheat 595 oC 568 oC
MCR
Economiser Inlet: Feedwater Temperature 289 oC 284 oC
Combustion System Pulverised Coal Fired Draught System Balanced Draught System
Main Water-Fuel Ratio Control and Stage AttemperationSteam Temperature Control System Reheat Parallel Gas Dampering and Spray Attemperation Main 28% MCR to MCR 35% ECR to MCR Steam Temperature Control Range Reheat 50% ECR to MCR 50% ECR to MCR
MCR: Maximum Continuous Rating, ECR: Economical Continuous Rating
Features
2. Imported variety coal combustion(Australia, Indonesia, South Africa, etc.)
···115 kinds of CoalGCV (AD kJ/kg) 20,660 - 33,240Inherent Moist. (%) 1.5 – 25.2Ash (%) 1.1 - 19.0Volatile Matter (%) 24.2 – 43.6Fixed Carbon (%) 35.6 – 61.8Fuel Ratio (-) 0.9 - 2.4Sulphur (%) 0.2 - 1.5Nitrogen (%) 0.7 – 1.9HGI (-) 40 - 89Ash Softening Temp (ºC) 1,100 - 1,500Ash Fusion Temp. (ºC) 1,180 - 1,600
1. Advanced steam condition 25MPa, 570ºC/595ºC
Features
2. Imported variety coal combustion(Australia, Indonesia, South Africa, etc.)
···115 kinds of CoalGCV (AD kJ/kg) 20,660 - 33,240Inherent Moist. (%) 1.5 – 25.2Ash (%) 1.1 - 19.0Volatile Matter (%) 24.2 – 43.6Fixed Carbon (%) 35.6 – 61.8Fuel Ratio (-) 0.9 - 2.4Sulphur (%) 0.2 - 1.5Nitrogen (%) 0.7 – 1.9HGI (-) 40 - 89Ash Softening Temp (ºC) 1,100 - 1,500Ash Fusion Temp. (ºC) 1,180 - 1,600
1. Advanced steam condition 25MPa, 570ºC/595ºC
Features
2. Imported variety coal combustion(Australia, Indonesia, South Africa, etc.)
···115 kinds of CoalGCV (AD kJ/kg) 20,660 - 33,240Inherent Moist. (%) 1.5 – 25.2Ash (%) 1.1 - 19.0Volatile Matter (%) 24.2 – 43.6Fixed Carbon (%) 35.6 – 61.8Fuel Ratio (-) 0.9 - 2.4Sulphur (%) 0.2 - 1.5Nitrogen (%) 0.7 – 1.9HGI (-) 40 - 89Ash Softening Temp (ºC) 1,100 - 1,500Ash Fusion Temp. (ºC) 1,180 - 1,600
1. Advanced steam condition 25MPa, 570ºC/595ºC
Fig. 17 Design Considerations Applied to Genesee Power Generating Station Phase 3 Boiler
Another overseas project, Council Bluffs Energy Centre No.3 Boiler for MidAmerican Energy
Company in USA (for 790MW Power Plant), is presently at the detailed engineering stage. Special
consideration will take into account the coal properties applying to Powder River Basin (PRB), which
can provide severe slagging in the boiler furnace. To cope with this undesirable coal property, the
furnace design is required to accommodate sufficiently large sectional area. The Standard design
established for Hitachi –Naka No.1 Boiler will therefore be fully applied to Council Bluffs Energy
Centre No.3 Boiler. Fig. 18 shows cross-sectional schematic views of the Council Bluffs Energy
Centre No.3 Boiler.
Fig. 18 Council Bluffs Energy Centre No.3 Boiler
Nanao-Ota500MW
Genesee #3
Width
Depth
Height
16.6 m
13.3 m
53.6 m
16.6 m
15.3 m
55.1 m
Volume 10240 m3 12070 m3
Plant Area 220 m2 254 m2
High Reliability 500mw Class Standard Design Philosophy Based On 7 Years Successful Operation Of Nanao Ota #2
Expanded Furnace Plane Area and Volume by +2m of depth to meet Genesee coal characteristics Reliable Design Philosophy confirmed from 7 years successful operation of Nanao-Ota boiler.
Expanded Furnace Plane Area and Volume by +2m of depth to meet Genesee coal characteristics Reliable Design Philosophy confirmed from 7 years successful operation of Nanao-Ota boiler.
Standard 500MW Class Boiler
CANADA EPCOR Genesee 3
Boiler circulation pump
Hitachi NR3burners
Tertiary superheater
Secondarysuperheater
Over air ports
Final superheater
Secondary reheater
Water separator
Primary reheater
Primary superheater
Economizer
Air heater
Forced draught fan
Bunkers
Nanao-Ota500MW
Genesee #3
Width
Depth
Height
16.6 m
13.3 m
53.6 m
16.6 m
15.3 m
55.1 m
Volume 10240 m3 12070 m3
Plant Area 220 m2 254 m2
High Reliability 500mw Class Standard Design Philosophy Based On 7 Years Successful Operation Of Nanao Ota #2
Expanded Furnace Plane Area and Volume by +2m of depth to meet Genesee coal characteristics Reliable Design Philosophy confirmed from 7 years successful operation of Nanao-Ota boiler.
Expanded Furnace Plane Area and Volume by +2m of depth to meet Genesee coal characteristics Reliable Design Philosophy confirmed from 7 years successful operation of Nanao-Ota boiler.
Standard 500MW Class Boiler
CANADA EPCOR Genesee 3
Boiler circulation pump
Hitachi NR3burners
Tertiary superheater
Secondarysuperheater
Over air ports
Final superheater
Secondary reheater
Water separator
Primary reheater
Primary superheater
Economizer
Air heater
Forced draught fan
Bunkers
Boiler circulation pump
Hitachi NR3burners
Tertiary superheater
Secondarysuperheater
Over air ports
Final superheater
Secondary reheater
Water separator
Primary reheater
Primary superheater
Economizer
Air heater
Forced draught fan
Bunkers
Hitachi NR3burners
Tertiary superheater
Secondarysuperheater
Over air ports
Final superheater
Secondary reheater
Water separator
Primary reheater
Primary superheater
Economizer
Air heater
Forced draught fan
Bunkers
B abcock-H itachi Supercritical Sliding PressureO peration B enson Boiler
M C R Steam Flow 2,531 t/hPlant Capacity 790 M W (Net)Steam C ondition 25.3 M Pa(g)/566℃/593℃
B oiler Type
8. Summary
Utility capacity and steam conditions have rapidly increased in Japan, to meet the demand for high
efficiency and low emission pollution in generating plant. To cope with these demands, the BHK
Benson technology has been and continues to be improved.
As evidence of this improvement, Tachibana-Wan No. 2 boiler with the advanced steam condition of
25.0MPa/ 600oC/ 610oC entered service in December of 2000. It was confirmed that this latest model
coal fired boiler, which was designed to operate satisfactory with a wide range of coal fuels and to
have improved countermeasures against environmental pollution, achieved all performance design
specifications during its commissioning and testing period.
Consequently, Hitachi-Naka No. 1 Boiler with advanced steam condition of 25.4MPa/ 604oC/ 602oC
is under construction. In this boiler unit, many special considerations have been implemented to
improve operability, maintainability and reliability together with performance development and these
innovative design features will be applied to future overseas projects.
BHK will continue to research and add improvements in performance and technology as their
contribution to global welfare in the form of better technologies for energy and environmental
systems.
References
1) T.C.McGough, J.V.Pigford, P.A.Lafferty, S.Tomasevich et al.: Selection and Fabrication of
Replacement Main Steam Piping for the Eddystone No. 1 Supercritical Pressure Unit, Welding
Journal, Vol.64, No.1 (1985) pp.29-36.
2) K.Sakai, S.Morita : The design of a 1000MW coal-fired boiler with the advanced steam
conditions of 593oC/593oC, International Conference on Advanced Steam Plant, IMechE
Conference Transaction 1997-2, (21-22 May 1997) pp.155-167.
3) S. Morita et al., “ Development of Extremely Low NOx Pulverized Coal Burners by Using the
Concept of ‘in-Flame’ NOx Reduction,” ICOPE-93, Vol. 2, pp. 325-330 (1993)