화학테러 피해 유형 및 대응방안...
TRANSCRIPT
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. 11. 12. 22.1 22.2 32.2.1 32.2.2 42.2.3 52.2.4 52.2.5 6. 81. 81.2 101.2.1 , 101.2.2 281.2.3 331.3 341.3.1 / 341.4 361.4.1 361.4.2 / 381.4.3 431.4.3 521.5 741.5.1 741.5.2 762. 812.1 812.1.1. 812.1.2. 842.1.3 992.1.4 EPA 1102.2 1222.2.1 122
2.2.2 1232.2.3 1272.3 1342.3.1 1342.3.2 1342.3.3 WMD 1452.3.4 GDK 1452.4 1482.4.1 1482.4.2 1482.5 , 1582.5.1 1582.5.2 1602.6 1612.7 1632.7.1 1632.7.2 1632.8 1703 1743.1 / 1743.1.1 1813.2 1853.2.1 / 1853.2.2 1893.2.3. 1903.3 1943.3.1 1943.3.2 1953.3.3 2003.3.4 2063.3.3. 2104.1 2394.1.1 2394.1.2 / 2424.2 2434.2.1 2434.2.2 245
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4.2.3 2454.2.4 2474.3 2474.3.1 2474.3.2 2524.3.3 2574.3.4 2584.4 2594.4.1 2594.4.2 (Risk Management) 2634.4.3 2684.5 2764.5.1 2764.5.2 2814.6 2844.6.1 (Emergency Operation Plan: EOP) 2844.6.2 () 2894.6.3 2924.6.4. 2934.6.5 2984.6.6 3004.7 3024.7.1 3024.7.2 3035. 3115.1 3115.1.1 3115.1.2. 3115.2 3135.2.1 3135.2.2 314 5.3 () 3165.3.1 3165.3.2 316. 3185.4 3185.4.1 318
5.4.2 3185.5 3205.5.1 3205.5.1.1 3205.5.1.2 3205.5.1.2 3205.5.1.3 3205.5.2 3215.6 3245.6.1 KM8 3245.6.2 KM9 3245.6.3 Water test kit 3255.6.4 Smart strip kit 3275.6.5 Classifier strip kit 3285.7 3305.7.1 CDS 3305.7.2 3305.8 3315.8.1 Chempro 100 3315.8.2 (APD-2000) 3355.8.3 (CAM2) 3375.8.4 HAPSITE 3405.9 3445.10 3535.11 3555.11.1 3555.11.2 3565.11.3 3565.12 358 362 371 1-1. 372 1-2. 379 1-3. PIC ( ) 381 1-4. ITF-25 383 1-5. EPCRA Section 302 (EHS) 385 1-6. CAA Section 112 392
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1-7. 38 396 1-8. 56 397 1-9. 399 1-10. (AEGL) 427 1-11. (ERPGs 2006) 441 2-1. Homeland Security Presidential Directive/HSPD-5 444 2-2. Homeland Security Presidential Directive/Hspd-7 449 3-1 (2004) 455 3-2 119 457 4-1 4593 EOP 4715 482 4-2 497. ( ) 503. ( ) 503 4-3 , 513 4-4 520 4-5 548 4-6 564 1. (56) 577 2. (19) 605 3. 624 4. GC/MS 625
1-1. CWC 12 1-2. 13 1-3. 14 1-4. (63) 15 1-5. 16 1-6. SCPOP 18 1-7. : 22 1-8 PIC ( , 38) 23 1-9. ITF-25 25 1-10. ITF-25 (98) 27 1-11. CAA Section 112 (195) 32 1-12. 38 33 1-13. 56 34 1-14. 35 1-15. 37. 1-16. 39 1-19. 40 1-18. 41 1-19. 41 1-20. 42 1-21. 43 1-22. 50 1-23. 51 1-24. 51 1-25. (8804) 52 1-26. 61 1-27 70 1-38. (10) 73 1-29. 74 1-30. 77 1-31. 78 2-1. 83 2-2. 84 2-3. 85 2-4. PDD 85
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2-5. NSPD HSPD 86 2-6. EO 87 2-7. NRP 88 2-8. NRP 90 2-9. NRP 91 2-10. NRP 15 97 2-11. 101 2-12. FEMA 103 2-13. NRP NCP 112 2-14. NRS 113 2-15. NRS 114 2-16. Office of Emergency Management 115 2-17. 118 2-18. 123 2-19. 124 2-20. (47) 2 126 2-21. 127 2-22. 131 2-23. 138 2-24. 144 2-25. 17 154 2-26. 159 2-27. 159 2-28. 167 2-29. 170 2-30. 172 3-1. () 179 3-2. 184 3-3. 188 3-4. 188 3-5. 190 3-6. (GB) (1) 191 3-7. (GB) (2) 191 3-8. (TGD)/VX 192 3-9. HD 192 3-10. 192 3-11. / 193
3-12. 195 3-13. 197 3-14. 199 3-15. 200 3-16. 205 4-1. 244 4-2. 253 4-3. 5 267 4-4. 270 4-5. 271 4-6 (2005 1 1 ) 276 4-7 (4 ) 277 4-8 278 4-9 (2004) 278 4-10 (2004) 279 4-11 309 4-11 () 310 5-1.
5-2.
5-3.
5-4.
5-5. KM8
5-6. KM9
5-7. Smart strip kit
5-8. Classifier strip kit
5-9. CDS
5-10.
5-11. Chempro 100
5-12. APD-2000
5-13. CAM2
5-14. HAPSITE
5-15. ()
5-16. ()
5-17.
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1-2. ITF-25 25 1-3. 29 1-4. EHS 31 1-5. CAA Section 112(r) 31 1-6. 53 1-7. 60 1-8. 60 1-9. 74 2-1. NIMS 93 2-2. 15 ESF 98 2-3. 99 2-4. NRP 100 2-5. FEMA 104 2-6. 107 2-7. 2007 ( $42,718,822,000) 107 2-8. WMD (DOD) 109 2-9. NIMS NRP 110 2-10. 112 2-11. Office of Emergency Management 115 2-12. 125 2-13. 125 2-14. 128 2-15. MAMAD MAMAK 136 2-16. 136 2-17. 137 2-18. 137 2-19. 139 2-20. ( ) 142 2-21. 144 2-22. 3 150 2-23. Multi-agency coordination group 155 2-24. 156 2-25. PROTECT 162 2-26. . 162 2-27. , , , 164
2-28. 168 2-29. 169 2-30. 169 2-31. 173 3-2 197 3-3 198 3-5. 202 3-6. 203 3-6. 210 3-7. 213 4-1. (1) 255 4-2. (2) 256 4-3. (3) 5-1
5-2
5-3
5-4
5-5
5-6 Smart strip kit
5-7 Classifier strip kit
5-8 Chempro 100
5-9 Chempro 100
5-10 Chempro 100
5-11 HAPSITE (Toluene)
5-12 IR
5-13
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ACGIH : American Conference of Governmental Industrial Hygienists
AEGLs : Acute Exposure Guideline levels
AG : Australia Group
AIHA : American Industrial Hygiene
BAT : Best available techniques
BEP : Best environmental practices
CAA : Clean Air Act
CWC : Chemical weapons convention
CWS : Chemical Warfare Service
DHS : Department of Homeland Security
DOT : Department of Transport
EHS : Exrecmely Hazardous Substance
EHS : Extremely Hazardous Substance
EPA : Environmental Protection Agency
EPA : Environmental Protection Agency
EPCRA : Emergency Planning and Community Right-to-know Act
ERPGs : Emergency Response Planning Guidelines
FEMA : Federal Emergency Management Agency
GP : general population limit
GPL : General Population Limit
HSE : Health and Safety Executive
IDLH : Immediately Dangerous to Life and Health
IFCS : Intergovernmental Forum on Chemical Safety
INC : Intergovernmental Negotiating Committee
ITF : International Task Force
LC : Lethal concentration
LC50 : Median Lethal Concentration
MIC : Methyl isocyanate
NAC : National Advisory Committee
NAC/AEGL : National Advisory Committee for acute exposure guideline level
NIOSH : National Institute for Occupational Safty and Health
NRC/AEGL : National research council
OPPT : Office of Pollution Prevention and Toxics
OSHA : Occupational Safety and Health Administration
PIC : Prior Informed Consent
POPs : Persistent Organic Pollutants
RMP : Risk Management Program
RTECS : Registry of Toxic Effects of Chemical Substances
SARA : Superfund Amendments and Reauthorization Act
SCPOP : Stockholm Convention on Persistent Organic Pollutants
STEL : Short Term Exposure Limit
TDA : Toluene Diamine
TDI : Toluene diisocyanate
TIC : Toxic Industrial Chemicals
TIM : Toxic Industrial Material
TSD : technical support document
WPL : Worker Population Limit
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Type of Chemical Agent Commercial Uses of the Chemical Ingredients
Mustard Agents
* lubricant additives * ballpoint pen ink
* manufacture of plastics, paper, and rubber
* chlorinating agents * photographic developing solutions *
textile dyes * pesticides * engineering plastics
* cosmetics * detergents * metal refining
* dye manufacture * pharmaceuticals * insecticides
* waxes and
polishes * toiletries * cement additives * synthetic resin
Tabun
* plasticizers * gasoline additives * hydraulic fluids
* insecticides * flame retardants * pharmaceuticals
* detergents * pesticides * missile fuels
* vulcanization of rubber * extraction of gold and silver from
ores
Sarin* flame retardants * gasoline additives * plasticizers
* paint solvents * ceramics * antiseptics
Soman
* lubricant additives * surfactants
* cleaning and disinfectant for brewery, dairy and other food
processing equipment
VX* organic synthesis * insecticide * lubricant oil additives *
pyrotechnics
1-3.
1.2.1.2 (AG : Australia Groups)
1984 UN
.
(Precursors)
1-4
.
- 15 -
ThiodiglycolPhosphorous oxychloride
Dimethyl methylphosphonateMethylphosphonyl difluoride (DF)Methylphosphonyl dichloride (DC)
Dimethyl phosphite (DMP)Phosphorus trichloride
Trimethyl phosphite (TMP)Thionyl chloride
3-Hydroxy-1-methylpiperidineN,N-Diisopropyl-(beta)-aminoethyl chlorideN,N-Diisopropyl-(beta)-aminoethane thiol
3-QuinuclidinolPotassium fluoride
2-ChloroethanolDimethylamine
Diethyl ethylphosphonateDiethyl N,N-dimethylosphoramidate
Diethyl phosphiteDimethylamine hydrochloride
Ethylphosphinyl dichlorideEthylphosphonyl dichlorideEthylphosphonyl difluoride
Hydrogen fluorideMethyl benzilate
Methylphosphinyl dichlorideN,N-Diisopropyl-(beta)
-amino-ethanolPinacolyl alcohol
O-Ethyl 2-diisopropylaminoethylmethylphosphonite (QL)
Triethyl phosphiteArsenic trichloride
Diethyl methylphosphoniteDimethyl ethylphosphonateEthylphosphinyl difluoride
Methylphosphinyl difluoride3-Quinuclidone
Phosphorus pentachloridePinacolone
Potassium cyanidePotassium bifluoride
Ammonium bifluorideSodium bifluorideSodium fluorideSodium cyanideTriethanolamine
Phosphorus pentasulphideDiisopropylamine
DiethylaminoethanolSodium sulphide
Sulphur monochlorideSulphur dichloride
Triethanolamine hydrochlorideN,N-Diisopropyl-2-aminoethyl
chloride hydrochlorideMethylphosphonic acid
Diethyl methylphosphonateN,N-Dimethylaminophosphoryl dichloride
Benzilic acid
Triisopropyl phosphiteEthyldiethanolamine
O,O-Diethyl phosphorothioateO,O-Diethyl phosphorodithioate
Sodium hexafluorosilicateMethylphosphonothioic dichloride
1-4. (63)
1985 Haydon 15
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1985 6 1
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Group) , ,
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2004 5 17 (POPs ; Persistent Organic Pollutants)
2001 3 3 .
12 , ,
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(Aldrine), (Chlorodane), DDT, (Dieldrine),
(Endrine), (Heptachlor), (Mirex), (Toxaphene),
HCBs(Hexachlorobenzene), PCBs, , (Furans) 12
1-6 .
, .
1972 UNEP
1987 (London Guideline)
(PIC) . 1992
,
21(Agenda 21) 19
. 21
(Intergovernmental Forum on Chemical Safety:
IFCS, 1994) (Interorganization
Programme on the Sound Management of Chemicals, 1995) ,
.
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Cas
Aldrin 309-00-2 :
: ,
Chlordane 57-74-9
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Dieldrin 60-57-1 :
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Endrin 72-20-8 :
:
Heptachlor 76-44-8 :
: ,
Hexachlorobenzene 118-74-1 :
: ,
Mirex 2385-85-5 :
:
Toxaphene 8001-35-2 :
:
Polychlorinated
Biphenyls(PCB)
:
: A 2
1-6. SCPOP
-
-
Cas
DDT
(1,1,1-trichloro-2,2-bis
(4-chlorophenyl)etha
ne)
50-29-3
: B 2
:
: B 2
:
-
Cas Polychloronated dibenzo-p-dioxin and
dibenzofurans(PCDD/PCDF)
Hexachlorobenzene (HCB)
Polychloronated biphenyls(PCB)
118-74-1 :
- 19 -
UNEP . 1997 UNEP
POPs
(Intergovernmental Negotiating Committee: INC) .
5 ,
2001 5 22 .
. POPs
POPs , ( D).
- (persistence)
POPs
. 2 ,
6 , (sediment) 6
.
- (bioaccumulation)
POPs .
POPs (low water solubility)
(high fat solubility)
.
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, km . POPs
(grasshopper effect)
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POPs . POPs
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-
- 20 -
, POPs,
(Aldrine), (Chlorodane), (Dieldrine), (Endrine),
(Heptachlor), (Mirex), (Toxaphene),
HCBs(Hexachlorobenzene) ( ) PCBs( )
9 , .
- DDT .
- POPs - (Action Plan)(4)
POPs,
, , PCB, HCB
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Best available techniques) (BEP: Best environmental
practices) . 5
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POPs (stockpile) POPs , ,
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- 21 -
1.2.1.4 (PIC ; Prior Informed Consent)
(Rotterdam Convention on the Prior Informed Consent Procedures for Certain
Hazardous Chemicals and Pesticides in International Trade) PIC(Prior
Informed Consent) . 19989 2004.2.24.
, 2005 2 83 .
2003 8 . PIC
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2,4,5-T
Methyl-parathion (emulsifiable concentrates(EC) with 19.5%, 40%, 50%, 60% active
ingredient and dusts containing 1.5%, 2%and 3% active ingredient)
AldrinMonocrotophos (Soluble liquid formulationof the substance that exceed 600 g active
ingredient/l)
Binapacryl
Parathion (all formulations - aerosols,dustable powder (DP), emulsifiable
concentrate (EC), granules (GR) andwettable powders (WP) - of this substance
are included, except capsule suspensions(CS)
CaptafolPhosphamidon (Soluble liquid formulationsof the substance that exceed 1000 g active
ingredient/l)
Chlordane DNOC and its salts
Chlordimeform(such as ammonium salt, potassium salt &
sodium salt)
ChlorobenzilateDustable powder formulations containing a
combination of
DDT Benomyl at or above 7%
Dieldrin Carbofuran at or above 10%
Dinoseb and dinoseb salt and Thiram at or above 15%
1,2-Dibromoethane (EDB) Crocidolite
Ethylene dichloride Polybrominated biphenyls (PBB)
Ethylene oxide Polychlorinated biphenyls (PCB)
Fluoroacetamide Polychlorinated terphenyls (PCT)
HCH (mixed isomers) Tris(2,3-dibromopropyl) phosphate
Heptachlor Actinolite
Hexachlorobenzene Anthophyllite
Lindane Amosite
Monocrotophos Tremolite
Mercury compounds, including inorganicmercury compounds, alkyl mercury
compounds and alkyloxyalkyl and arylmercury compounds
Toxaphene
PentachlorophenolMethamidophos (Soluble liquid formulationof the substance that exceed 600 g active
ingredient/l)
1-8 PIC ( , 38)
-
- 24 -
1.2.1.5 ITF-25 (International Task Force)
, , 3 (task force)
, (TIC ; Toxic
Industrial Chemicals)
1996 .
,
.
.
.
,
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.
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.
. (. )
ITF-25 17( 1-9) ,
6(arsine, chlorine, cyanogen chloride, hydrogen cyanide, hydrogen sulfide,
phosgene) 2 ,
. 11
HSE(Health and Safety Executive) DOT(Department of Transport)
.
,
(Steumpfle , 1996).
- 25 -
arsine
chlorine
cyanogen chloride
hydrogen cyanide
hydrogen sulfide
phosgene
allyl alcohol
ammonia
acrolein
bromine
formaldehyde
hydrogen chloride
hydrogen fluoride
hydrogen selenide
methyl isocyanate
oxygen difluoride
phosphine
1-9. ITF-25
ITF-25
cut-off 4
(1-2).
156
98
62581 High;
36 80 medium;< 36 Low
1,164
LCt50
-
- 26 -
,
,
.
RTECS(Registry of Toxic Effects of Chemical Substances)
, 1,164 . cut-off
20 ,
156 . cut-off
, 30
98
1-10 . hazard index
3
.
. High : ,
, (21).
. Medium : high" ,
(41)
. Low : (36)
- 27 -
formaldehydehydrogen cyanidecarbon disulfideethylene oxide
phosgenesulfur dioxide
boron trifluoridehydrogen chloridehydrogen fluoride
ammoniasulfuric acid
nitric acid, fumingphosphorus trichloride
fluorinechlorine
hydrogen sulfidetungsten hexafluoride
arsinehydrogen bromideboron trichloride
diboranemethyl hydrazinemethyl bromide
methyl mercaptanacetone cyanohydrin
trichloroacetyl chloridedimethyl sulfate
chloroacetonemethyl chloroformate
ethylene dibromideacrolein
allyl amineacrylonitrile
chloroacetonitrileallyl alcohol
n-butyl isocyanatemethanesulfonyl chloride
tert-octyl mercaptantrifluoroacetyl chloride
carbonyl sulfide1,2-dimethyl hydrazine
methyl isocyanatecarbon monoxide
diketenemethyl chlorosilane
allyl chlorocarbonatecrotonaldehydesulfur trioxide
titanium tetrachloride
phosphorus pentafluoridehydrogen selenide
silicon tetrafluorideselenium hexafluoridetellurium hexafluoride
chlorosulfonic acidsulfuryl chloride
phosphinestibine
phosphorus oxychloridenitrogen dioxideboron tribromide
iron pentacarbonylparathion
allyl isothiocyanatetetramethyl lead
hexachlorocyclopentadienetetraethyl lead
chloroacetyl chloridetoluene 2,6-diisocyanate
chloroacetaldehydetetraethyl pyrophosphateisopropyl chloroformaten-propyl chloroformate
ethylene iminecarbonyl fluoride
cyanogenethyl chloroformate
isobutyl chloroformatetoluene 2,4-diisocyanaten-butyl chloroformate
perchloromethyl mercaptanethyl phosphonous dichloride
tert-butyl isocyanateisopropyl isocyanate
sulfuryl fluorideethyl chlorothioformate
brominearsenic trichloridebromine trifluoride
bromine pentafluoridechlorine trifluoride
hydrogen iodidenitric oxide
chlorine pentafluoridebromine chloride
sec-butyl chloroformatediphenylmethane-4'-diisocyanateethyl phosphonothioic dichloride
1-10. ITF-25 (98)
-
- 28 -
1.2.2
2001 10 8 1979
(FEMA; Federal Emergency Management Agency) ,
9.11 (Department of Homeland Security; DHS)
FEMA
.
,
17 ( 4,000) 3 74
(45) (,
, 2005).
, (Environmental
Protection Agency; EPA) (Occupational Safety and
Health Administration; OSHA) ,
3 (,
, 2004). 3
(EPCRA ; Emergency
Planning and Community Right-to-know Act) (CAA ; Clean Air
Act) .
EPCRA 1984
1986 10 17
(SARA ; Superfund Amendments and Reauthorization Act)
. EPCRA
, ,
(Community Right-to- know)
. EPCRA (Emergency planning : Section 301-303),
(Emergency release notification : Section 304), ,
(Hazardous chemical storage reporting requirements : Section 311-312),
(Toxic chemical release inventory : Section 313) 4
.
- 29 -
(EPA)
(OSHA)
(EPA)
(OSHA)
(EPA)
(OSHA)
1-3.
EPCRA
,
(community officials)
. Section 303
,
(EHS; Exrecmely Hazardous Substance)
356(1-5) . EHS ,
cut-off . cut-off Inhalation
LC50 (Lethal concentration)0.5/(exposure time 8 ), Dermal
LD50(Lethal dose)50 /, Oral LD5025 / ,
.
,
. 2 cut-off ,
,
Inhalation LC502/(exposure time 8 ), Dermal LD50400
-
- 30 -
/, Oral LD50200 / ( 1-4.). 356
(TPQ) .
(EPA; Environmental Protection Agency) (CAA ; Clean
Air Act) (RMP; Risk Management Program)
. RMP
77 (
) 63 13
.
(ratio) SHI(Substance Hazard Index) 1,000
. EPA
, ,
() . EHS
, cut-off value .
0.5Hg
. NFPA(National Fire
Protection Association) Rating 4"
.
, (Sulfuric acid, phenol,
parathion, and nitrobenzene ) .
195( 1-5, 1-11).
- 31 -
RTECS (Registry of Toxic Effects of Chemical Substances ) (79,000)
12
Primary Listing Criteria
Inhalation LC50 0.5/L (exposure time 8), Dermal LD50 50 /, Oral LD50 25 /For mammals
Secondary Listing Criteria *
- Large volume production (13,600)- Inhalation LC50 2/L
(exposure time 8), - Dermal LD50 400 /, - Oral LD50 200 /For mammals
356
*Primary criteria.
1-4. EHS
7763
Criteria 1 [, EHS]
Inhalation LC50 0.5/L (exposure time 8), Dermal LD50 50 /, Oral LD50 25 /
Criteria 3 [Flammability Criteria]
- NFPA flammability rating 4 ( 22.8, 37.8 )
139
Criteria 2 []
0.5mmHg
1-5. CAA Section 112(r)
-
- 32 -
Hydrochloric acid (anhydrous), Methyl chloride[Methane, chloro-], Toluene
2,4-diisocyanate [Benzene, 2,4-diisocyanato-1-methyl-]1 Toluene
2,6-diisocyanate [Benzene, 1,3-diisocyanato-2-methyl-]1
Toluene diisocyanate, Ammonia (anhydrous)Ammonia (conc 20% or greater)
Bromine, Chlorine, Ethylene oxide [Oxirane], Hydrocyanic acid, Hydrogen fluoride/Hydrofluoric
acid, Hydrogen sulfideMethyl isocyanate, Phosgene[Carbonic
dichloride], Sulfur dioxide (anhydrous), Sulfur
trioxide, Vinyl chloride, Acrolein [2-Propenal], crylonitrile[2-Propenenitrile]
1,1-Dimethylhydrazine [Hydrazine, 1,1-dimethyl-], Acrylyl chloride, Allyl alcohol
[2-Propen-1-ol], Allylamine[2-Propen-1-amine], Arsenous trichloride, Arsine, Boron trichloride, Boron trifluoride, Boron trifluoride compound with
methyl ether (1:1) [Boron, trifluoro[oxybis[metane]]-, T-4-
Carbon disulfide, Chloroform [Methane, trichloro-], Chloromethyl ether [Methane,
oxybis[chloro-], Chloromethyl methyl ether [Methane, chloromethoxy-], Crotonaldehyde
[2-Butenal], Crotonaldehyde, (E)- [2-Butenal, (E)-], Cyclohexylamine, [Cyclohexanamine],
Diborane, Dimethyldichlorosilane [Silane, dichlorodimethyl-], Epichlorohydrin, [Oxirane,
(chloromethyl)-], Ethylenediamine [1,2-Ethanediamine], Ethyleneimine [Aziridine],
Fluorine, Formaldehyde(solution)Furan, Hydrazine, Hydrogen selenide Iron,
pentacarbonyl-, Isobutyronitrile[Propanenitrile, 2-methyl-]
Isopropyl chloroformate, Ethyl chloride, Ethyl nitrite, Ethylamine, Ethylene, Hydrogen,
Isobutane, Methane, Methyl ether,Methylamine, Propadiene [1,2-Propadiene],
Propane, Propylene, Propyne, Silane, Tetrafluoroethylene, Trifluorochloroethylene,
Trimethylamine, Vinyl acetylene, Vinyl fluoride, Vinyl methyl ether, Vinylidene, fluoride,
1-Chloropropylene, 1-Pentene, 2-Chloropropylene, 2-Methyl-1-butene,
2-Pentene, Acetaldehyde, Ethyl ether, Ethyl mercaptan, Isopentane, Isoprene, Isopropyl chloride, Isopropylamine, Methyl formate,
Pentane, Tetramethylsilane, Trichlorosilane, Vinyl ethyl ether, Vinylidene chloride,
1H-Tetrazole, 5-Nitrobenzotriazol, Ammonium nitrate, Ammonium perchlorate,
Ammonium picrate, Barium azide, Cyclotetramethylenetetranitramine,
Cyclotrimethylenetrinitramine,
Diazodinitrophenol, Diethyleneglycol dinitrateMethacrylonitrile [2-Propenenitrile, 2-methyl-], Methyl chloroformate, [Carbonochloridic acid, methylester], Methyl hydrazine [Hydrazine, methyl-], Methyl mercaptan [Methanethiol], Methyl thiocyanate [Thiocyanic acid, methyl
ester], Methyltrichlorosilane [Silane, trichloromethyl-], Nickel carbonyl
Nitric acid (conc 80% or greater), Nitric oxide, Peracetic acid [Ethaneperoxoic acid], Perchloromethylmercaptan, Phosphine,
Phosphorus oxychloride, Phosphorus trichloride, Piperidine, Propionitrile, [Propanenitrile], Propyl
chloroformate [Carbonochloridic acid, propylester], Propylene oxide [Oxirane,
methyl-], Propyleneimine [Aziridine, 2-methyl-], Sulfur tetrafluoride,
Tetramethyllead,[Plumbane, tetramethyl-], Tetranitromethane [Methane, tetranitro-],
Titanium tetrachloride, Trimethylchlorosilane [Silane, chlorotrimethyl-], Vinyl acetate
monomer [Acetic acid ethenyl ester], Chlorine dioxide, Cyanogen chloride, Hydrochloric acid,
Oleum, 1,3-Butadiene, 1,3-Pentadiene, 1-Butene, 2,2-Dimethylpropane, 2-Butene,
2-Butene-cis, 2-Butene-trans, 2-Methylpropene, 3-Methyl-1-butene,
Acetylene, Bromotrifluorethylene, Butane, Butene, Carbon oxysulfide, Chlorine monoxide,
Cyanogen [Ethanedinitrile], Cyclopropane, Dichlorosilane, Difluoroethane,
Dimethylamine, Ethane, Ethyl acetylene, Hexanitrostilbene, Hexolite, Lead azide,
Lead styphnate, Mannitol hexanitrate, Mercury fulminate, Nitro urea, Nitrocellulose
Nitroglycerin, Nitroguanidine or Picrite, Nitrostarch, Nitrotriazolone, Pentaerythrite
tetranitrate, Tetranitroaniline, Trinitroaniline or Picramide, Trinitroanisole, Trinitrobenzene,
Trinitrobenzenesulfonic acidTrinitrobenzoic acid, Trinitrochlorobenzene or
Picryl chloride, Trinitro-meta-cresol, Trinitronaphthalene, Trinitrophenetole,
Trinitrophenol or Picric acid, Trinitrophenylmethyl nitramine or Tetryl,
Trinitroresorcinol or Styphnic acid, Trinitrotoluene, Tritonal, Urea nitrate, Black powder, Bombs, photo-flash, Bombs, with
bursting charge, Detonator assemblies, Dinitroglycoluril or Dingu, Dinitroresorcinol,
Dipicryl sulfide, Flares, Fuze, Guanyl nitrosaminoguanylidene hydrazine, Hexotonal,
Octolite or Octol, Octonal, Pentolite, Torpedoes, Trinitrofluorenone, Dinitrophenol
Guanyl nitrosaminoguanylte trazene, Dipicrylamine or Hexyl,
1-11. CAA Section 112 (195)
- 33 -
1.2.3
.
( 33060-2580, 2001) 5
/ .
( 1).
,
546 .
,
, ,
, ,
38( 1-12)
, 56( 1-13) .
.
.
2-Chloroethanol, 2-Chloroethydiethyl ammonium chloride
AcroleinAmiton
AmmoniaAmmonium bifluorideArsenic trichloride
BromineChlorine
Chloropicrin Cyanogens chloride
Ethylene oxideHydrogen chlorideHydrogen cyanideHydrogen fluorideHydrogen selenideMechlorethamideMethyl bromideMethyl chloride
Methyl ethyl ketoneMethyl isocyanate
MustardParaquatPhosgenePhosphine
Phosphorus oxychloridePhosphorus pentachloridePhosphorus pentasulfidePhosphorus trichloride
Potassium cyanidePotassium fluoride
SarineSodium cyanideSodium fluoride
sulfur monochloridesulfuric acid
Thionyl cholrideToluene
1-12. 38
-
- 34 -
Formaldehyde
Mehtyl hydrazineFormic acid
MethanolBenzene
Methyl ChlorideMethyl amine
Hydrogen cyanideVinyl chloride
Carbon disulfideEthylene oxide
PhosgeneTrimethylaminePropylene oxide
Methyl ethyl ketoneMethyl vinyl ketone
Acrylic acidMethyl acrylateNitrobenzene
1-Methyl-4-nitrotolueneBenzyl chloride
AcroleinAllyl chlorideAcrylonitrile
Ethylene diamineAllyl alcohol
m-CresolToluene
Ethyl acetate
Sodium cyanideEthylenimine
Toluene-2,4-diisocyanate(TDI)Carbon monoxide, gas
Acryloyl chlorideZinc phosphide
Methyl ethyl ketone peroxideIsophorone diisocyanate
SodiumHydrochloric acid
(Hydrogen Chloride)Hydrogen fluoride, gas
AmmoniaSulfuric acidNitric acid
Phosphorus trichlorideFluorineChlorine
Hydrogen sulfideArsine
Chlorosulfonic acidPhosphine
Phosphorus oxychlorideChlorine dioxide
DiboranePhenol. liquidButylamine
Triethylamine
1-13. 56
1.3
1.3.1 /
,
.
- (CWC)
- (Australia Group)
- (SCPOP)
- (PIC)
- ITF-25
- (EPA) clean air acr EPCRA
(EHS)
- 35 -
-
38 56
1-14
1-9 .
/ /
CWC
, , ,, ,
13
42
AG
Thiodiglycol 63
ITF-25
LCt50100g.min/m3 : , : 30/
Formaldehyde 98
SCPOP
: 2 : 6 Aldrin 12
PIC
,
: 29 :
9
CAA
LCt500.5 mg/(8 ) Dermal LD5050mg/kg Oral LD5025 mg/kg 0.5 mmHg
NFPA 4( 22.8, 37.8 )
:77
: 63
EPCRA(EHS)
1 : LCt500.5mg/( 8 )
Dermal LD5050 mg/kgOral LD5025 mg/kg
2 : , 13,600/ LCt502 mg/(
8 )Dermal LD50400 mg/kg
Oral LD50200 mg/kg
: 356
38
,
2-Chloroethanol 38
56
,
Formaldehyde 56
1-14.
-
- 36 -
1.4
1.4.1
, , , , , ,
, , ,
.
, , ,
. ITF-25 , ,
, EPCRA , CAA
, , .
, , ,
.
.
,
, , ,
.
.
.
,
.
.
- , ,
- ,
-
- 37 -
.
.
, , , (, ),
.
.
,
, , .
, , , ,
.
.
1-15 .
, ,
-
,
-
(, )
- CWC
- ,
-
- , ,
-
-
- ,
1-15.
-
- 38 -
1.4.2 /
1.4.2.1
.
- .
. (
)
. , (
) .
.
-
.
. (
)
.
- .
1) Phosgene( 7)
2) Cyanogen chloride( 13.8)
3) Hydrogen cyanide( 25.6)
.
-
VX .
, .
. 24
.
- .
/ . ,
.
, .
VX Tabun Lewisite Sarin Hydrogencyanide Cyanogen chloride Phosgene Chlorine .
- 39 -
(Sarin) (HD)
15(10), 2(43) 12(10), 1(43)
2(10), 1(43) 10(10), 7(43)
. 1-16.
.
.
.
. ,
.
.
.
-
.
.
,
KM256 15
,
1 .
- 1
.
- .
, .
/
.
-
- 40 -
- .
,
.
.
- ,
. , (cyanogen chloride)
.
1.4.2.2 /
( 1-17)
( 1-18) (, )
( 1-19, 1-20) .
1-23 .
()
1000 BC : Arsenic smoke
600 BC
1914 :
1915
1919 : (DM), (DA) : (HD)
19231926 : Bromo methyl ethyl ketone,
(PS)
19351940
: , (CG) : (CN) : (DA) : (HD), (PD)
19371945
: (CN) : (DA) : (AC) : (L), (HD) : (CG)
19631967 : (CN) : (HD) : (CG)
19651975 : 2-chlorobenzalmalononitrile(CS)
19831988 : 2-chlorobenzalmalononitrile(CS) : (HD) : (GB), (GA)
/
19941995 : (GB)
1-19.
- 41 -
Acid 12 Pesticide 1
Arsenic 1 Poison gas 1
Cyanide 1 Sodium hydroxide 1
Hydrogen cyanide 1 unknown chemical 3
Unknown 11
: Center for Nonproliferation Studies "2002 WMD Terrorism Chronology"
1-18.
LCt50 [mg.min/m3], LD50 [g/kg]
[mmHg]
[]
Tabun(GA) LCt50 : 400 , LD50 : 0.014 0.037 (20) 11.5
Sarin(GB) LCt50 : 100, LD50 : 0.024 2.1 (20) 224(525)
Soman(GD) LCt50 : 50, LD50 : 0.5 0.4 (25)
VX LCt50 : 10, LD50 : 0.014 0.0007 (20) 26
AC LCt50 : 2,000, LD50 : 10 600 (20) 1
CK LCt50 : 11,000, LD50 : - 1,000 (20)
HD LCt50 : 1,500, LD50 : 10 0.072 (20) 23
HN-1 LCt50 : 1,500, LD50 : 10 0.255 (25)
HN-2 LCt50 : 3,000, LD50 : - 0.427 (25)
HN-3 LCt50 : 1,500, LD50 : - 0.011 (25)
L LCt50 : 1,300, LD50 : 5 0.39 (20)
CX LCt50 : 3,200, LD50 : - 11.2 (25)
CG LCt50 : 3,200, LD50 : -
CS LCt50 : 6,100, LD50 : -
DM LCt50 : 11,000, LD50 : -
BZ LCt50 : 200,000, LD50 : -
1-19.
-
- 42 -
AC Hydrogen cyanide
BA Bromacetone
BZ QNB, 3-quinuclidinyl benzilate
CA Bromobenzenecyanide
CG Phosgene
CK Cyanogen chloride
CL Chlorine
CN Chloroacetophenone
CNBCNB (benzen 45, carbon tetrachloride
45,chloroacetophenone 10)
CNC CNC(chloroacetophenone30,chloroform 70)
CNSCNS (chloroacetophenone23, chloroform
38.5 chloropicrin 38.5
CR Dibenz[1.4] oxazepine
CS Pepper gas
CS1 (CS powder 95, silica aerogel 5)
CS2 ( CS powder)
CSX (Trioctylphosphite 99g CS 1g)
CX Phosgene oxime
DA Diphenylchloroarsine
DC Diphenylcyanoarsine
DM Adamsite
DP Diphosgene
ED Ethyldichloroarsine
GA Tabun, Le-100
GB Sarin
GD Soman
GF CMPF, cyclosin
GV 2-dimethylaminoethyl-(dimethylanido)-phosphon ofluoridate
H Sulfur mustard
HD (distilled mustard)
HL MX(HD 37~50:L50~63% )
HN-1 -1
HN-2 -2
HN-3 -3, TO
(HL) ( ~)
HT HT (HD 60; T 40% )
L
MD Methyldichloroarsine
PD Phenyldichloroarsine
PS Chloropicrin, NC. G8
Q (Sesquimustard)
SA Arsenic trihydride
T Bis(2-Chloroethyl sulfide) monoxide
1-20.
- 43 -
GB-2
methylphosphonyldifluoride(DF)
isopropanol( DF isopropanol 72%
isopropylamine 28% OPA
)*
GB
CD-2 DF pinacolyl alcohol GD
VX-2O-ethyl O-2-diisoprprylaminoethylmethylphosphonite(QL)
VX
DC** methylphosphonic dichloride
DF methylphosphony klifluoride
OPA isopropanol isopropylamine
QL O-ethyl O-2-diisoprprylaminoethyl methylphosphonite* .
** DC DF .
1-21.
1-1720
,
.
.
1.4.3
1.4.3.1
.
1968 3
. 11
. PCB
-
- 44 -
, PCB ,
.
1kg 67 PCB , 5
, , , ,
, . 1 4,000 ,
1,068 .
100 70
. 1972 PCB
.
.
PCB
- -.
1983 .
.
. 1986 11
1
. , , 90
1,300 .
, , (11 5)
.
1330 .
,
4
(2 20t ). 400
.
.
.
.
400 SF( )
4 SF .
(SF 1) 750
SF .
- 45 -
, .
,
ECC
. 1989 3 22
.
.
(Union Carbide)
.
(MIC : Methyl isocyanate)
. 1984 12 3 8
( 36 ) 2 .
.
.
,
.
, , .
. 2 2,800 ,
1 20 .
2 ,
.
3 5 30 . 1998 4
1 9 .
.
3 820 , 200
. 1460
(1) , 1987
500 200 . 80,000
1500 2,407 10,000 .
30
, 10 .
-
- 46 -
.
1976 710 (Seveso) ICMESA
. 2kg
, trichlorophenol . ,
7
. 15
5 11 .
. 200 ,
. .
,
. 3 7 ,
18 ha .
1 10ha
. 2 5
.
.
.
, .
, , ,
.
,
. , EU
. EEC ,
,
.
.
1975
, , , ,
.
.
- 47 -
,
,
. .
.
100
.
.
.
-
1974 1,130ppm
, 1 1 10-240mg , , , ,
, . 6 ,
.
EPA WHO 0.001ppm 100 0.1ppm
.
-
1981 Georgia Pacific 3
, 0.11ppm
. 1 ( 1)
1990 12 10 . Georgia Pacific
9,000 (4 ),
, .
- Dee
1984 Deep (80% 2,4,6-
) 0.085ppm, 2ppm . ,
, , 95%
8 . 1-48 .
-
- 48 -
1.4.3.2
.
1991 3 14 22:00 06:00
30 .
.
, 1990 10 20 5
. 2
, 1 1990 10 20
. 1 9.5 1 1
8.4 , 24
.
,
. ,
(Diaphragm:,
) ,
(Dike:
)
.
. ,
.
.
,
.
, , , ,
, ,
.
3 16, 17
,
, , , ,
.
. TDI(Toluene diisocyanate)
1994 8 TDI
. TDI
- 49 -
, 1.4mm . TDI
.
HC1
.
, .
.
,
.
,
. 3 39
.
. TDA(Toluene Diamine)
1991 9 TDI TDA
(Tar + TDA) ()
. TDA
TDA Tar
. TDA
Overflow
.
.
TDA
.
TAR TDA TDA
. TDI 1.5km
TDA .
.
.
-
- 50 -
.
.
.
.
1-221.25 .
CAS No CAS No
1 57-11-4 Stearic acid 28 1304-28-5 Barium oxide
2 64-19-7 Acetic acid 29 1305-62-0 Calcium hydroxide
3 67-56-1 Methanol 30 1310-73-2 Sodium hydroxide
4 71-43-2 Benzene 31 1330-20-7 Xylene
5 74-82-8 Methane 32 1333-74-0 Hydrogen
6 74-85-1 Ethylene 33 1338-23-4Methylethyl ketone
peroxide
7 74-86-2 Acetylene 34 1746-01-6 Dioxine
8 75-01-4 Vinyl chloride 35 6484-52-2 Ammonium nitrate
9 75-28-5 Isobutane 36 7429-90-5 Aluminum
10 75-44-5 Phosgene 37 7440-23-5 Sodium
11 76-06-2 chloropicrin 38 7440-37-1 Argon
12 78-93-3 Methyl ethyl ketone 39 7446-09-5 Sulfur dioxide
13 79-01-6 Trichloroethylene 40 7631-90-5 Sodium bisulfite
14 95-80-7 2,4-Diaminotoluene 41 7647-01-0 Hydrochloric acid
15 98-95-3 Nitrobenzene 42 7664-41-7 Ammonia
16 100-21-0 Terephthalic acid 43 7664-93-9 Sulfuric acid
17 106-97-8 Butane 44 7697-37-2 Nitric acid
18 107-13-1 Acrylonitrile 45 7727-37-9 Nitrogen
19 107-44-8 Sarin 46 7758-94-3 Ferrous chloride
20 108-88-3 Toluene 47 7782-44-7 Oxygen
21 108-95-2 Phenol 48 7782-50-5 Chlorine
23 110-54-3 n-Hexane 49 7790-94-5 Chlorosulfonic acid
22 110-82-7 Cyclohexane 50 7803-49-8 Hydroxylamine
24 115-07-1 Propylene 51 8007-45-2 Coal tar
25 124-38-9 Carbon dioxide 52 9003-07-0 Polypropylene
26 143-33-9 Sodium cyanide 53 9009-54-5 Polyurethane
27 630-08-0 Carbon monoxide 54 68648-87-3 Alkyl benzene
1-22.
- 51 -
: 04. 5. 5 : : , 3
: 14- : 2- : 12
: 04. 4. 22 : :
: 3- : 3
: 00. 11. 2 : :
: 58- : 6- : 52
: 93. 2. 25 : () :
: 4- : 1- : 3
: 94. 9. 8 : () : TDI
, TDI,
: 57- : 3- : 54
: 00. 8. 24 : () MEK-PO : MEK-PO
: 25- : 6- : 19
: 03. 10. 3 : () : HP
()
: 7- : 1- : 6
1-23.
PCB
: 68. 3. : : PCB
PCB
1,068 70
Flixborough
: 74. 6. 1 : Flixborough :
28
: 76. 7. 19 : : TOP()
TOBD(Tetra Chloro Benzo Dioxine)
34%
LPG
: 79 : : LPG BLEVE
:3,150(650, :
2,500)
MIC
: 86.12 .2 : :
(Methylisocyanate)
:202,800( :2,800), :
20)
: 86. 11. 1 :
(90) 1,300
:400
: 89. 10. 23 : :
:153( : 23,
: 130)
1-24.
-
- 52 -
(, )
1 16 48
2 11 8
3 9 8
4 6 55 5 5
6 5 4
7 4 3
8 3 , LPG 2 8 59 8 83
1-25. (8804)
1.4.3
1.4.3.1
.
.
, ,
.
.
50 %
GPL(general population limit) ( 1-6).
- 53 -
1-6.
LC50, EC50, IDLH,
AEGL, ERPG, STEL, WPL, GPL
.
. AEGLs(Acute Exposure Guideline levels)
(EPA)
1988 (OPPT : Office of Pollution
Prevention and Toxics) . 1996
OPPT AEGL
(NAC : National Advisory Committee) NAC
,
(EHS : Extremely Hazardous Substance) AEGLs .
AEGLs
10, 30, 1, 4, 8 5
,
. AEGLs ,
AEGLs AEGL-1,
-
- 54 -
AEGL-2, AEGL-3 3 (1-11)
.
- AEGL-1 :
,
(ppm
or mg/m3).
- AEGL-2 :
(ppm or
mg/m3).
- AEGL-3 :
(ppm or mg/m3).
AEGL
. 4 AEGL
AEGL draft AEGLs,
proposed AEGLs, interim AEGLs, final AEGLs .
.
- Draft AEGLs : ,
technical support
document(TSD) TSD
AEGL
- Proposed AEGLs : AEGL AEGL
(NAC/AEGL : National Advisory Committee for acute
exposure guideline level) 2/3
AEGL . proposed AEGL
30 Federal Resister
. Proposed AEGL AEGL
AEGL
2/3
.
- Interim AEGLs : AEGL
AEGL . interim AEGL
- 55 -
TSD NRC/AEGL(National research
council)
NRC/AEGL
NAC/AEGL
.
- Final AEGLs : NRC/AEGL
AEGL .
. ERPGs(Emergency Response Planning Guidelines)
ERPGs AIHA(American Industrial Hygiene) Emergency Response Planning
Committee
, ERPG-1, ERPG-2, ERPG-3
().
- ERPG -1 : ,
.
- ERPG -2 :
.
- ERPG -3 :
.
. STEL(Short Term Exposure Limit)
ACGIH(American Conference of Governmental Industrial Hygienists)
-15 4 -
,
,
. STEL ()
. STEL
. 8
STEL .
. LC50(Median Lethal Concentration)
50% .
. EC50(Median Effective Concentration)
50 % .
. IDLH(Immediately Dangerous to Life and Health)
-
- 56 -
NIOSH(National Institute for Occupational Safty and Health)
, 30
.
. WPL(Worker Population Limit)
8 .
. GPL(General Population Limit)
24,
.
,
1.4 AEGL-1 .
AEGL-1
.
. ,
,
,
30
30 AEGL-1
.
,
4
4 AEGL-1
.
.
1.4
.
AEGL-1
,
- 57 -
,
30 4 AEGL-1
, (, ,
) AEGL-1 30 4
.
.
,
.
.
1.4.3.1
.
.
, ,
, , .
, ,
,
, ,
.
.
,
, , .
, ,
.
-
- 58 -
,
.
.
.
.
-
.
-
(, )
.
- CWC 1 2, 3
LCt500.5 mg/(
8 ), Dermal LD5050 mg/kg, Oral LD5025 mg/kg
, 0.5 mmHg
CWC 1-1
. 2, 3 LCt50
0.5 mg/( 8 ), Dermal LD5050 mg/kg, Oral LD5025
mg/kg , 0.5 mmHg
.
- ITF-25 . medium
LCt500.5 mg/( 8 ), Dermal LD5050 mg/kg,
Oral LD5025 mg/kg , 0.5 mmHg
LCt50100g.min/m3 ,
.
LOW ,
.
- 59 -
- CAA , ,
EPCRA EHS 1 .
LCt500.5 mg/( 8 ), Dermal LD50
50 mg/kg Oral LD5025 mg/kg , 0.5
mmHg
. EHS 2 LCt502 mg/(
8 ), Dermal LD50400 mg/kg Oral LD50200 mg/kg EHS
1 48
.
- (38, 56) LCt50100g
min/m3, LCt500.5 mg/( 8 ), Dermal LD5050 mg/kg,
Oral LD5025 mg/kg , 0.5 mmHg
CWC .
,
,
.
CWC
.
- SCPOP, PIC LCt50100gmin/m3, LCt500.5 mg/
( 8 ), Dermal LD5050 mg/kg, Oral LD5025 mg/kg
, 0.5 mmHg CWC
.
.
CWC
.
-
- 60 -
1-7.
1-8.
- 61 -
No. CAS No nameITF-25 EHS CAA CWC AG SCPOP PIC
98 358 198 128 63 10 39 38 56 54
1 75-44-5 Carbonyl dichloride(Phosgene, CG) 0 0 0 0 0 0 0
2 10025-87-3 Phosphorus oxychloride 0 0 0 0 0 0 0
3 74-90-8 Hydrogen cyanide(AC) 0 0 0 0 0 0
4 75-21-8 Ethylene oxide 0 0 0 0 0 0
5 7664-39-3 Hydrogen fluoride, gas 0 0 0 0 0 0
6 7719-12-02 Phosphorus trichloride 0 0 0 0 0 0
7 7784-34-1 Arsenic trichloride 0 0 0 0 0 0
8 107-02-8 Acrolein 0 0 0 0 0
9 107-13-1 Acrylonitrile 0 0 0 0 0
10 143-33-9 Sodium cyanide 0 0 0 0 0
11 7647-01-0 Hydrochloric acid(Hydrogen Chloride) 0 0 0 0 0
12 7664-41-7 Ammonia 0 0 0 0 0
13 7664-93-9 Sulfuric acid 0 0 0 0 0
14 7782-50-5 Chlorine(CL) 0 0 0 0 0
15 7803-51-2 Phosphine 0 0 0 0 0
16 50-00-0 Formaldehyde 0 0 0 0
17 60-34-4 Mehtyl hydrazine 0 0 0 0
18 75-15-0 Carbon disulfide 0 0 0 0
19 107-18-6 Allyl alcohol 0 0 0 0
20 151-56-4 Ethylenimine 0 0 0 0
1-26.
.
1-26 .
-
- 62 -
21 584-84-9 Toluene-2,4-diisocyanate(TDI) 0 0 0 0
22 624-83-9 Methyl isocyanate 0 0 0 0
23 7446-09-05 Sulfur dioxide 0 0 0 0
24 7697-37-2 Nitric acid 0 0 0 0
25 7783-06-04 Hydrogen sulfide 0 0 0 0
26 7783-07-05 Hydrogen selenide 0 0 0 0
27 7784-42-1 Arsine(SA) 0 0 0 0
28 10026-13-8 Phosphorus pentachloride 0 0 0 0
29 19287-45-7 Diborane(VM) 0 0 0 0
30 107-44-8 O-Isopropyl methylphosphonofiuoridate(GB) 0 0 0
31 51-75-2 Bis(2-chloroethyl)methylamine(HN2) 0 0 0
32 74-87-3 Methyl Chloride 0 0 0
33 74-93-1 Methylmercaptane 0 0 0
34 1975-01-04 Vinyl chloride 0 0 0
35 75-56-9 Propylene oxide 0 0 0
36 75-74-1 Plumbane, tetramethyl- 0 0 0
37 78-53-5Amiton: O,O-Diethyl
S-[2-(diethylamino)ethyl]phosphorothiolate(VG) 0 0 0
38 79-22-1 Methyl chloroformate 0 0 0
39 1991-08-07 Toluene-2,6-diisocyanate 0 0 0
40 98-95-3 Nitrobenzene 0 0 0
41 107-07-3 2-Chloroethanol 0 0 0
42 107-11-9 2-Propen-1-amine 0 0 0
43 107-15-3 Ethylene diamine 0 0 0
44 108-23-6 Carbonochloridic acid,-methylethyl ester 0 0 0
45 108-95-2 Phenol. liquid 0 0 0
46 109-61-5 Propyl chloroformate 0 0 0
47 151-50-8 Potassium cyanide 0 0 0
48 309-00-2 Aldrin 0 0 0
- 63 -
49 505-60-2 Mustard gas: Bis(2-chloroethyl)sulfide(HD) 0 0 0
50 506-77-4 Cyanogen chloride(CK) 0 0 0
51 594-42-3 Trichloromethanesulfenyl chloride 0 0 0
52 630-08-0 Carbon monoxide, gas 0 0 0
53 676-97-1 Methylphosphonyl dichloride(DC) 0 0 0
54 814-68-6 Acryloyl chloride 0 0 0
55 1498-40-4 Ethylphosphinyl dichloride 0 0 0
56 4170-30-3 2-Butenal 0 0 0
57 7446-11-09 Sulfur trioxide 0 0 0
58 7550-45-0 Titanium chloride (TiCl4) (T-4)- 0 0 0
59 7637-07-02 Borane, trifluoro- 0 0 0
60 7719-09-07 Thionyl chloride 0 0 0
61 7726-95-6 Bromine 0 0 0
62 7782-41-4 Fluorine 0 0 0
63 7790-94-5 Chlorosulfonic acid 0 0 0
64 8001-35-2 Camphechlor 0 0 0
65 10025-67-9 Sulfur monochloride 0 0 0
66 10102-43-9 Nitric oxide 0 0 0
67 10294-34-5 Borane, trichloro- 0 0 0
68 67-66-3 Chloroform 0 0
69 72-20-8 Endrin 0 0
70 74-83-9 Bromomethane 0 0
71 75-55-8 Aziridine, 2-methyl 0 0
72 75-77-4 Trimethylchlorosilane 0 0
73 75-78-5 Dimethyldichlorosilane 0 0
74 75-79-6 Silane, trichloromethyl- 0 0
75 75-86-5 Acetone cyanohydrin| 0 0
76 1976-02-08 Trichloroacetyl chloride 0 0
-
- 64 -
77 77-47-4 Hexachlorocyclopentadiene 0 0
78 77-78-1 Dimethyl sulfate 0 0
79 77-81-6 Ethyl N-dimethylphosphoramidocyanidate(GA) 0 0
80 78-00-2 Tetraethyl lead 0 0
81 78-38-6 Diethyl ethylphosphonate 0 0
82 78-82-0 Isobutyronitrile 0 0
83 79-21-0 Ethaneperoxoic acid 0 0
84 96-79-7 N,N-Diisopropyl-(beta)-aminoethyl chloride 0 0
85 96-80-0 N,N-Diisopropyl-(beta)-amino-ethanol 0 0
86 100-44-7 Benzyl chloride 0 0
87 102-71-6 Triethanolamine 0 0
88 106-89-8 Epichlorohydrin 0 0
89 106-93-4 ethylene dibromide 0 0
90 107-12-0 Propionitrile 0 0
91 107-30-2 Methane, chloromethoxy- 0 0
92 108-05-4 Acetic acid ethenyl ester 0 0
93 108-91-8 Cyclohexylamine 0 0
94 110-00-9 Furan 0 0
95 110-89-4 Piperidine 0 0
96 121-45-9 Trimethyl phosphite 0 0
97 122-52-1 Triethyl phosphite 0 0
98 123-73-9 2-Butenal, (e)- 0 0
99 126-98-7 2 -Propenenitrile, 2-methyl- 0 0
100 139-87-7 Ethyldiethanolamine 0 0
101 298-00-0 Methyl parathion 0 0
102 302-01-2 Hydrazine 0 0
103 353-42-4 Boron, trifluoro[oxybis[methane]]-, (T-4)- 0 0
104 430-78-4 Ethylphosphinyl difluoride 0 0
- 65 -
105 460-19-5 cyanogen 0 0
106 463-58-1 carbonyl sulfide 0 0
107 464-07-3 Pinacolyl alcohol: 3,3-Dimethylbutan-2-ol 0 0
108 509-14-8 Methane, tetranitro- 0 0
109 534-52-1 Dinitrocresol 0 0
110 538-07-8 Bis(2-chloroethyl)ethylamine(HN1) 0 0
111 541-25-3 2-Chlorovinyldichloroarsine(L) 0 0
112 542-88-1 Methane, oxybis[chloro- 0 0
113 555-77-1 Tris(2-chloroethyl)amine(HN3) 0 0
114 556-64-9 Methyl thiocyanate 0 0 0
115 676-83-5 Methylphosphinyl dichloride 0 0
116 676-98-2 Methylphosphonothioic dichloride 0 0
117 676-99-3 Methylphosphonyldifluoride(DF) 0 0
118 677-43-0 N,N-Dimethylaminophosphoryl dichloride 0 0
119 683-08-9 Diethyl methylphosphonate 0 0
120 753-59-3 Methylphosphinyl difluoride 0 0
121 753-98-0 Ethylphosphonyl difluoride(SD) 0 0
122 756-79-6 Dimethyl methylphosphonate 0 0
123 762-04-9 Diethyl phosphite 0 0
124 868-85-9 Dimethyl phosphite 0 0
125 869-24-9 2-Chloroethydiethyl ammonium chloride 0 0
126 944-22-9 O-Ethyl S-phenyl ethylphosphonothiolothionate 0 0
127 993-13-5 Methylphosphonic acid 0 0
128 993-43-1 ethyl phosphonothioic dichloride 0 0
129 1066-50-8 Ethylphosphonyl dichloride 0 0
130 1314-80-3 Phosphorus pentasulfide 0 0
131 1314-84-7 Zinc phosphide 0 0
132 1563-66-2 Carbofuran 0 0
-
- 66 -
133 1619-34-7 Quinuclidin-3-ol 0 0
134 2404-03-07 Diethyl N,N-dimethylosphoramidate 0 0
135 4098-71-9 Isophorone diisocyanate 0 0
136 4261-68-1N,N-Diisopropyl-2-aminoethyl?chloride
hydrochloride 0 0
137 5842-07-09 N,N-Diisopropyl-(beta)-aminoethane thiol 0 0
138 6163-75-3 Dimethyl ethylphosphonate 0 0
139 6923-22-4 Monocrotophos 0 0
140 7681-49-4 Sodium fluoride 0 0
141 7783-60-0 Sulfur fluoride (SF4), (T-4)- 0 0
142 7783-80-4 Tellurium hexafluoride 0 0
143 7789-23-3 Potassium fluoride 0 0
144 10049-04-4 Chlorine dioxide 0 0
145 10102-44-0 Nitrogen dioxide 0 0
146 10265-92-6 Methamidophos 0 0
147 10545-99-0 Sulfur dichloride 0 0
148 13171-21-6 Phosphamidon 0 0
149 15715-41-0 Diethyl methylphosphonite 0 0
150 50782-69-9O-Ethyl-S-[2(diisopropylamino)ethyl]ethylphos
phonothioate(VX) 0 0
151 57856-11-8O-Ethyl
O-2-diisopropylaminoethylmethylphosphonite(QL)
0 0
152 68648-87-3 Alkyl benzene 0 0
153 76-06-02 Chloropicrin(PS) 0 0
154 78-95-5 chloroacetone 0
155 96-64-0 O-Pinacolyl methylphosphonofiuoridate(GD) 0
156 107-14-2 chloroacetonitrile 0
157 111-36-4 n-butyl isocyanate 0
- 67 -
158 124-63-0 methanesulfonyl chloride 0
159 141-59-3 tert-octyl mercaptan 0
160 329-99-7 Cyclohexyl methylphosphonofluoridate(GF) 0
161 354-32-5 trifluoroacetyl chloride 0
162 503-38-8 Diphosgene(DP) 0
163 532-27-4 Chloroacetophenone(CN) 0
164 540-73-8 1,2-dimethyl hydrazine 0
165 578-94-9 Adamsite(DM) 0
166 592-34-7 n-butyl chloroformate 0
167 593-89-5 Methyldichloroarsine(MD) 0
168 598-14-1 Ethyldichloroarsine(ED) 0
169 598-31-2 Bromacetone(BA) 0
170 674-82-8 diketene 0
171 693-07-2 Bis(2-Chloroethyl sulfide) monoxide(T) 0
172 696-28-6 Phenyldichloroarsine(PD) 0
173 712-48-1 Diphenylchloroarsine(DA) 0
174 993-00-0 methyl chlorosilane 0
175 1189-87-3 Isopropyl ethylphosphonofluoridate(GE) 0
176 1445-76-7 O-Isopropyl methylphosphonochloridate 0
177 1794-86-1 Phosgene oxime(CX) 0
178 2625-76-5 2-Chloroethylchloromethylsulfide 0
179 2698-41-1 Pepper gas(CS) 0
180 2937-50-0 allyl chlorocarbonate 0
181 3563-36-8Sesquimustard:
1,2-Bis(2-chloroethylthio)ethane 0
182 4206-94-4 Phosphonic acid, methyl 0
183 6581-06-02 3-Quinuclidinyl benzilate(BZ) 0
184 7647-19-0 phosphorus pentafluoride 0
-
- 68 -
185 7783-61-1 silicon tetrafluoride 0
186 7783-79-1 selenium hexafluoride 0
187 7783-82-6 tungsten hexafluoride 0
188 7791-25-5 sulfuryl chloride 0
189 7803-52-3 stibine 0
190 10035-10-6 hydrogen bromide 0
191 10294-33-4 boron tribromide 0
192 19395-87-0 Dibenz[1.4] oxazepine (CR) 0
193 23525-22-6 Diphenylcyanoarsine(DC) 0
194 26447-40-5 diphenylmethane-4'-diisocyanate 0
195 40334-70-1 Tris(2-chlorovinyl)arsine 0
196 62207-76-5Cobalt,
((2,2'-(1,2-ethanediylbis(nitrilomethylidene)) 0
197 63869-13-6 Bis(2-chloroethylthio)methane 0
198 63905-10-2 1,3-Bis(2-chloroethylthio)-n-propane 0
199 63918-89-8 O-Mustard: Bis(2-chloroethylthioethyl)ether 0
200 14102-74-12-dimethylaminoethyl-(dimethylanido)-phospho
nofluoridate(GV) 0
201 142868-93-7 1,4-Bis(2-chloroethylthio)-n-butane 0
202 142868-94-8 1,5-Bis(2-chloroethylthio)-n-pentane 0
: , 4
: , 23
: ,
- 69 -
1.4.3.2
.
, ,
,
.
,
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,
.
.
.
.
.
.
-
- 70 -
CAS No NAME OF MATERIAL
SMALL SPILLS(From a small package or leak from a large package)
SMALL SPILLS(From a small package or leak from a large package)
FirstISOLATE
in all Directions
ThenPROTECT
persons Downwind during-
FirstISOLATE
in all Directions
ThenPROTECT
persons Downwind during-
Meters (feet) DAY NIGHT Meters (feet) DAY NIGHTKilometers (Miles) Kilometers (Miles) Kilometers (Miles) Kilometers (Miles)1 50-00-0 Formaldehyde High2 67-66-3 Chloroform High3 74-87-3 Methyl Chloride High4 1975-01-04 Vinyl chloride High5 75-15-0 Carbon disulfide High6 75-21-8 Ethylene oxide 30m 100ft 0.1km 0.1mi 0.2km 0.1mi 90m 300ft 0.8km 0.5mi 2.4km 1.5mi High7 75-56-9 Propylene oxide High8 77-47-4 Hexachlorocyclopentadiene 30m 100ft 0.1km 0.1mi 0.1km 0.1mi 60m 200ft 0.4km 0.3mi 0.5km 0.3mi High9 77-78-1 Dimethyl sulfate 30m 100ft 0.1km 0.1mi 0.1km 0.1mi 60m 200ft 0.5km 0.3mi 0.8km 0.5mi High10 98-95-3 Nitrobenzene High11 106-89-8 Epichlorohydrin High12 107-13-1 Acrylonitrile High13 107-18-6 Allyl alcohol 30m 100ft 0.1km 0.1mi 0.1km 0.1mi 60m 200ft 0.4km 0.2mi 0.6km 0.4mi High14 108-91-8 Cyclohexylamine High15 108-95-2 Phenol. liquid High16 4098-71-9 Isophorone diisocyanate High
1-27
.
1-29
.
- 71 -
17 7647-01-0 Hydrochloric acid(Hydrogen Chloride) High18 7664-39-3 Hydrogen fluoride, gas 30m 100ft 0.1km 0.1mi 0.5km 0.3mi 210m 700ft 1.9km 1.2mi 4.3km 2.7mi High19 7664-41-7 Ammonia 30m 100ft 0.1km 0.1mi 0.1km 0.1mi 60m 200ft 0.6km 0.4mi 2.2km 1.4mi High20 7664-93-9 Sulfuric acid 60m 200ft 0.4km 0.2mi 1.0km 0.6mi 330m 1000ft 2.5km 1.5mi 6.5km 4.0mi High21 7681-49-4 Sodium fluoride High22 7697-37-2 Nitric acid 30m 100ft 0.1km 0.1mi 0.2km 0.2mi 60m 200ft 0.6km 0.4mi 1.2km 0.8mi High23 7719-09-07 Thionyl chloride 30m 100ft 0.3km 0.2mi 0.8km 0.5mi 90m 300ft 1.0km 0.6mi 2.2km 1.4mi High24 7719-12-02 Phosphorus trichloride 30m 100ft 0.2km 0.1mi 0.4km 0.3mi 150m 500ft 1.5km 1.0mi 3.5km 2.2mi High25 7782-50-5 Chlorine(CL) 30m 100ft 0.2km 0.2mi 1.2km 0.8mi 240m 800ft 2.4km 1.5mi 7.4km 4.6mi High26 7790-94-5 Chlorosulfonic acid 30m 100ft 0.1km 0.1mi 0.1km 0.1mi 30m 100ft 0.3km 0.2mi 0.4km 0.3mi High27 10025-87-3 Phosphorus oxychloride 30m 100ft 0.2km 0.2mi 0.4km 0.3mi 120m 400ft 1.0km 0.7mi 2.2km 1.4mi High28 10035-10-6 hydrogen bromide 30m 100ft 0.1km 0.1mi 0.5km 0.3mi 180m 600ft 1.8km 1.1mi 5.7km 3.6mi High29 26447-40-5 diphenylmethane-4'-diisocyanate High30 107-07-3 2-Chloroethanol 30m 100ft 0.2km 0.1mi 0.3km 0.2mi 90m 300ft 0.8km 0.5mi 1.6km 1.0mi Medium31 124-63-0 methanesulfonyl chloride 60m 200ft 0.4km 0.2mi 0.5km 0.4mi 150m 500ft 1.6km 1.0mi 2.6km 1.6mi Medium32 302-01-2 Hydrazine Medium33 1314-80-3 Phosphorus pentasulfide 30m 100ft 0.1km 0.1mi 0.6km 0.4mi 150m 500ft 1.0km 0.6mi 3.9km 2.4mi Medium34 1314-84-7 Zinc phosphide Medium35 1563-66-2 Carbofuran Medium36 6923-22-4 Monocrotophos Medium37 7726-95-6 Bromine 60m 200ft 0.5km 0.3mi 1.8km 1.1mi 330m 1100ft 3.3km 2.1mi 7.3km 4.6mi Medium38 7789-23-3 Potassium fluoride Medium39 7803-51-2 Phosphine 60m 200ft 0.7km 0.4mi 3.1km 1.9mi 450m 1400ft 4.3km 2.7mi 9.6km 6.0mi Medium40 10026-13-8 Phosphorus pentachloride 30m 100ft 0.1km 0.1mi 0.5km 0.3mi 90m 300ft 0.8km 0.5mi 3.1km 1.9mi Medium41 13171-21-6 Phosphamidon Medium42 51-75-2 Bis(2-chloroethyl)methylamine(HN2) 30m 100ft 0.2km 0.1mi 0.2km 0.1mi 60m 200ft 0.5km 0.3mi 1.2km 0.7mi Low43 78-00-2 Tetraethyl lead LowHigh : 1,000
Medium : 1,000 1
Low : 1
-
- 72 -
1.4.3.3
.
,
.
.
.
.
.
SCPOP .
SCPOP , ,
SCPOP
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10
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(38, 56) .
- 73 -
CAS No
AEGL ERPGLevel UNIT 10min 30min 1hr 4hr 8hr ERPG-1 ERPG-2 ERPG-3
1 74-90-8 Hydrogen cyanide(AC)AEGL 1 ppm 2.5 2.5 2.0 1.3 1.0
NA 10 ppm 25 ppmAEGL 2 ppm 17 10 7.1 3.5 2.5AEGL 3 ppm 27 21 15 8.6 6.6
2 75-21-8 Ethylene oxideAEGL 1 ppm NR NR NR NR NR
NA 50 ppm 500 ppmAEGL 2 ppm 80 80 45 14 7.9AEGL 3 ppm 360 360 200 63 35
3 75-44-5 Carbonyl dichloride(Phosgene, CG)AEGL 1 ppm NR NR NR NR NR
N/A 0.2 ppm 1 ppmAEGL 2 ppm 0.60 0.60 0.30 0.080 0.040AEGL 3 ppm 3.6 1.5 0.75 0.20 0.090
4 107-44-8 O-Isopropyl methylphosphonofiuoridate(GB)AEGL 1 mg/m3 0.0012 0.00068 0.00048 0.00024 0.00017AEGL 2 mg/m3 0.015 0.0085 0.0060 0.0029 0.0022AEGL 3 mg/m3 0.064 0.032 0.022 0.012 0.0087
5 7647-01-0 Hydrochloric acid(Hydrogen Chloride)AEGL 1 ppm 1.8 1.8 1.8 1.8 1.8
3 ppm 20 ppm 150 ppmAEGL 2 ppm 100 43 22 11 11AEGL 3 ppm 620 210 100 26 26
6 7664-39-3 Hydrogen fluoride, gasAEGL 1 ppm 1.0 1.0 1.0 1.0 1.0
2 ppm 20 ppm 50 ppmAEGL 2 ppm 95 34 24 12 12AEGL 3 ppm 170 62 44 22 22
7 7664-41-7 AmmoniaAEGL 1 ppm 30 30 30 30 30
25 ppm 150 ppm 750 ppmAEGL 2 ppm 220 220 160 110 110AEGL 3 ppm 2,700 1,600 1,100 550 390
8 7664-93-9 Sulfuric acidAEGL 1 mg/m3 0.20 0.20 0.20 0.20 0.20
2 mg/m3 10 mg/m3 30 mg/m3AEGL 2 mg/m3 8.7 8.7 8.7 8.7 8.7AEGL 3 mg/m3 270 200 160 110 93
9 7782-50-5 Chlorine(CL)AEGL 1 ppm 0.50 0.50 0.50 0.50 0.50
1 ppm 3 ppm 20 ppmAEGL 2 ppm 2.8 2.8 2.0 1.0 0.70AEGL 3 ppm 50 28 20 10 7.1
10 10025-87-3 Phosphorus oxychlorideAEGL 1 ppm NR NR NR NR NRAEGL 2 ppm NR NR NR NR NRAEGL 3 ppm 1.1 1.1 0.85 0.54 0.27
1-38. (10)
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1803
. 1903 Franklin Roosevelt
Bureau of Public Roads, Reconstruction Finance Corporation
, 1934
Flood Control Act
.
1950
.
(Civil Defense Director) ,
. (Federal Civil Defense
Administration(FCDA)) .
DOD(Department of Defense) Office of Defense Mobilization
, 1958 FCDA (Office of Civil and Defense
Mobilization) .
1961 ,
.
1968 (National Flood Insurance Act)
(NFIP)
.
1970 (Crisis Management)
. Dept. of Commerce(,
), General Services Administration(, /
), Treasury Dept.( ), Nuclear Regulatory Commission(),
Dept. of Housing and Urban Development 100
. 1974 (Disaster Relief
Act) . 1979 3 31
EO 12127 12148 FEMA . FEMA
-
- 82 -
(Integrated
Emergency Management System(IEMS))
FEMA .
FEMA 1980
FEMA
. FEMA , ,
,
1989 Hugo, Loma Prieta (), 1992 Andrew
FEMA . FEMA
FEMA James L. Witt(19932001)
, , , ,
.
1990 1993 World Trade Center, 1995 Oklahoma city
. 1995 10 PDD-39
FRP ,
Nunn-Lugar-Domenici 1996 FEMA,
, , , National Guard
. 1999
TOPOFF ,
2000 . 2001 9 11
World Trade Center .
911
Office of Homeland Security , 2002
11 25 Homeland Security Act , 2003 1 24
, ,
22, 179,000 (Department of Homeland
Security, DHS) .
911 ,
, 2005 Katrina
. 2005
(Crisis Management) ,
.
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.
1800 1950
1803
1934 Flood Control Act
1950
1958
( )
1960
1961
( )
1970
1974 Disaster Relief Act
( )
1979. 3. 31. FEMA
1980
FEMA
FEMA
1990 Witt
1993 World Trade Center, 1995 Oklahoma city
, ,
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20012004
2002 Homeland Security Act
2003. 1. 24. Dept. of Homeland Security
22 179000
2004 FRP NRP
2005
( Katrina )
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-
- 84 -
1993 World Trade
Center 6, 1,043
1995
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2001 911 3,404, 2,337
2-2.
2.1.2.
2.1.2.1
. Nunn-Lugar-Domenici Act
1993 (WTC) , 1995 , 1995
3
(Nunn-Lugar-Domenici) 1993 9 23 WMD
Act .
,
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. Presidential Decision Directives(PDD)
Presidential Decision Directive (PDD)
,
PDD PDD-39, 62, 63. PDD-39 1995 6
FEMA , 1998 5
PDD-62(Combating Terrorism)
, (Office of the National
Coordinator for Security, Infrastructure Protection and Counterterrorism)
, , WMD (Consequence
Management)
. 1998 5 PDD-63(Protecting America's Critical
Infrastructure) ,
.
- 85 -
NCSCID National Security Council Intelligence Directives 19471977 TrumanFord
NSAM National Security Action Memorandums 19611969 Kennedy, Johnson
NSSM National Security Study Memorandums 19691977 Nixon, Ford
NSDM National Security Decision Memorandums 19691977 Nixon, Ford
PRM Presidential Review Memorandums 19771981 Carter
PD Presidential Directives 19771981 Carter
NSSD National Security Study Directives 19811989 Reagan
NSDD National Security Decision Directives 19811989 Reagan
NSR National Security Reviews 19891993 Bush
NSD National Security Directives 19891993 Bush
PRD Presidential Review Directive 19932000 Clinton
PDD Presidential Decision Directives 19932000 Clinton
NSPD National Security Presidential Directives 2001 G. W. Bush
2-3.
PDD 1 Establishment of Presidential Review and Decision Series 1993. 1. 20.
PDD 2 Organization of the National Security Council 1993. 1. 20.
PDD 36 U.S. Policy on Protecting the Ocean Environment 1995. 4. 5.
PDD 39 Counterterrorism Policy[FEMA abstract and Federal Response Plan] 1995. 6. 21.
PDD 62Protection Against Unconventional Threats to the Homelandand Americans Overseas
1998. 5. 22.
PDD 63
Critical Infrastructure Protection [Fact Sheet, White Paper, DODCIP Plan, National Plan for Information Systems Protection (Jan2000), and Report to Congress on Status of Federal CriticalInfrastructure Protection Actions (Jan 2001)]
1998. 5. 22.
PDD 75 Counterintelligence for the 21st Century (Fact Sheet) 2001. 1. 5.
2-4. PDD
. Homeland Security Presidential Directives(HSPD)
W.
National Security Presidential Directives (NSPDs) . NSPD 1
Presidential Decision Directives
Presidential Review Directives .
-
- 86 -
. 2001 2 13
(National Security Council) 2001 3 13
. 2001 10 29
Homeland Security Presidential Directives (HSPDs)
. NSPD HSPD ,
HSPD-5 7 .
NSPD 1 Organization of the National Security Council System 2001. 2. 13.
NSPD 17 [National Strategy to Combat Weapons of Mass Destruction]2002. 12. 11.
()
NSPD 46 [on the war on terrorism] ~2006. 3.
HSPD 1 Organization and Operation of the Homeland Security Council 2001. 10. 29.
HSPD 3 Homeland Security Advisory System 2002. 3. 11.
HSPD 4[National Strategy to Combat Weapons of Mass Destruction]
(unclassified version)2002. 12. 11.
HSPD 5Management of Domestic Incidents [Initial National Response
Plan, 30 September 03]2003. 2. 28
HSPD 6 Integration and Use of Screening Information 2003. 9. 16.
HSPD 7Critical Infrastructure Identification, Prioritization, and
Protection2003. 12. 17.
HSPD 8 National Preparedness 2003. 12. 17.
HSPD 11 Comprehensive Terrorist-Related Screening Procedures 2004. 8. 27.
HSPD 15 [on the war on terrorism] ~2006. 3.
HSPD 16 [on threats to commercial aircraft] 2006. 6.
2-5. NSPD HSPD
. (Executive Orders : EO)
,
, . EO
1936 3 13 . EO FEMA EO 12127
12148 13228.
- 87 -
EO 12127 Federal Emergency Management Agency 1979. 3. 31.
EO 12148 Federal Emergency Management 1979. 7. 20.
EO 13228Establishing the Office of Homeland Security and theHomeland Security Council
2001. 10. 8.
EO 13260Establishing the President's Homeland Security AdvisoryCouncil and Senior Advisory Committees for HomelandSecurity
2002. 3. 19.
EO 13354 National Counterterrorism Center 2004. 8. 27.
EO 13356Strengthening the Sharing of Terrorism Information toProtect Americans
2004. 8. 27.
EO 13382Blocking Property of Weapons of Mass DestructionProliferations and Their Supporters
2005. 6. 28.
2-6. EO
2.1.2.2
. (Federal Response Plan : FRP)
(FRP) Robert T. Stafford Disaster Relief and Emergency
Assistance Act
,
.
, , ,
, ,
, ,
12 (Emergency Support Function, ESF)
/
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1996 Atlanta 1997 2 Terrorism
-
- 88 -
Incident Annex .
FRP 2004 12 NRP .
. (National Response Plan : NRP)
911 2003 2
HSPD-5 2004 12 .
NRP FRP ,
FRP
. NRP .
NRP .
Federal Response Plan(FRP) : 1992
EPA : ESF#10 Hazardous Materials
Federal Radiological Emergency Response
Plan(FRERP)
: 1996
EPA :
Environmental Radiation Ambient
Monitoring Systems
Domestic Terrorism Concept of Operations
Plan(CONPLAN)
: 2001
PDD-39 6
- DOJ/ FBI, FEMA,
DOD, DOE, EPA, HHS
- : FBI
- : FEMA
EPA : (OSC)
( )
National Oil Spill and Hazardous
Substance Pollution Contingency Plan(NCP)
: 1968
,
: EPA
2-7. NRP
FRP NRP Incident Annex
, , , / , ,
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NRP
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NRP
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.
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.(2005 DRF : 22$)
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)
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.
(awareness),
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(response),
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NRP
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Dept. of Defense Dept. of Education
Dept. of Energy Dept. of Health and Human Resources
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Dept. of the Interior Dept. of Justice
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Federal Bureau of Investigation Federal Communication Commission
General services Administration National Aeronautics and Space Administration
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, (tribal)
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Homeland Security Operation Center(HSOC)
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National Response Coordination Center(NRCC) .
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, Regional
Response Coordination Center(RRCC) , Principal
Officer(FCO) Federal Resource Coordinator(FRC) . Incident
Command System(ICS) Unified Command(UC)
DHS Principal Federal
Official(PFO)
. Federal
Coordinating Officer(FCO) DHS
,
Joint Field Officer(JFO) .
FBI .
(National Incident Management System: NIMS)
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2-1. NIMS
NRP
NRP
-
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Homeland Security Council(HSC) National Security Council(NSC)
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Homeland Security Operations Center(HSOC)
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- Terrorist Screening Center(TSC), FBI SIOC, National Counter Terrorism
Center(NCTC)
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FBI Strategic Information Operations Center(FBI SIOC)
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National Counterterrorism Center(NCTC)
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NRP (ESF)
NRP (ESF) HSOC National Response Coordination
Center(NRCC) ESF
. ESF NRCC .
Regional Response Coordination Center(RRCC) ESF , ESF
. ESF
(SOP), . ESF
-
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, .
ESF
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/
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Defense Support of Civil Authorities(DSCA)
( ESF )
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ESF #1 Dept. of Transportation(DOT)
ESF #2 DHS
ESF #3 U.S. Army Corps of Engineers
ESF #4 U.S. Forest Service
ESF #5 FEMA
ESF #6 , FEMA
ESF #7 General Services Administration
ESF #8 HHS
ESF #9 FEMA
ESF #10 EPA
ESF #11 Dept. of Agriculture
ESF #12 DOE
ESF #13 DHS, DOJ
ESF #14 FEMA
ESF #15 DHS
2-10. NRP 15
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2-2. 15 ESF
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*
2.1.3
NRP NIMS .
NRP
NIMS ,
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) , Homeland
Security Operations Center(HSOC) DHS
. HSPD-5 .
DHS
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DHS
DHS( )
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Interagency Incident Management
Group(IIMG) National Response Coordination Center(NRCC)
. NRP .
2-4. NRP
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DHS Office of State and Local Government Coordination and
Preparedness(SLGCP) in Office for Domestic Preparedness(ODP)
- 101 -
130$ .(2003 50.56$, 2004 31.02$, 2005 25.19
$, 2006 26.90$) State
Homeland Security Program(SHSP), Urban Areas Security Initiative(UASI), Law
Enforcement Terrorism Prevention Program(LETPP), Citizen Corps Program(CCP),
Emergency Management Performance Grants(EMPG), Metropolitan Medical
Response System(MMRS) Program, Targeted Infrastructure Protection
Grants(TIPG) .
960,000 28,495
830,000 5,841
() 710,000 27,496
2-11.
* www.saftysource.com
(local emergency manager)
.
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,
Emmitsburg FEMA Emergency
Management Institute(EMI) .
(Certified Emergency Management Program)
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50 6
Office of Emergency Management ,
(State Emergency Response Team(SERT))
.
.
1970 34 52 National
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Volunteer Organization Against Disasters(NVOAD)
. USA Freedom Corps
24,000
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. FEMA
FEMA 1979 . 911
.
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(Preparedness, Response
and Recovery Directorate)
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Mitigation
Administration)
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Flood Insurance Program)
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Directorate)
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Service Directorate)
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National Oceanic and Atmospheric Admin.
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DOJ
DOD, FEMA, DOE, EPA WMD
. Domestic Emergency Support Team(DEST)
DHS FBI ( )
,
Office of Emergency Preparedness
Dept. of Health and Human Services
National Disaster Medical System(NDMS) Metropolitan Medical Response
System(MMRS)
. NDMS
- Disaster Medical Assistance Team(DMAT)
- Disaster Mortuary Operational Response Team(DMORT)
- Veterinary Medical Assistance Team(VMAT)
- Federal Coordinating Centers(FCCs)
- National Pharmacy Response Team(NPRT)
- National Nurse Response Team(NNRT)
. MMRS
Washington Metropolitan Medical Strike Team(MMST) (
)
DHS Office of State and Local Government Coordination and
Preparedness(SLGCP)
MMRS :
-
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-
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- WMD
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- WMD
MMRS
-
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