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Study Questions and Material ReadingsStudy QuestionsStudy Questionsreference papersCottonBasic Inorganic Chemistryhomework
2001
Basic Inorganic Chemistry (3rd edition) (F. Albert Cotton)
Principles of Modern Chemistry (5th edition) (David W. Oxtoby)
Descriptive Inorganic Chemistry (2nd edition) (Geoff Rayner Vanhan)
2004Study Questions and Material Readings
20054
Inorganic Chemistry (R. B. Heslop)
Chem One (J. Wasew, etc)
Chemistry Problems (sec. edition) (M. H. seenko)
General Chemistry (R. H. Petrucei)
Chemistry (L. & P. Pauling)
General College Chemistry (5th edition) (L. W. reenan)
General Chemistry (J. E. Brading)
Modern Inorganic Chemistry (G. F. Liptrot)
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20017
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51
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58
61
65
67
69
75
I 79
II 87
90
Study Questions
Chapter 1 The Behavior of Gases, Liquids and Solutins92
Chapter 2 The Basic Chemical Thermodynamics and Chemical Equilibia94
Chapter 3 The Basic Chemical Kinetics99
Chapter 4 Equilibia of Acids and Bases102
Chapter 5 Ionic Equilibia in Aqueous System105
Chapter 6 The Oxidation-Reduction Reactions and Electrochemistry108
Chapter 7 The Atomic Structure111
Chapter 8 The Chemical Bond and Molecular Structures113
Chapter 9 Group VIII s and p Elements119
Chapter 10 Group I and II s Elements121
Chapter 11 Group VII p Elements 124
Chapter 12 Group VI p Elements 127
Chapter 13 Group V p Elements130
Chapter 14 Group IV p Elements133
Chapter 15 Group III p Elements136
Chapter 16 The Coordination Compounds138
Chapter 17 The Transition Elements 141
Chapter 18 The Elements of the First Transition Series 144
Chapter 19 The Elements of the Second Transition Series 146
Chapter 20 Scandium, Yttrium, the Lanthanides and the Actinides 148
I-1 SI 150
I-2 SI 150
II 151
III tp 152
IV (fH m(fG mS m 153
V K 159
VI Ksp(298K) 160
VII-1 (298K) 161
VII-2 (298K) 163
VIII K 165
IX KbKf 166
X 298K, p 166
XI 167
XII 168
1. 71/3
2. 2730.0atm480g1001001.00atm
3. 308.0gCO26.0gO2N210dm3800 mmHg
(1) (2)
(3) (4)
4. COCO21.82g(dm3(STPCO
5. 202050500760mmHg200dm3
6. S2F10291atm
7. 8.2dm34.0g0.50mol2atm 127
(1) (2)
(3)
(4)
2H2(g) + O2(g) 2H2O(g)
127
8. 451atm2.56g(dm3
(1) (2)
9. 1.00atm100300cm3H2100 cm3O2271.00atm
(2726.7mmHg)
10. 0.75molA42molO2
11. AB25
A O2 500 cm31atm
B N2 500 cm30.5atm
AB
(1) (2)
(3)
12. 1dm3100 cm3HCl 10%(1.19g(cm3)270.327g(65.4)(1atm)
13. 5.00g251atm10dm3
14. 5.00gFeCl3()1dm34270.89atmFe2Cl6FeCl3
15. CxHyClz816CO216H2O8Cl2()
16. 100cm3O250cm3COC2H6COC2H6CO2H2O()85cm3COC2H6
17. 2.0(104dm3(STP)NaI
O3 + 2I + H2O O2 + I2 + 2OH
I20.0106mol(dm3
I2 + 2Na2S2O3 2NaI + Na2S4O6
I2Na2S2O34.2dm3
(1) Na2S2O3I2
(2) 20000dm3O3
(3) STPO3
(4) O3
18. 20cm330 cm340 cm3()
19. NH32.92
20. (UF6352)(14) (CD3F39)UF6
21. 50atm5010.0gCO285cm3
22. 18760mmHg2.70dm3CaCl23.21g18(29.0)
23. 16747mmHg1dm3CO2CO2
24. ABAB(100)300mmHg100mmHg1001molA1molB100XXA
25. 80753mmHg290mmHg1/3 mol2/3mol
(1) (2)
()
26. 254dm3750mmHg(STP)3dm3()
27. 4g156g200mmHg196.4mmHg
(1) (2)
28. 253%(C6H10O5)0.0272atm
29. 30N232mmHg656mmHg606cm3
30. 455.1K48.139kJ(mol1 400KkPa
31. 40370mmHg740mmHg4.00dm3)
(1)
(2)
32. ,93
((Hevap=43kJ(mol1)
33. (148.4)5dm31atmN211032g1401215g110140
34. 10g100g1.205g()1.273g
35. 250.31mmHg()199.1mmHg0.0147
(1)
(2) ()
36. 0, 1N223.54cm3(dm3O248.89cm3(dm3N279%O2 21%()N2O2
37. 20730mmHg1000g9.3cm3
38. 1atm203.1cm3/100cm3100dm3
39. 0.550g0.045g157.093.46%6.54%()(178.4)
40. 25mg1.00g2.0K(C10H16OKf =40)
41. 1.5g200g42.72g1000g
42. 6g100g1.02K
43. 0.244g20g5.2325.478
44. 0123.54cm3(dm3148.89cm3(dm3
45. 100cm32.30g0.465
46. CO2760mmHg100g335mgCO2(0)CO25atm01kgCO2
47. 5%(M=60.05)10%(M=180.02)
48. (CH2OHCH2OH)
(1) 20
(2) (1.11g(cm3 )30dm3(1)
(3) 1atm
49. 5g100g0.65K (Kb=2.64)
50. 5.12g(C10H8)100gCCl4CCl42.00KCCl4
51. 1.50
(1) (2) 25 (3) 25
52. 407.7atm
(1) (2) c = m
53. 0.328%80g40.026atm
(1)
(2)
54. 100ml1.35g259.9(103atm
55. 255.0g1dm37.6mmHg
56. 1717.5g150cm3
57. 0.03525
58. (C6H12O6)(C12H22O11),1%(g(cm3)
59. 045.0g2.97atm
60. CO2Tc = 304.3Kpc = 72.8105 PaCO2
(1) 1bar50bar50ml298K
CO2 a = 3.59105Padm6mol(2 b = 0.0427 dm3 mol(1
(2) 305K350K220gdm(3330 gdm(3and 440 gdm(3
(3) /5.2? 95Pd/Al2O3
4 (a) (b)
(5) ( a) (b)
(6) CO22COCOCl2CO21
1. 60cm23atm20cm
(1) (2)
2. 1dm31atm10dm3
(1)(2)(3)
3. 5.1atm566dm31/2
(1)
(2)365.75kJ
4. 100g2940kJ2.09kJ
5. 1atm10040.67kJ(mol11mol(29.7dm3)
6. 3.71kJ1.2kJ
7. 41.16kJ
8. 2atm10dm320dm31254J
9. 10dm316dm3125.4J,(U(H
10. 300K3mol8atm2atm4WQ(U(H
11. 2dm305atm1atm1atmW(U(HQ
12. 1atm2molH21molO21001atm2mol115.8kJ(mol1H2O(g)(H(U
13. 25(1atm)1/2molOF2
OF2(g) + H2O(g) ( O2(g) + 2HF(g)
161.35kJ(mol1OF2(H(U
14. : N2(g)+3H2(g)(2NH3(g)87.2kJ(mol1
(H(U(25)
15. A + B ( C + D (H = 41.8kJ(mol1
C + D ( E (H = 20.9 kJ(mol1
(H
(1) C + D ( A + B
(2) 2C + 2D ( 2A + 2B
(3) A + B ( E
16. (H (G 298(S
(1) C4H10(g) ( C4H6(g)2H2(g)
(2) C4H8(g) ( C4H6(g)H2(g)
(3) C4H8(g)1/2O2(g) ( C4H6(g)H2O(g)
17. (H 298
(1) C2H4(g) + H2(g) = C2H6(g)
(2) 3C2H2(g) = C6H6(l)
(3) C2H5OH(l) = C2H4(g) + H2O(l)
18.
C() + O2(g) = CO2(g) (H 298= 395.01kJ(mol1
C() + O2(g) = CO2(g) (H 298= 393.13kJ(mol1
C()C()(H 298=
19. PCl5(s)(25)
2P(s) + 3Cl2(g) = 2PCl3(l) (H = 634.5kJ(mol1
PCl3(l) + Cl2(g) = PCl5(s) (H = 137.1kJ(mol1
20. AgCl25
Ag2O(s) + 2HCl(g) = 2AgCl(s) + H2O(l) (H 1= 324.4kJ(mol1
2Ag(s) + 1/2O2(g) = Ag2O (H 2= 30.56kJ(mol1
1/2H2(g) + 1/2Cl2 = HCl(g) (H 3 = 92.21kJ(mol1
H2(g) + 1/2O2(g) = H2O(l) (H 4 = 285.6kJ(mol1
21. SO2SO2SO3SO3H2OH2SO4(l)H2SO4(l)
SO2(g)(Hf = 296.6kJ(mol1
SO2(g)1/2O2=SO3(g)(H = 98.19kJ(mol1
H2O(l)(Hf = 285.6kJ(mol1
SO3(g)+H2O(l)=H2SO4(l)(H = 130.2kJ(mol1
22. ((Hf )(H
(1) 2Al(s) + Fe2O3(s) ( Al2O3(s) + 2Fe(s)
(2) SiH4(g) + 2O2(g) ( SiO2(s) + 2H2O(g)
(3) CaO(s) + SO3(g) ( CaSO4(s)
(4) CuO(s) + H2(g) ( Cu(s) + H2O(g)
(5) C2H4(g) + H2(g) ( C2H6(g)
23.
Fe2O3(s) + 3CO(g) ( 2Fe(s) + 3CO2(g) (H 1= 27.59kJ(mol1
3Fe2O3(s) + CO(g) ( 2Fe3O4(s) + CO2(g) (H 2= 58.52kJ(mol1
Fe3O4(s) + CO(g) ( 3FeO(s) + CO2(g) (H 3= + 38.04kJ(mol1
(H
FeO(s) + CO(g) ( Fe(s) + CO2(g)
24. COH2O()
H2O(g) + C() (CO(g) + H2(g) (H
25. (H
2C() + 2H2(g) + H2O(l) ( C2H5OH(l)
H2O(l)H2O(g)(H
26.
(1) 3H2(g) + N2(g) ( 2NH3(g) (H= 92.4kJ(mol1
(2) 2H2(g) + O2(g) ( 2H2O(g) (H= 483.7kJ(mol1
4NH3(g) + 3O2(g) ( 2N2(g) + 6H2O(g)
27. CH4
(1) CH4 + 2O2 ( CO2 + 2H2O(l) (H = 890.3kJ(mol1
(2) 2H2 + O2 ( 2H2O(l) (H = 572.7kJ(mol1
(3) C()
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