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20017TA

Study Questions and Material ReadingsStudy QuestionsStudy Questionsreference papersCottonBasic Inorganic Chemistryhomework

2001

Basic Inorganic Chemistry (3rd edition) (F. Albert Cotton)

Principles of Modern Chemistry (5th edition) (David W. Oxtoby)

Descriptive Inorganic Chemistry (2nd edition) (Geoff Rayner Vanhan)

2004Study Questions and Material Readings

20054

Inorganic Chemistry (R. B. Heslop)

Chem One (J. Wasew, etc)

Chemistry Problems (sec. edition) (M. H. seenko)

General Chemistry (R. H. Petrucei)

Chemistry (L. & P. Pauling)

General College Chemistry (5th edition) (L. W. reenan)

General Chemistry (J. E. Brading)

Modern Inorganic Chemistry (G. F. Liptrot)

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20017

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6

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31

39

44

51

52

55

58

61

65

67

69

75

I 79

II 87

90

Study Questions

Chapter 1 The Behavior of Gases, Liquids and Solutins92

Chapter 2 The Basic Chemical Thermodynamics and Chemical Equilibia94

Chapter 3 The Basic Chemical Kinetics99

Chapter 4 Equilibia of Acids and Bases102

Chapter 5 Ionic Equilibia in Aqueous System105

Chapter 6 The Oxidation-Reduction Reactions and Electrochemistry108

Chapter 7 The Atomic Structure111

Chapter 8 The Chemical Bond and Molecular Structures113

Chapter 9 Group VIII s and p Elements119

Chapter 10 Group I and II s Elements121

Chapter 11 Group VII p Elements 124

Chapter 12 Group VI p Elements 127

Chapter 13 Group V p Elements130

Chapter 14 Group IV p Elements133

Chapter 15 Group III p Elements136

Chapter 16 The Coordination Compounds138

Chapter 17 The Transition Elements 141

Chapter 18 The Elements of the First Transition Series 144

Chapter 19 The Elements of the Second Transition Series 146

Chapter 20 Scandium, Yttrium, the Lanthanides and the Actinides 148

I-1 SI 150

I-2 SI 150

II 151

III tp 152

IV (fH m(fG mS m 153

V K 159

VI Ksp(298K) 160

VII-1 (298K) 161

VII-2 (298K) 163

VIII K 165

IX KbKf 166

X 298K, p 166

XI 167

XII 168

1. 71/3

2. 2730.0atm480g1001001.00atm

3. 308.0gCO26.0gO2N210dm3800 mmHg

(1) (2)

(3) (4)

4. COCO21.82g(dm3(STPCO

5. 202050500760mmHg200dm3

6. S2F10291atm

7. 8.2dm34.0g0.50mol2atm 127

(1) (2)

(3)

(4)

2H2(g) + O2(g) 2H2O(g)

127

8. 451atm2.56g(dm3

(1) (2)

9. 1.00atm100300cm3H2100 cm3O2271.00atm

(2726.7mmHg)

10. 0.75molA42molO2

11. AB25

A O2 500 cm31atm

B N2 500 cm30.5atm

AB

(1) (2)

(3)

12. 1dm3100 cm3HCl 10%(1.19g(cm3)270.327g(65.4)(1atm)

13. 5.00g251atm10dm3

14. 5.00gFeCl3()1dm34270.89atmFe2Cl6FeCl3

15. CxHyClz816CO216H2O8Cl2()

16. 100cm3O250cm3COC2H6COC2H6CO2H2O()85cm3COC2H6

17. 2.0(104dm3(STP)NaI

O3 + 2I + H2O O2 + I2 + 2OH

I20.0106mol(dm3

I2 + 2Na2S2O3 2NaI + Na2S4O6

I2Na2S2O34.2dm3

(1) Na2S2O3I2

(2) 20000dm3O3

(3) STPO3

(4) O3

18. 20cm330 cm340 cm3()

19. NH32.92

20. (UF6352)(14) (CD3F39)UF6

21. 50atm5010.0gCO285cm3

22. 18760mmHg2.70dm3CaCl23.21g18(29.0)

23. 16747mmHg1dm3CO2CO2

24. ABAB(100)300mmHg100mmHg1001molA1molB100XXA

25. 80753mmHg290mmHg1/3 mol2/3mol

(1) (2)

()

26. 254dm3750mmHg(STP)3dm3()

27. 4g156g200mmHg196.4mmHg

(1) (2)

28. 253%(C6H10O5)0.0272atm

29. 30N232mmHg656mmHg606cm3

30. 455.1K48.139kJ(mol1 400KkPa

31. 40370mmHg740mmHg4.00dm3)

(1)

(2)

32. ,93

((Hevap=43kJ(mol1)

33. (148.4)5dm31atmN211032g1401215g110140

34. 10g100g1.205g()1.273g

35. 250.31mmHg()199.1mmHg0.0147

(1)

(2) ()

36. 0, 1N223.54cm3(dm3O248.89cm3(dm3N279%O2 21%()N2O2

37. 20730mmHg1000g9.3cm3

38. 1atm203.1cm3/100cm3100dm3

39. 0.550g0.045g157.093.46%6.54%()(178.4)

40. 25mg1.00g2.0K(C10H16OKf =40)

41. 1.5g200g42.72g1000g

42. 6g100g1.02K

43. 0.244g20g5.2325.478

44. 0123.54cm3(dm3148.89cm3(dm3

45. 100cm32.30g0.465

46. CO2760mmHg100g335mgCO2(0)CO25atm01kgCO2

47. 5%(M=60.05)10%(M=180.02)

48. (CH2OHCH2OH)

(1) 20

(2) (1.11g(cm3 )30dm3(1)

(3) 1atm

49. 5g100g0.65K (Kb=2.64)

50. 5.12g(C10H8)100gCCl4CCl42.00KCCl4

51. 1.50

(1) (2) 25 (3) 25

52. 407.7atm

(1) (2) c = m

53. 0.328%80g40.026atm

(1)

(2)

54. 100ml1.35g259.9(103atm

55. 255.0g1dm37.6mmHg

56. 1717.5g150cm3

57. 0.03525

58. (C6H12O6)(C12H22O11),1%(g(cm3)

59. 045.0g2.97atm

60. CO2Tc = 304.3Kpc = 72.8105 PaCO2

(1) 1bar50bar50ml298K

CO2 a = 3.59105Padm6mol(2 b = 0.0427 dm3 mol(1

(2) 305K350K220gdm(3330 gdm(3and 440 gdm(3

(3) /5.2? 95Pd/Al2O3

4 (a) (b)

(5) ( a) (b)

(6) CO22COCOCl2CO21

1. 60cm23atm20cm

(1) (2)

2. 1dm31atm10dm3

(1)(2)(3)

3. 5.1atm566dm31/2

(1)

(2)365.75kJ

4. 100g2940kJ2.09kJ

5. 1atm10040.67kJ(mol11mol(29.7dm3)

6. 3.71kJ1.2kJ

7. 41.16kJ

8. 2atm10dm320dm31254J

9. 10dm316dm3125.4J,(U(H

10. 300K3mol8atm2atm4WQ(U(H

11. 2dm305atm1atm1atmW(U(HQ

12. 1atm2molH21molO21001atm2mol115.8kJ(mol1H2O(g)(H(U

13. 25(1atm)1/2molOF2

OF2(g) + H2O(g) ( O2(g) + 2HF(g)

161.35kJ(mol1OF2(H(U

14. : N2(g)+3H2(g)(2NH3(g)87.2kJ(mol1

(H(U(25)

15. A + B ( C + D (H = 41.8kJ(mol1

C + D ( E (H = 20.9 kJ(mol1

(H

(1) C + D ( A + B

(2) 2C + 2D ( 2A + 2B

(3) A + B ( E

16. (H (G 298(S

(1) C4H10(g) ( C4H6(g)2H2(g)

(2) C4H8(g) ( C4H6(g)H2(g)

(3) C4H8(g)1/2O2(g) ( C4H6(g)H2O(g)

17. (H 298

(1) C2H4(g) + H2(g) = C2H6(g)

(2) 3C2H2(g) = C6H6(l)

(3) C2H5OH(l) = C2H4(g) + H2O(l)

18.

C() + O2(g) = CO2(g) (H 298= 395.01kJ(mol1

C() + O2(g) = CO2(g) (H 298= 393.13kJ(mol1

C()C()(H 298=

19. PCl5(s)(25)

2P(s) + 3Cl2(g) = 2PCl3(l) (H = 634.5kJ(mol1

PCl3(l) + Cl2(g) = PCl5(s) (H = 137.1kJ(mol1

20. AgCl25

Ag2O(s) + 2HCl(g) = 2AgCl(s) + H2O(l) (H 1= 324.4kJ(mol1

2Ag(s) + 1/2O2(g) = Ag2O (H 2= 30.56kJ(mol1

1/2H2(g) + 1/2Cl2 = HCl(g) (H 3 = 92.21kJ(mol1

H2(g) + 1/2O2(g) = H2O(l) (H 4 = 285.6kJ(mol1

21. SO2SO2SO3SO3H2OH2SO4(l)H2SO4(l)

SO2(g)(Hf = 296.6kJ(mol1

SO2(g)1/2O2=SO3(g)(H = 98.19kJ(mol1

H2O(l)(Hf = 285.6kJ(mol1

SO3(g)+H2O(l)=H2SO4(l)(H = 130.2kJ(mol1

22. ((Hf )(H

(1) 2Al(s) + Fe2O3(s) ( Al2O3(s) + 2Fe(s)

(2) SiH4(g) + 2O2(g) ( SiO2(s) + 2H2O(g)

(3) CaO(s) + SO3(g) ( CaSO4(s)

(4) CuO(s) + H2(g) ( Cu(s) + H2O(g)

(5) C2H4(g) + H2(g) ( C2H6(g)

23.

Fe2O3(s) + 3CO(g) ( 2Fe(s) + 3CO2(g) (H 1= 27.59kJ(mol1

3Fe2O3(s) + CO(g) ( 2Fe3O4(s) + CO2(g) (H 2= 58.52kJ(mol1

Fe3O4(s) + CO(g) ( 3FeO(s) + CO2(g) (H 3= + 38.04kJ(mol1

(H

FeO(s) + CO(g) ( Fe(s) + CO2(g)

24. COH2O()

H2O(g) + C() (CO(g) + H2(g) (H

25. (H

2C() + 2H2(g) + H2O(l) ( C2H5OH(l)

H2O(l)H2O(g)(H

26.

(1) 3H2(g) + N2(g) ( 2NH3(g) (H= 92.4kJ(mol1

(2) 2H2(g) + O2(g) ( 2H2O(g) (H= 483.7kJ(mol1

4NH3(g) + 3O2(g) ( 2N2(g) + 6H2O(g)

27. CH4

(1) CH4 + 2O2 ( CO2 + 2H2O(l) (H = 890.3kJ(mol1

(2) 2H2 + O2 ( 2H2O(l) (H = 572.7kJ(mol1

(3) C()