メキシコ国 プラスチック成形技術 人材育成プロジェクト · メキシコ国...
TRANSCRIPT
メキシコ国
プラスチック成形技術
人材育成プロジェクト
プロジェクト事業完了報告書
別冊 I:
日本人専門家から CNAD インストラクターへの
技術移転に関する成果品
平成 26 年 11 月
(2014 年)
独立行政法人国際協力機構(JICA)
株式会社日本開発サービス(JDS)
メキシコ国 プラスチック成形技術人材育成プロジェクト
プロジェクト事業完了報告書
別冊I:日本人専門家からCNADインストラクターへの技術移転に関する成果品
目 次
Annex I: 理論研修用教材:PPT テキスト ..................................................................................... A-1
Annex II: 実習教育用教材:実習作業指示書/手順書 ................................................................. A-595
(1) 実習作業指示書 ...................................................................................................................... A-595
(2) 実習指導手順書 ...................................................................................................................... A-635
ANNEX I:
理論研修用教材:PPTテキスト
A-1
Module Sub-Module Page 1 プラスチック
成形方法 1-1 プラスチック成形の概要 31-2 熱可塑性プラスチックの成形法
(押し出し成形、射出成形、サーモフォーミング、回転成形、ブロー成型)
9
1-3 熱硬化性プラスチックの成形法 (圧縮成形、トランスファー成形、エポキシ樹脂の取扱い)
17
1-4 製品の二次加工 242 プラスチック
材料 2-1 特性と特徴 332-2 同定(材料判別方法) 442-3 分類 522-4 成分 572-5 特徴付け 662-6 材料の色とカラーリング 882-7 各種プラスチックとその応用 962-8 射出成形プラスチックの特性評価 105
3 射出成形設備機器
3-1 射出成形設備機器の概要 1173-2 射出成形機の種類とその構造 1293-3 射出成形機の構成部分 1423-4 油圧成形システムとその機能 1663-5 電気成形システムとその機能 1733-6 制御系とその機能 1813-7 測定機器とその機能 1923-8 プラスチック成形工場のレイアウト 1993-9 付帯機器とその機能 208
4 射出成形機のメンテナンス
4-1 予防メンテナンス (4-1~4-3) 2144-2 事後メンテナンス - 4-3 電気系、油圧系、ニューマチック系、電子系の概要 -
5 射出成形 プロセス
5-1 射出成形プロセスの原理 2225-2 射出成形条件の概要
(温度、時間、圧力、速度、型締め圧、加工材料の分量) 238
5-3 射出成形条件の設定 2495-4 プロセスの管理 2645-6 可塑化と材料のフロー 2735-7 成形前の材料処理 2805-8 プリヒート、添加剤、色素 2865-10 製品重量と材料歩留まり計算 2945-11 再生材料使用上の留意点 298
6 射出成形に おける段取り替え
6-1 金型取付け/金型取外し 3096-2 冷却回路(電気配線)の接続 3276-3 射出シリンダー内材料交換(パージ処理) 3336-4 初期成形条件設定と成形品サンプリング 339
A-2
Module Sub-Module Page 7 製品の品質/
生産管理 7-1 理論的概念・概要 (7-1~7-2) 3447-2 射出成形企業に適用する品質システム - 7-3 品質管理に使うグラフ 3577-4 製品の不良の原因と分析方法(QC7toolほか) 3667-5 工程能力管理 3897-6 5SとKAIZEN活動 4037-7 金型段取り改善の手法(SMED) 411
8 射出成形不良と成形条件調整
8-1 材料乾燥条件に関連する成形不良 (8-1~8-5) 4198-2 可塑化条件に関連する成形不良 - 8-3 射出条件に関連する成形不良 - 8-4 保圧条件に関連する成形不良 - 8-5 成形品取り出しに関連する成形不良 - 8-6 成形不良改善に関する応用演習 4288-7 金型に関連する成形不良 437
9 プロセスに おける安全管理
9-1 射出成形作業における危険 4429-2 作業者の安全防具 4499-3 成形機の安全システム 450
10 プラスチック 射出成形の金型
10-1 一般概要(機能・分類) 45610-2 金型の構造、構成部品(インサートほか) 46710-3 金型と使用機械の適合 48710-4 キャビディーとコア 49310-5 ランナーゲート方案 50410-6 金型の温度制御 51410-7 離型機構(突き出し/アンダーカット処理) 52510-8 金型用材料 (10-8~10-9) 53710-9 熱処理・表面処理 - 10-10 金型のデザイン・メンテナンス 54510-11 金型のメンテナンス(金型の分解・組立) 56410-14 金型のメンテナンスによる品質生産性改善① 58310-15 金型のメンテナンスによる品質生産性改善② 589
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16.1
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39
A-42
16.2�
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40
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100% 1 187 1130 33,700
2 154 1070 31,600
3 146 1040 30,900
4 140 1110 30,200
30% 1 � 1180 34,700
2 � 1180 34,700
3 � 1180 34,700
4 � 1180 34,700
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LDPE 0.914 0.928 100 110 -100
LLDPE 0.92 0.94
PP Homo-polymer) 0.90 0.91 160 165 -20
GP PS 1.05 90 100
HI PS 1.00 1.05 -85
AS 1.06 1.08
ABS 1.16 1.21
ABS High-impact 1.01 1.05
PVC soft 1.16 1.35 -50 80
PVC rigid 1.38 1.55 212 220 80
PMMA 1.15 1.19 105 120
PET 1.33 1.40 255 260 70 80
15�2��
PA6 1.12 1.15 223 78
PA66 1.13 1.16 255 265 90
PA66 GF33% 1.33 1.34
PA610 1.07 1.09 210 220
POM (homo-polymer) 1.41 1.43 165 175 -70
PC 1.20 1.24 145
PC GF30% 1.40 1.43
PBT 1.31 1.32 220 230 45 60
PBT GF30% 1.48 1.53
PPE modfy 1.08
16
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A-47
PPS (for non-reinforced) 1.34 285-290 85-95
PSF(amorphous) 1.24 190
PES (amorphous) 1.37 225-230
PSU(amorphous) 1.24-1.25 185-190
PPSF(amorphous) 1.29 220
PAR (amorphous) 1.21 193
LCP type GF30 1.62
PEEK 1.32 334-340 143
PI(Thermal) 1.36-1.43 250
17
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Gerd Potsch Walter�Michaeli :Injection�Moldin An�Introduction�p39(1995)��HANSER
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A-51
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7 20078 2007
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(3)
(4)
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1
1.4�(1) 1870 Isaiah,�Jhon Hyatt
(2) Leo�Baekeland 1907 (Bakelite)
(3) 1924 Herman�Staudinger
(4) 1927 ((5) 1930
Du�Pont Wallace�Carothers1938
(6) 1872 � 19261956
Osswald,Menges, p3�7 1997
F.Johannaber:Injection Molding�Machines�A�user’s�Guide,2E(1983)P13�Hnaser 5
1
2
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:
100% PE�HD 70�80%,PA 35�45%,POM 70�80%
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p2(2004)
�5
9
4
PE Polyethylene
PP Polypropylene PE(
PET Polyethyleneterephthalate
4.1
10
PS polystyrene
SAN Acrylonitrile�styrene�copolymer
PS ,�PS
ABS Acrylonitrile�butadiene�styrene�copolymer
,
PMMA polymethylmethacrylate
PVC Polyvinyl�chloride
PV C Polyvinylidene chloride(
PVAc polyvinylacetate 28 HDT(38 )
PVA Polyvinyl�alcohol
11
4
4.2
A-54
PA polyamide
POM polyoximethylene PA
PBT Polybuthylene �terephthalate
PE�UHMV
Polyetyleneultra�high�molecular�weight
12
4
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13
4
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PTFE Fluorocarbon�resin , ,
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14
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EP Epoxy�resin
SI Silicone
PUR polyurethane
PI polyimide
16
6�2009
8%
91%
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885,820ton
vol61,No.6p25,(2010)
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Total� 10,911,794�ton
PF 227,006�UF 72,974�MF 92513UP 117401PDAP 63458EP 149386PU 163082
885,820�PE 2805123PS 799684
AS AS 92394ABS ABS 348369
PP 2410807112055
PMMA 165831PVA 192386PVC 1668119PV C 67565PA 188820
14687PC 280334POM 82719PET 500469PBT 122221m�PPE 27741
9879324146650
10,911,794�
9,879,324ton
PE:25.7%PP:22.1%PVC:15.3%PS,�ABS,�AS:11.4%
17
7�2007
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2%
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16%
3%
8%
3% 10%
2007(ton)24% 30715826% 7448192% 1993761% 1626515% 6533941% 149785
17% 21710753% 436716
16% 19757153% 4202798% 9973383% 434156
10% 1244691
100% 12661577
16,616
: vol 61,No.6�p46
Film:�24%
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total 24,038�
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, vol 61,No.6p45
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19
A-56
2011/9/28,29
1
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A-57
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A-62
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26
5.
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28
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31
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A-65
2012/2/13,14,15
1
M2
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2.2.(1) (PE)2.(2) (PP)2(3) (PET)2.(4)2.(5) (PS)2.(6)2.(7) AS (SAN)2.(8) ABS (ABS)
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4
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A-66
1.(2)
Metal Plastic
Impact�strength�ASTM�D256 IZOD
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5p133,2004,
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7
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/ /
PVC 170 0.29 0.15
PS 100 0.41 0.20
PA 118 0.22 0.24
PE 110 0.50 0.40
PC 98 0.15 0.09
PP 110 0.34 0.23
PMMA 278 0.35 0.22
POM 269 0.37 0.25
ABS 118 0.30 �
9,[7],18,[1965]
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8
A-67
1.(5)�1
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PE�LD 18,500 4,000 1,400 20
PE�HD 3,000 600 220 10
PP( 3,800 860 200 11
PP( 1,680 550 100 6
PET 400 60 25 27
PA6 79 20 6 145
PS 2,400 5,000 800 160
PC 1,225 200 35 80
PVC 442 150 56 40
PVD 70 <115 22 1.5
PVA 10 7 �
EVOH � 2 �
PVDC OPP 15 5�10 1.5 4 5 39 8 38 1990
1(cc/m2/atm,24hr)
at�20 ,65%RH,t=25�m
2(g/m2,24hr)
at�40 ,90%RH,t=25�m
9
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10p33,2004,
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11
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1.(8)
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12p55,2004,
�6
A-68
1.(9)�
%g/cm3
PA66,PA6 35�45 1.24
1.231.071.08
1.141.14
POM 70�80 1.54 1.25 1.41
PET 30�40 1.50 1.33 1.38
PBT 40�50 � � 1.38
PTFE 60�80 2.35 2.00 2.1
PP Isotactic) 70�80 0.95 0.85 0.905
PP Atactic) 50�60 0.95 0.85 0.896
PE�HD 70�80 1.0 0.85 0.95
PE�LD 45�55 1.0 0.85 0.92
Gottfried�W.Ehrenstein:�Plymeric Materials,p67,2001,HANSER
�4
13
1.(10)
arc�resistance)tracking�resistance)
�7 (a)� (b)
14
2.
4 ,(�CH3)
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16
A-69
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17
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,
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18
2.(4)
19
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20
A-70
2.(6)
21p77,2004,
HI�PS PP EPDM ABS,HI�PS/PPE
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22
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23
ABS S�S
24
�1�ABS� PS�HI
Gottfried�W.Ehrenstein:�Plymeric Materials,p110,2001,HANSER
A-71
2.( ) (PVC)
(moisture(water)resistance)
25
�
2.(10) (PMMA)
1.49
26
�
3.
27
3.(1)POM PA PBT PC m�PPE
::
28p105,2004,
�5
A-72
3.(2)
1.�PA66 6.�PEEK2.�PA6 7.�PFS3.�PBT 8.�PPS4.�mPPE 9.�PES5.�PC 10.�PEI
30 33Wt%
29
�10 (1.81MPa)
p69,2004,
3.(3) PA
,
PA6 : Tm=226 Tg=48 ,std.hum (2.7%),�saturated�(9.5%)PA12 : Tm=170�180 std.hum (0.7%),�saturated�(1.5%)PA11 : Tm=185 std.hum (1.1%),�saturated�(1.8%)PA6,6 : Tm=265 std.hum (2.5%)�saturated�(8.5%)�PA6,10 : Tm=210�220 std.hum (1.5%)�saturated�(3.2%)
PA12
30
PA6
PA6,6
PA6�:
31Gottfried�W.Ehrenstein:�Plymeric Materials,p244,2001,HANSER
ISO�527
f
Saturated : (8.0%)Std.hum : 23 50%RH (2.8%)Dry : (0.2%)
�11�PA6
3.(4) POM
80%
Homo�polymerCopolymer
32
A-73
3.(5) (PC)
200 30
(�100 125 )
33
3.(6)� m�PPE�
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.
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.
.
34
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PBT
35
3.(8) (GF�PET)
PET
220 242
36
A-74
4.(1)PS SAN PMMA PC
% 88�90 90 92�93 87�89
� 1.59 1.57 1.49 1.59
Tensile strength MPa 36�52 69�82 48�73 64�66
Tensile elongation�at�break
% 1.2�2.5 2�3 2�5 110�120
IZOD Impact�strength J/m 14�28 25�30 22�28 800�1000
RockWell hardness M65�90 M79�90 M80�100 M70
deflection�temperature�under�load
70�100 80�95 100 138�142
10�4/ 0.8 0.7 0.7 0.7
Density g/cm3 1.06 1.07 1.19 1.20
p49,,682001,3,1ASTM 37
�11
�6
4.(2)Solvent PVC 1 PVC 2 PS ABS PE PP
10%�hydrochloric�acid �
38%�hydrochloric�acid �
10%�sulfuric�acid
98%�sulfuric�acid
10%��Nitric acid
61%��Nitric acid
sodium�hydroxide�
potassium�hydroxide �
p107(1975)
PVC 1 PVC 2
38�7���� (
Solvent PVC 1 PVC 2 PS ABS PE PP
Acetone
benzene
tetrachloromethane
Chloroform
cresol
diethyl�ether
ethyl�alcohol�
tetrahydrofuran
Toluene
xylene
trichloroethylene
Gasoline
oil
4.(2)
39
4.(3)Solvent PA POM PMMA PC PTFE
10%�hydrochloric�acid
38%�hydrochloric�acid
10%�sulfuric�acid
98%�sulfuric�acid
10%��Nitric acid
61%��Nitric acid
sodium�hydroxide�
potassium�hydroxide
p107(1975)
40�8���� (
A-75
Solvent PA POM PMMA PC PTFE
Acetone
benzene
tetrachloromethane
Chloroform
cresol
diethyl�ether
ethyl�alcohol�
tetrahydrofuran
Toluene
xylene
trichloroethylene
Gasoline
oil
4.(3)
41
4.(4) –(1)
item unit PE�LD PE�HD PP PVC PS
Density g/cm3 0.91�0.925 0.941�0.965 0.90�0.91 1.38�1.55 1.06
crystalline/��amorpous
crystalinity %
Semi�crystalline40�55
Semi�crystalline60�80
Semi�crystalline60�70
amorphous amorphous
Glass transition�TempMelting point�Range
�100110
�125135
20170
80�110�
90�100�
Vicat Softening�PointHDT(1.81MPa) A�
�35
60�6550
9045
9272
9084
Tensile�modulusElasticity
Tensile���strengthstrainelognaition
MPaMPa%%
200�4008�1020>50
600�140018�308�12>50
1300�180025�408�18>50
2700�300050�604�610�50
3100�330030�55�1.5�3
Thermal Limits��ShortLongtime
80�9060�70
80�11060�80
13090
7060
9080
N.Rao/K.O7Brien�[Design�Data�for�Plastics�Engineers],p34,1998,�HANSER
Gottfried�W.Ehrenstein[Polymeric�Materials�],2001,HANSER
Tensile�tests�;ISO�527,�
42
�9� �(1),�(2)
item unit SAN ABS PMMA PETDensity g/cm3 1.08 1.03�1.07 1.15�1.19 1.33�1.40
crystalline/��amorphous
crystalinity%
amorphous amorphous amorphous Semi�crystalline30�40
Glass transition�TempMelting point�Range
95�105�
�85/95�105�
80�90�
80255
Vicat Softening�PointHDT(1.81MPa) A� 101�104
102100
85103
19080
Tensile�modulusElasticity
Tensile���strengthstrainelognaition
MPaMPa%%
3500�370065�85�2.5�5
2200�300045�652.5�315�20
3100�330060�80�2�6
2100�310055�804�7>50
Thermal Limits��ShortLongtime
9585
85�9575�85
85�9565�80
170100
4.(4) –(2)
43
item unit PA�6 PA�66 POM PC m�PPE
Density g/cm3 1.12�1.15 1.13�1.16 1.41�1.43 1.20�1.24 1.04�1.06
crystalline/��amorphous
crystalinity
%Semi�crystalline
30�40
Semi�crystalline
35�45
Semi�crystalline70�80
amorphous amorphous
Glass transition�TempMelting point�Range
78225
90265
�70170
145�
140�
Vicat Softening�PointHDT(1.81MPa) A�
18077,(63)�
200130,(70)�
165140�,(110)�
102100�(135) (128)�
Tensile�modulusElasticity
Tensile���strengthstrainelognaition
MPaMPa%%
2800/1000/60080/45/�4/25/�30/>50/�
3000/1600/80085/60/�5/20/�25/>50/�
3000�320060�758�2520� >50
2200�240055�656�7100�130
230050�553�536�45
Thermal Limits��ShortLongtime
140�16080/100
140�17080�100
110�14090�100
135100
120100
4.(5) �(1)
ASTM�method� ,p117 2004,
44�10� �(1),�(2)
Gottfried�W.Ehrenstein[Polymeric�Materials�],2001,HANSER
A-76
item unit PBT GF�PET2
PA6�GF30 2
PA66�GF33 2
PBT�GF30 2
Density g/cm3 1.30�1.32 1.55�1.70 1.35�1.42 1.33�1.34 1.48�1.53
crystalline/��amorphous
crystalinity%
Semi�crystalline40�50
Semi�crystalline
Semi�crystalline
Semi�crystalline
Semi�crystalline
Glass transition�TempMelting point�Range
45�60226 256
Vicat Softening�PointHDT(1.81MPa) A�
180(60)� 1 210�227 200�232 230�243 196�225
Tensile�modulusElasticity
Tensile���strengthstrainelognaition
MPaMPa%%
2500�280050�603.5�720�>50
9,000�9,900138�166��2.0�7.0
8,600�10,000166
2.2�3.6
7,800125�140
4�7
9,000�10,30096�131
2.0�4.0
Thermal Limits��ShortLongtime
160100
4.(5) �(2)
1 ASTM�method� ,p117 2004,2 2009,
45
A-77
1
2012.6.13/14
M2
M2�5
Module�M2�5�2
1.2.(1)(2) (PPS)(3) (PSF)(4) (PAR)(5) (LCP)(6) (PEEK)(7) (PES)(8) (PAI)(9) (PEI)(10) (PTFE)
3.(1) (PF)(2) (UF)(3) (MF)(4) (EP)(5) (UP)(6) DAP)(7) (SI)(8) (PUR)
4.(1)(2)(3)(4)
5.(1)(2)(3)(4)
6.7.(1)(2)� EVA EVOH(3)�1��2�
2
150
m�PPE
3
2.[ ]
150
120
224
4504
A-78
2.(1)
40,000 50%UL UL746B
5
at�1.82MPa
�1
PPS
LCPPESPSF
TPIPEEKPAI
at�2011.4.1
�2
2.(2)� PPS
6
�SO2�
175 160 Tg190 ,
7
2.(4)� PAR
1.21
140 175 Tg195PC
PC,PSF
8
A-79
2.(5) LCP
(
Type1 300
Type2 240
Type3:<200
9
SD(UL94V�0)�
2.(6)� PEEK�
240160
( )�
10
PEEK®�PEEK®
2.(7)� PES�
�SO2�
180 210 T 225200
PSF
11
OA
2. PAI
200
12Bushing
A-80
2.(9)� PEI1.
170 200 Tg 217
13
2.(10)� PTFE
C2F4C2H4
2.13 2.23260 325 330
0
CF2CF2 n
14
3.�[ ](1)
(2)(3)
(4)
(5)
15
3.(1) PF
(
16
A-81
3.(2)�� UF
17
3.(3)�� MF�
C N H
130
18
3.(4)�� EP�
A
A
19
3.(5)�� UP
�C=C� �COO�
FRP
FRP
130 �60
FRP UV
20
A-82
3.(6) PDAPUP
DAP
21
3.(7)�� SISi�O�Si�
. 150
�75
22
3.(8) PUR
(urethane�bond)
(Diisocyanates) (Polyol) �OH
80 100
23
4.�Elastomer)
Thermoplastic�Elastomer)
�
�
24
A-83
4.(1)
:
Hard�segment ex�.PS
25
4.(2)�
Thermoplastic�Elastomer
Pseudo�cross�linkingA�block B�block
Monomer�A Monomer�B
Fig��a��Random�copolymer
Fig��b��Block�copolymer
26
4.(3),
2
1.0
27TPE�Hardness Shire�A)Compressio
n(pe
rmanent)�strain�(%
)
Compression(permanent)�strain�(%)70 22hrsSBC:�Stylene,����������PVC:PVCTPO:Olefine,����������TPV:TPU:Urethane,� TPE:Polyester
4.(5)
28Seikei�kakou vol12,No12,200
TPO TPS TPEE TPAE TPU TPVC
:
TPE thermoplastic�elastomerTPO: thermoplastic�Olefinic elastomerTPS: thermoplastic�Styrene�elastomerTPEE: thermoplastic�Polyester�elastomer�TPAE: thermoplastic Polyamide�based�elastomerTPU: thermoplastic� Urethane�elastomerTPVC: :��thermoplastic�PVC�based�elastomer
A-84
5.Polymer�Alloy ]
m�PPE
PC ABS PC PS PBT ABS PA ABS
29
Polymer�Blend
Polymer�Alloy
p364,8�(1954)
� Polymer�Blend incompatible
compatible
miscible
5.(1)�
�a �b
AB
30
5.(2)�
A B
A B
Polymer�B
Polymer�A
p24�25,(2010) 31
5.(3)
/ABSm�PPEPPPA
ABSPBT/PETPMMALCP
PPE HIPS/PSPA
PBT PCPETPS
p40 2000932
A-85
6.
P 2009 33
PEPPPVCPETABSPA6
7.(1)
((Celluloid)
Cellulose�Acetate
34
CAB
7.(2)�EVA EVOH
EVAEVOH ethylene�vinylalcohol copolymer EVOH
1.19�1.14
EVA LDPE PVC
EVOH
EVA EVOH:
35
7.(3)
36
Material % MPa
ABS 0.4� 0.9 50 80 53.97 171.7
PS 0.4� 0.7 20 60 68.69 206.1
SAN 0.2 0.7 50 80 68.69 225.7
EVA 0.2 0.7 50 80 103 274.8
PP 1.0 2.5 20 90 68.69 137.8
PP�GF40% 0.2 0.8 20 90 68.69 137.8
HDPE 2.0 6.0 10 60 68.69 137.8
PMMA 0.1 0.4 40 90 68.69 137.8
PA6 0.5 1.5 40 120 34.34 137.8
PA66 0.8 1.5 30 90 34.34 137.8
POM 2.0 2.5 60 120 68.69 137.8
PBT GF30% 0.2 0.8 40 80 54.95 176.6
PC 0.5 0.7 80 120 68.69 137.8
PPS�GF40% 0.2 0.4 130 150 34.34 137.8
m�PPE 0.1 0.5 80 90
PET 0.2 0.4 70 100
A-86
�1�item unit PPS PSF PAR 1 LCP type
GF�30specific�gravity g/cm3 1.34 1.24�1.25 1.21 1.62
crystalline/��amorphouscrystalinity %
Semicrystalline amorphou Amorphous Semicrystalline
Glass transition�TempMelting point�Range
85�95285�290
185�190�
193280
HDT(1.81MPa) A� (110)� 1 (174)� 1 175 240
Tensile�modulus ElasticityTensile���strength
strainelongation
Bending�modulus�Elasticity
MPaMPa%%MPa
370075�85�4�53,700
2500�270070�805.5�620�>50
210070�60
210
2.215,000
Thermal Limits��ShortLongtime
260200
170150 150
Tim�A.Osswald/Georg�Menges.Materials�Science�of�Polymer�for�Engineers,p8,2003,�HANSER 37
1 ASTM�method� ,p118 2004,
2� (2009)
item unit PEEK PES PAI 1 PEI PTFE
Density g/cm3 1.32 1.37 1.38 1.27 2.14�2.20
crystalline/��amorphous
crystalinity%
Semi�crystalline�30
amorphous amorphous amorphous Semi�crystalline55�90
Glass transition�TempMelting point�Range
145335
225�230�
280�
215�230�
125�130325�330
HDT(1.81MPa) A� (168)� 1 (204)� 1 (204)� 1 (200)� 1
Tensile�modulusElasticity
Tensile���strengthstrainelongation
MPaMPa%%
37001005>50
2600�280080�905.5�6.520�80
5,0001508
2900�3000856�7>50
390�55014��30�200�400
Thermal Limits��ShortLongtime
300(240)
210180
�230
190(170)
280240
�1 �(2)
1 ASTM�method� ,p118 2004, 38
item unit PF EP 2 PUR 2 UP 3 PDAP
specific�gravity g/cm3 1.37�1.46 1.11�1.40 1.03�1.50 1.35�2.30 1.70�1.98
HDT(1.81MPa) A� 149�188 149�260 177�260 177�290
Tensile�modulus ElasticityTensile���strengthTensile���elongationBending strength
MPaMPa%MPa
5,500�11,70034�620.4�0.848�96
2,40027�893.0�6.0
70�6901�69100�10,0005�62
5,500�113,800103�2071.0�5.069�207
9,700�15,20041�763.05.062�138
Thermal Limits��ShortLongtime 150 130 130
Gottfried�W.Ehrenstein [Polymeric�Materials],�2001,�HANSER
�2�
123
39
2009 p485�
HDT:�heat�distortion�temperature,DTUL:�deflection�temperature�under�load
A-87
1
2012.6.20
M2
M2�6
Module�M2�6M5�8
1.2.(1)(2)(3) CIE�X.Y.Z(4)(5)
3.(1)(2)(3)(4)(5)(6)(7)(8)
(9)(10)(11)(12)4.(1)(2)(2) ABS(3)(4)(5)(6)(7)(8)
2
3
2.
380�780nm
�2 �3�1 4
A-88
2.(2)
hue
brightness
chroma
5
2.(3)�CIE�X.Y.Z
XYZ(R G B )
x,�y,�Z 3Y xy �4 XYZ
x y
E
� 4XYZ6
2.(4)
5Y 5PB
�5
7
2.(5)
RGB� Red,�Green,�Blue X.Y.Z x,�y
X.Y.Z x,�y
CIE CIE�XYZ
�6�
p11(1966) 8
A-89
9
3.(1)
10
3.(2)
�7
p17�(1966)
incident�light
reflected�light
scattered�light
transmitted�beam
synchrotron�radiationabsorption
refraction
11
3.(3)
pigment;�colorant
Inorganic�pigments
12
organic�coloring�matter
DyesOrganic�pigments�
A-90
3.(4)dye
anthraquinone dye
azo dye�N=N�)
oil�soluble�dyestuff
pigment
300
13
3.(5)
�8
p237�(1989) �9 14
3.(6)
PVC PVC
PVC,�PS,ABS,�PET,�Nylon
,PVC)
PE
PVC
PVC PVCPVC
15
3.(7)PVC paste�color
PVC PVC
PVC
liquid�color)
PS,ABS,PVC,PET(Nonionic�surfactant), �
16
A-91
3.(8)
p434(1989)
�10Liquid�color�system
System�1
System�2
Natural�Resin
Injection�molding�machine
Liquid�color�vessel
Metering�pump
17
3.(9)�dry�powder color
(dispersing�agent)
1�2mm
vehicle) 18
3.(10)masterbatch 5 50wt%
20
5/100 5
19
3.(11)
p440(1989)
kneader
pelletizer
Extruders cooling�pool
Banbury type�mixer�
Henshel type�mixer�
Row�materials
�11�
20
A-92
3.(12)
p442(1989)
Measures Blend Molding
ResinMaster�batch
Line
Resin
Master�Batch
Line�2 Line�3
Resin
Master�batch
the�automatic�Measuring�Instruments,Mixing
�12
21
4.(1)PVC
[ ]: ultramarine.
[ ](a) (b) (c) (d)
c>b>a>d
p36�192(1996)
22
4.(2)
PS yellowing
PS
[ ]
23
4.(3)ABSABS[ ]
ABS PS PMMA
ABS
[ ]�
24
A-93
4.(4)
[ ]
120 220 180 2300 220 300
[ ]
25
4.(5)
[ ]200 220 .
[ ]
26
4.(6)
[ ]
[ ]
27
4.(7)
[ ]
[ ]
[ ]
[ ]
28
A-94
4.(8)
[ ]
[ ]
29
4.(9)
[ ]
[ ]
30
A-95
1
2012/10/15,16
M2
M2�7
Module�M2�7
1.2.(1)PVC�(2)�PE�(LDPE)�(3)�PE�(HDPE)�(4)�PP�(5)�PS�(6)�ABS(7)�SAN�(AS)(8)�PMMA�(9)�PET�3.(1) PA�(2)�POM�(3)�PC�(4)�m�PPE�(5)�PBT�(6)�GR�PET
4.(1) PPS�(2) LCP(3) PES�(4) PAR�(5) PSF�(6) PEI�(7) PTFE�(8)�PEEK�(9)�PAI�5.(1) PF(2)MF(3)UF(4)EP(5)UP(6)SI(7)PUR(8)PDAP
2
1.�
OA,
PC/PBT
PC
EVOH
3
2.(1)PVC�
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10)
PVC
PVC
Note (1) (2) (3) (4) (5) (6) (7)(8) (9) (10)
4
A-96
2.(2)PE LDPE)�
(1) (2) (3) (4) (5) (6) (7) (8)
Note (1) (2) (3) (4) (5) (6)(7) (8)
LLDPE
5
2.(3)PE HDPE)�
(1) (2) (3) (4) (5) (6) (7)
Note (1) (2) (3) (4) (5)(6) (7)
HDPP
6
2.(4)PP�
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
,
Note (1) (2) (3) (4) (5) (6)(7) (8) (9) (10) (11)
7
2.(5)PS� (GPPS,�HIPS)
(1) (2) (3) (4) (5) (6)
CD
:����
:
Note (1) (2) (3) (4) (5) (6)
GPPS PS
8
A-97
2.(6)ABS
(1) (2) (3) (4) (5) (6) (7)
,
Note (1) (2) (3) (4) (5)(6) (7)
9
Note (1) (2) (3) (4) (5) (6)
2.(7)SAN(AS)
(1) (2) (3) (4) (5) (6)
SAN SAN
10
2.(8)PMMA�
(1) (2) (3) (4) (5) (6)
OA
Note (1) (2) (3) (4) (5) (6)
11
2.(9)PET�
(1) (2 (3) (4) (5) (6) (7) (8)
C�PET)
Note (1) (2) (3) (4) (5)(6) (7) (8)
A�petC�PET)
12
PP
A-98
3.(1)PA
(1) (2) (3) (4) (5) (6) (7)
PA66(PA66) (PA6)
PA6PA6
Note (1) (2) (3) (4)(5) (6) (7)
PA6GF30 PA6GF30 PA6,6GF,PA6,1013
3.(2)POM�
(1) (2) (3) (4) (5) (6)
OA
DVD�ROM
Note (1) (2) (3) (4) (5) (6)
14
3.(3)PC�
(1) (2) (3) (4) (5) (6) (7) (8)
CD DVD
Note (1) (2) (3) (4) (5) (6)(7) (8)
15
3.(4)m�PPE�
(1) (2) (3) (4) (5) (6) (7) (8)
LED IC
Note (1) (2) (3) (4) (5) (6) (7)(8)
16
A-99
3.(5)PBT�
(1) (2) (3) (4) (5) (6) (7)
�
OA
Note (1) (2) (3) (4) (5)(6) (7)
� PBT
17
3.(6)GR�PET
(1) (2) (3) (4) (5) (6) (7) (8)
Note (1) (2) (3) (4) (5) (6)(7) (8)
18
4.(1)PPS�
(1) (2) (3) (4) (5) (6) (7)
CD,DVD
Note (1) (2) , (3) (4) (5) (6)(7)
PPS
19
Note (1) (2) (3) (4) (5) (6)(7) (8)
4.(2)LCP
(1) (2) (3) (4) (5) (6) (7) (8)
CD
SD
20
A-100
4.(3)PES�
(1) (2) (3) (4) (5) (6) (7) (8) (9)
OAIC
Note (1) (2) (3) (4) (5) (6)(7) (8) (9)
21
4.(4)PAR�
(1) (2) (3) (4) (5) (6) (7) (8) (9)
Note (1) (2) (3) (4) (5) (6) (7)(8) (9)
22
4.(5)PSF�
(1) (2) (3) (4) (5) (6) (7) (8) (9)
�
Note (1) (2) (3) (4) (5) (6)(7) (8) (9)
23
4.(6)PEI�
(1) (2) (3) (4) (5) (6) (7) (8) (9)
Note (1) (2) (3) (4) (5)(6) (7) (8) (9)
24
A-101
4.(7)PEEK�
(1) (2) (3) (4) (5) (6) (7) (8)
ABSAT
Note (1) (2) (3) (4) (5)(6) (7) (8)
25
4.(8)PAI�
(1) (2) (3) (4) (5) (6) (7) (8)
Note (1) (2) (3) (4) (5)(6) (7) (8)
26
4.(9)PTFE�
(1) (2) (3) (4) (5) (6) (7) (8)
,
Note (1) (2) (3) (4) (5)(6) (7) (8)
27
5.(1)PF
(1) (2) (3) (4) (5) (6)
Note (1) (2) (3) (4) , (5)(6)
28p223(2011)
A-102
5.(2)MF
(1) (2) (3) (4) (5) (6) (7)
Note (1) (2) (3) (4) (5) (6)(7)
29
5.(3)UF
(1) (2) (3) (4) (5) (6) (7)
,
Note (1) (2) (3) (4) (5)(6) (7)
30
5.(4)EP
(1) (2) (3) (4) (5) (6)
,
Note (1) (2) (3) (4) (5)(6)
�II CFRP)
31
5.(5)UP
(1) (2) (3) (4) (5)
Note (1) (2) , (3) (4)(5)
FRTP
32
A-103
5.(6)SI
(1) (2) (3) (4) (5) (6)
Note (1) (2) (3) (4) (5) (6)
33
5.(7)PUR
(1) (2) (3) (4) (5) (6) (7)
RIM
Note (1) (2) (3) (4) (5)(6) (7)
34
5.(8)PDAP
(1) (2) (3) (4) (5) (6) (7)
Note (1)� (2) (3) (4) (5) (6)(7)
PDAP
35
A-104
2.�
M2�8
2012/10/172013/2/112013/6/11
1
Module�M2�81.2.(1)(2)(3)(4)(5)
3.(1)(2)
4.(1)(2)(3)(4)(5)(6)(7)(8)
5.(1)(2)(3)(4)
6.(1)(2)(3)(4)(5)
7.8.(1)(2) Tg HDT(3)(4)(5)(6) ASTM� IZOD
2
1)
2)
3)
4) JIS ASTM ISO
3
2.
1)
(1)
2)
(1)
4
A-105
2.(1)1)
1013.25hPa 4
Where��� specific��gravity
massvolume
�4� 4 DensityH2O1.000g 3
� ���������4
W1gW2gW3g
(W2 W1) (w3�w1)
2)ASTM�D792
�15
2.(2)
1)
2) :ASTM�D570,JIS�K7209,ISO�62,��A
(Wt%)
PTFE 0.00
PE <0.01
PP <0.01
(Wt%)
PVC�(rigid)PVC�(soft)
0.07�0.40.5�1.0
ABS 0.2�0.6
PS 0.01�0.03
PMMA 0.1�0.4
PC 0.15
POM�(Homo) 0.25�0.40
PA6 1.3�1.91�
6
2.(3)
1)
ESC2)
JIS�K7114 ISO�175 JIS�K�6911� JIS�K7108 ISO6252
7
2(4)
1)2)
JIS�K�7105JIS�K7105 JIS�K7142 ISO489
JIS�K7105JIS�K7105 K7136 K7361�1 ISO14782 13468�1
8
A-106
2(5)1)
2) :JIS�K7125B,�ASTM�D3985�05GTR=Vc/(R T Pv A (dp/dt)[mol/m2S Pa]JIS�K7129 (g/m2/24hr)=240�m/(t S)
�2� �39
3.1)
2)
103 107 S�1
10
3.(1)1) M.F.R
2)JIS�K7210,ISO1133,ASTM�D1238
Temperature Load g Applied
190 2160 PE,POM,PP
200 5000 ABS,PP
230 2160 PP
275 325 PA6.6
280 2160 PC
�4 POM MFR �2�M.F.R
p2011
3.(2)
1)
2)
�5 PC �6
�8 3 pin
12
A-107
4.1)
2)
3) [ ]
13
4.(1)1)
2)ASTM�D638��,JIS�K7113,ISO527,
�7 �
(1)
(2)
(3)
(4)
(5)
Note(1) (2) PMMA,�GPPS,FP(3) Rigid�PVC,SAN (4) Soft�PVC,�LDPE,PP(5) ABS,�POM,�PC
�3 Stress�Strain�Carve�Type
14
4.(2)1)
2)ASTM�D790,JIS�K7203,ISO�178
3
Load
�8��
Load
Load
R
15
4.(3)1)
Strain Stress2)
JIS�K7181 ISO�604 ASTM�D695�892
�9�� �2��
Load
Shear�stress
Stress
Strain
Yield�pointBreak�point
0.2%Stress
0.2%
16
A-108
4.(4)1)
2):
IZOD�impact� strength�test (ASTM�D2794,JIS�K7110,ISO180)Charpy�impact��strength�test�(ISO179,JIS�K7111).
�9���Izot Charpy impact�strength�test
Izot impact
Hammer
Test�specimen
Impactnotch
notch
impact
17
Charpy�impact�test Impact�Machine
4.(5)1)
PV
2)
JIS�K7218
F/W F= W=
�11
�10
�3
Load
18
4.(6)1) 1
2)JIS�K�7118 ASTM�D638�
�14
�13 S�N
1
�12 S�N
19
4.(7)1) Creep
2)JIS�K�715, ASTM�D2990
�15��� �16�
20
A-109
4.(8)1)2)
JIS�K7202�2,ISO2039�2 ASTM�D785Rockwell�hardness, ) ,
Load (N)Diameter�ofthe steel�ball
(mm)Resin
R 588.4 12.7 PE,PA,
L 588.4 6.35 PA
M 980.7 6.35 Thermosettingresin
E 980.7 3.175 PS,PMMA
�4���
�4�
�17��
21
51)
2)
M2�1 sheet#20�2722
5.(1)1)2)
JIS�K7123 DSC� ASTM�D177
The�disk�heat�flux�meter�method
� � �/�C d� � A STM�D792
TMA Thermo�mechanical�Analysis
�5�� 23
5.(2)1)
DTUL�Deflection�Temperature�Under�LoadJIS�K�7191,�ISO�75,�ASTM�D�648�
Vicat softening�temperature K7206 ISO�306Ball�pressure�temperature)
Bbrittle�temperature JIS�K7216
50
�6�
24
A-110
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Solvent PVC 1 PVC 2 PS ABS PE PP
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38%�hydrochloric�acid �
10%�sulfuric�acid
98%�sulfuric�acid
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sodium�hydroxide�
potassium�hydroxide �
p107 1975
PVC 1 PVC 2
34
8.
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benzene
tetrachloromethane
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cresol
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tetrahydrofuran
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35
8. 1
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A-113
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38
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8.(4)
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Tensile�elasticity(MPa)
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A-114
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Tensilestrength(Mpa)
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super�engineering�plastics� 1.2�1.5 200^300 5�15 70�200
high�tension�steel 7.8 1000 210 1400
aluminum 2.7 500 73 510
Note
41 42
8.(6).1�ASTM�D638�Tensile�properties�of�Plastics�test
terms unit DefinitionTensile stress MPa =W/A�0 where A0=original�cross�sectional area
W=Load
Tensile strength MPa T=Wmax/A���where A0=original�cross�sectional areaW=Load
Tensaile strain % = L/L0�����where L0�=Original�distance��between�gage�marks�L =Increment distance��between�gage�marks�=elongation
Total�strain ,at�break % �U=(LU�L0)/L0��where L0=Original�distance��between�gage�marks�LU=Distance��between�gage�marks�at�moment�of�rupture��
Modulus�of�Elasticity MPa E=S1(stress)/e1(strain)
(tangent�modulus�of�Elasticity)
43
8.(6).2�ASTM�D790�Flexure properties�of�Plastics Test
terms unit DefinitionMaximum�Fiber�Stress
MPa S=3PL/2bd2where S=stress�in�the�outer�fibers�at�midspan [Mpa]
P=Load�at�a�given�point��on�the�load�deflection�curve�[Mpa]L=support�span�[m]b=width�of�beam�tested�[m],andd=depth�of�beam�tested�[m]
Flexural�StrengthBending�Strength
MPa
Maximum�strain�in�the�outer�fibers�mm/mm�,
mm/mm
r=6Dd/L2where r=Maximum�strain�in�the�outer�fibers�mm/mm�,
D=Maximum�Deflection of�center�of�the� beam�[mm]L=support�span�[mm],andd=depth��[mm]
Modulus�of�Elasticity MPa EB=L3m/4bd3where EB=modulas of�Elasticity in�bending [Mpa]
m=slpoe of�the�tangent�to�the�initial��straight�–line��portion�of�the��load�deflection�curve�[Mpa]of�deflection
L=support�span�[m]b=width�of�beam�tested�[m],andd=depth�of�beam�tested�[m]
44
8.(6).3�ASTM�D695Compressive�properties�of�Rigid�Plastics�test�
terms unit Definition
Compressive StrengthMPa c=Wmax/A0
where�Wmax=Maximum�compressive�LoadA0=original�minimum�cross�sectional area�of�the�specimen
Compressive Yield�Strength
MPa cyield=Wmax/A0where�W= compressive�Load�carried�specimen�at�the�yield�pointA0=original�minimum�cross�sectional area�of�the�specimen
Modulus�of�Elasticity MPa Ec= (�2� �1)�/� (�2��1)where Ec=modulas of�Elasticity in�compressiving [Mpa]
m=slpoe of�the�tangent�to�the�initial��straight�–line��portion�of�the��load�deflection�curve�[Mpa]of�deflection
�=�the�compressive��stress�,measure�from�the�point�where���the�extended tangent� line�intersect�the�strain�–axis.
A-115
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8.(6).4�ASTM�D256�Impact�Resistance�of�plastics�test�
terms unit Definition
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