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    CHAPTER ONE

    1.1 INTRODUCTION

    Pollutants are substances which cause pollution. Pollution is not a new phenomenon.

    Infact, it is older than what most people realize. Archaeologist digging through site ofupper Palaeolithic settlement (settlement of the first modern humans between forty

    thousand and ten thousand years ago) routinely found piles of discarded stone tools and

    the litter form the making of these tools.

    Although pollution has been a major problem since the centuries preceding the middle

    ages, it is worth noting that the most significant land and soil pollution began during the

    20th century, when industries began manufacturing and using synthetic materials such as

    plastic, PCBs (polychlorodiphenyl tricholorethene (DDT). These materials are not only

    toxic, they also accumulate in the environment they are biodegradable thus, organicbased pollutants have the potential to disrupt hormonal systems and modify the natural

    growth of humans and animals. It alters significantly the content and diversity of

    organism in the soil.

    As the world population grows, and humans moved form nomadic to settle societies,

    however pollutants increase in magnitudes and becoming a real problem for the

    environment and it human and non-human inhabitants. The dispersal pollutant form it

    source can be through the atmosphere, via the water bodies or directly into the soil. The

    soil has in recent years been selected as a medium in which pollutant are being dispose.

    Once in the soil, not only can it enter the food chain, thereby affecting plant, animals and

    humans, but in some cases altering the composition of the soil and it ability to perform it

    many function.

    Furthermore, pollutant can often be transported from the soil to water bodies, where they

    contribute further damages to the environment. Soil pollutant is now much more under

    the spot light of government, though they are many countries that still ignore the effect of

    soil pollution.

    1.2 AIM AND OBJECTIVEThe aim of this project is to determine how quickly different liquid pollutant would travel

    through different soil types.

    1.3 SIGNIFICANCE OF STUDY

    The information gained from this experiment will benefit farmer, drilling industries,

    botanists who have soil problem to better understand absorbency in different soil types,

    as pollutant can impact soil everywhere and the effects are potentially disastrous small

    chemical change in soil can render it inhospitable to plant. Also chemical that runoff

    through soil into river and stream can contaminate drinking water.

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    1.4 SCOPE OF STUDY

    The project is limited to the use of three different types of liquid pollutant Diesel,

    Kerosene and Lubricating Oil; and three different soil types sand, loamy and clay.

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    CHAPTER TWO

    LITERATURE REVIEW

    2.1 POLLUTANT

    Pollutants are any substances that diminish the quality of the soil and change the naturalsoil equilibrium. They are ingredient causing pollution. They are not deliberately

    manufactured, but are the by product of manufacturing processes. At different stages of

    the manufacturing, these pollutants are generated (Miller, G.T. 2000). According to

    (Tietenberg, T. 2006) Pollutants can also be defined by their zones of influence, both

    horizontally and vertically.

    The horizontal zone refers to the area that is damaged by a pollutant. Local pollutants

    cause damage near the emission source while regional pollutants cause damage further

    from the emission source.The vertical zone is referred to whether the damage is ground-level or atmospheric.

    Surface pollutants cause damage by concentrations of the pollutant accumulating

    near the Earth's surface Global pollutants cause damage by concentrations in the

    atmosphere.

    2.2 POLLUTANT PATHWAY

    According to (Dr Dilip, 2004) a pollutant is released along a pathway a retraceable root

    from it source. This pathway allows migration of the pollutant to a target of vary

    sensitivity. They are different form of pollutants, each of which comes from different

    sources.

    2.3 FORM OF POLLUTANT AND ITS SOURCE.

    Different forms of pollutant have different properties for mobility, migration and impacts,

    each of this properties vary according to it source.

    They are three different forms of pollutant, which are Liquid, Solid and Gaseous

    Liquid Pollutant

    Source

    i. Spilled raw material,

    ii. Leakage form machinery and pipe workiii. Damage supply line and drains

    iv. Deliberate discharge of effluent.

    Solid Pollutant

    Source

    i. Product of waste powder, resins, granule e.t.c

    GaseousPollutant

    Source

    i. Evaporation of organic and volatile chemicals.ii. Process fume and smoke.

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    iii. Naturally occurring radioactive gases.

    2.4 LIQUID POLLUTANT

    These are substances that flow with little or no tendency to disperse, having relatively

    high incompressibility, and which cause pollution. Many liquid pollutants are produced,

    during the process of manufacturing pesticide, medicine and other chemical. They arealso released during refinement and processing (Tutorvista, 2010).

    Liquid pollutants exist in two forms: point source and non-point source. Point source

    pollutant is used to describe thing that pollute the environment directly, it can be traced

    back to a single origin or source example, pipe dumping contaminant, a sewage treatment

    plant discharge, while non-point source describe things that pollute the environment

    indirectly, it cannot be traced back to a single origin or source such as polluted runoff

    from agricultural areas draining into a river, urban runoff from a roadway, storm drain, or

    from ships at sea.There are four origins that these sources can come from, they are as follows: agricultural

    industry, manufacturing industry, municipal and nuclear wastes, each of them is

    discussed below.

    2.5 LIQUID POLLUTANT SOURCE OF ORIGIN

    i. Agricultural Industry

    Pesticides, insecticides and herbicides are commonly used in the agriculture industry to

    treat crops and protect them against the threat of insect infestation or disease. These types

    of chemical compounds may also be used on a smaller scale to treat lawns, flower beds or

    gardens. According to (Green P. 2008), the use of pesticides, insecticides and herbicides

    can cause a reduction in soil fertility, pollution of groundwater and contamination of root

    crops. Liquid fertilizers that contain nitrates, phosphorous or potassium can also lead to

    deterioration of soil quality, potential groundwater contamination and a general

    degradation of the quality of crops produced.

    ii. Manufacturing Industry

    According to (Green P. 2008), power plants, paper plants and companies operating in theiron, steel or chemical industries are responsible for creating hazardous liquid waste.

    Liquid waste produced by these entities typically enters the soil as waste-water runoff or

    through illegal or improper dumping. Heavy metals such as cadmium, lead, copper and

    zinc, chromium, mercury and arsenic are often present in industrial waste. As these

    chemicals are absorbed into the soil, they have the potentials to contaminate groundwater

    or be consumed by wildlife, which may allow the transfer of these compounds up to the

    food chain.

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    ii. Municipal waste

    The improper management and control of municipal waste can also lead to leakage of

    hazardous liquids into the soil. The primary sources of municipal waste pollutants include

    leakage from septic tanks, sewage that enters rivers, the improper disposal of motor oil,

    paint and other chemicals (NSDL, 2007).

    iii. Nuclear Waste

    Liquid nuclear waste also has the ability to contribute to soil pollution. Radioactive waste

    is typically classified according to its purpose their heat energy potential and their

    composition. Nuclear waste can remain for a few hours or a few thousand years,

    depending on its composition (EPA, 1998).

    2.6 SOIL

    Soil is a series of thin layer on the surface of the Earth on which the living beings

    survive. It is the layer of materials in which plants have their roots. Soil is made up of

    many things like weathered rock particles and decayed plant and animal matter

    (Birkeland, 1991).

    It takes a long time for soil formation and more than thousand years for the formation of

    a thin layer of soil. Since soil is made up of such diverse materials like broken down rock

    particles and organic matter, it can be classified into various types, though based on the

    size of the particles it contains.

    2.7 SOIL CLASSIFICATION

    Sand, Silt, and Clay are the three basic types of soil. Some soils are made up of the

    combination of the three to form Loamy Soil. The texture of the soil, how it looks and

    feels, depends upon the amount of each one in that particular soil (Sanchez, 2003).

    i. Sandy Soil

    This type has the biggest particles and the size of the particles thus determine the degree

    of aeration and drainage that the soil allows. It is granular and consists of rock andmineral particles that are very small. Therefore the texture is gritty and sandy soil is

    formed by the disintegration and weathering of rocks such as limestone, granite, quartz

    and shale. Sandy soil is easier to cultivate if it is rich in organic material but then it

    allows drainage more than is needed, thus resulting in over-drainage and dehydration of

    the plants in summer. It warms very fast in the spring season. So if you want to grow

    your plant in sandy soil it is imperative that you water it regularly in the summers and

    give a break in the winters and rainy season, sandy soil retains moisture and nutrients. In

    a way sandy soil is good for plants since it lets the water go off so that it does not remain

    near the roots and lead them to decay.

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    ii. Silt Soil

    Silt soil is considered to be one of the most fertile of soils. It can occur in nature as soil or

    as suspended sediment in water column of a water body on the surface of the earth. It is

    composed of minerals like Quartz and fine organic particles. It is granular like sandy soil

    but it has more nutrients than sandy soil and it also offers better drainage. In case silt soilis dry, it has a smoother texture and looks like dark sand. This type of soil can hold more

    moisture and at times becomes compact; it offers better drainage and is much easier to

    work with when it has moisture.

    iii. Clay Soil

    Clay is a kind of soil that occurs naturally and consists of very fine grained material with

    very less air spaces, which is the reason it is difficult to work with since the drainage in

    this soil is low, most of the time there is a chance of water logging and that causes harm

    to the roots of the plant. Clay soil becomes very heavy when wet and if cultivation has tobe done, organic fertilizers have to be added. Clay soil is formed after years of rock

    disintegration and weathering. It is also formed as sedimentary deposits after the rock is

    weathered, eroded and transported.

    iv. Loamy Soil

    This soil consists of sand, silt and clay. It is considered to be the perfect soil for

    Agriculture. The texture is gritty and retains water very easily, yet the drainage is well.

    There are various kinds of loamy soil ranging from fertile to very muddy and thick sod.

    Yet out of all the different kinds of soil loamy soil is the ideal for cultivation.

    Besides this kind of classification soil can also be classified as Acidic and Alkaline soil

    depending on the amount of humus, organic matter and the underlying bedrock. Every

    soil has its own advantages and disadvantages and there are various plants that have

    different requirements. All plants do not need the same kind of soil.

    2.8 CAUSES OF LIQUID POLLUTANT ON THE SOIL

    Soil pollution is a growing problem and understanding what causes it, is key to

    preventing it. Pollutants in the soil can have a negative impact on plant and animal life

    and potentially lead to contamination of groundwater. Soil pollution can be limited to

    surface soil or it can be spread to underground layers, depending on the type ofcontaminant. Hazardous liquids derived from agricultural, industrial and other activities

    represent the most type of soil pollutants (Davenport, 2005).

    Farming Chemicals

    Chemicals are widely used to protect crops from succumbing to insects, weeds and fungi,

    though these chemicals are a good short-term treatment to problems in agriculture, they

    also can create new problems that are harder to solve. Pesticides, herbicides and other

    chemical agents can contaminate the soil and deplete it of nutrients. The reduction of

    nutrients can make soils less able to yield high-quality crops of certain plants. Chemicalrunoff also can affect soil beyond the plot where crops are grown and hamper the soil for

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    Human Waste Products

    Trash from landfills and littering can decompose over time, but they also can release

    liquid chemicals that kill plants and make soil inhabitable to life forms, including plants

    and animals. Chemicals found in cosmetic products and other items, such as batteries,can linger in soil, zapping it of it nutrients. Some of this is unavoidable, but many

    products can be recycled by methods that do not damage soil to such a degree.

    Fuel By-Products

    Fuel leakages from automobiles, that gets washed away due to rain and seep into the

    nearby soil can influence the soil and be harmful to the land. The by-products from coal-

    powered plants, oil refineries and nuclear waste can put various chemical substances into

    the soil many of which can remain for years. This type of soil pollution is commonly

    found in highly industrialize areas. The pollutants produced by fuel as well as otherfactors, can contaminate the soil and also can be carried through the soil and enter into

    groundwater, which can make the water extracted from some wells undrinkable without

    treatment.

    2.9 EFFECT OF LIQUID POLLUTANT ON THE SOIL

    Different source of liquid pollutants have different effect on the nature of soil. Lets look

    into the effect caused by each of these pollutants.

    Agricultural Pollutant

    a) Synthetic fertilizers: Excessive use of nitrogenous fertilizers leads to accumulation of

    nitrates in the soil. Vegetation in nitrate rich soil may exert toxic effects on those

    consuming it. Excess use of fertilizers also destroys the microbial flora in the soil, thus

    leading to interruption of essential processes in soil, such as nitrogen fixation. Also with

    the continued accumulation of these potassium salts and nitrates in soil, the salt content in

    soil could increase and cause salinisation.

    b) Pesticides are often used to keep away pests which damage crop produce and often

    cause soil pollution as they are mostly non biodegradable. They take many years to

    degrade and remain as a toxic residue in soil. Pesticide residues in soil may be taken upby plants and cause phyto-toxicity. They may also enter aquatic environment through run

    off after rain and enter the food chain.

    Industrial and Manufacturing Pollutants

    c) Industrial effluents: liquid pollutants from tanneries, thermal power plants, paper,

    fertilizer, iron, and steel industry often end up in the soil and cause degradation of soil

    due to their toxicity.

    d) Urban wastes: wastes generated in urban living areas such as sewage sludge, hospital

    wastes, etc also are a major cause of soil pollution. These wastes tend to accumulate in

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    soil, encourage the growth of pathogenic organism and cause diseases also waste material

    like plastic tend to remain non biodegradable in soil and affect soil productivity.

    2.10 PROPERTIES OF SOIL

    According to (Brady, et al. 2003) since soils develop under a variety of conditions, thesoil in one location can be very different from the soil in another location. In order to

    understand soil, and how one soil differs from another, the chemical and physical

    properties are enumerated as followed:

    Chemical properties

    Soil chemistry is the interaction of various chemical constituents that takes place among

    soil particles and in the soil solutionthe water retained by soil. The chemical

    interactions that occur in soil are highly complex. The chemical qualities of soils

    change with time.

    Cation Exchange Capacity

    The cation exchange capacity is a measure of the capacity of the soil to hold some

    nutrients. It plays a role in soil fertility. Some plant nutrients and metals exist as

    positively charged ions, or cations, in the soil environment. Among the more common

    cations found in soils are hydrogen (H+), aluminum (Al+3), calcium (Ca+2), magnesium

    (Mg+2), and potassium (K+). Most heavy metals also exist as cations in the soil

    environment. Clay and organic matter particles are predominantly negatively charged

    (anions), and have the ability to hold cations from being leached or washed away. The

    adsorbed cations are subject to replacement by other cations in a rapid, reversible processcalled cation exchange.

    Soil pH

    Soil pH refers to the level of acidity in a soil. The pH is a measure of the number of

    hydrogen (H+) ions that are in the soil. Soil pH can be altered by ammendments.

    Increasing organic matter will decrease pH (increase acidity). Lime can be added to

    increase pH (increase alkalinity). Certain fertilizers are delivered as acidic or basic

    solutions. These will also alter soil pH.

    Salinity

    Saline soils are soils with lots of soluble salts.

    Sodic soils are saline soils with lots of Na+,

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    Soil structure is the way the soil particles are arranged into larger units called peds. A

    soil with good soil structure has many more channels, or macrospores, for the movement

    of air and water.

    Soil Colour: this ranges from gray, black, white, reds, browns, yellows and under theright conditions green. It is influenced by the content of organic matter and water.

    2.11 USES OF SOIL

    Agriculture-Soil is used in agriculture, where it serves as the primary nutrient base for

    plants; however, as demonstrated by hydroponics, it is not essential to plant growth if the

    soil-contained nutrients could be dissolved in a solution. The types of soil used in

    agriculture (among other things, such as the purported level of moisture in the soil) vary

    with respect to the species of plants that are cultivated.

    Fuel-Organic soils, especially peat, serve as a significant fuel resource

    Soil material is a critical component in the mining and construction industries.

    Soil serves as a foundation for most construction projects. Massive volumes of soil can

    be involved in surface mining, road building and dam construction. Earth sheltering is the

    architectural practice of using soil for external thermal mass against building walls.

    Food-Both animals and humans in many cultures occasionally consume soil. Some

    monkeys consume soil, together with their preferred food (tree foliage and fruits), in

    order to alleviate tannin toxicity (Setz et al 1999).

    Soils filter and purify water Rain water and pooled water from ponds, lakes and rivers

    percolate through the soil horizons and the upper rock strata; thus becoming groundwater.

    Pests (viruses) and pollutants, such as persistent organic pollutants (chlorinated

    pesticides, polychlorinated biphenyls), oils (hydrocarbons), heavy metals (lead, zinc,

    cadmium), and excess nutrients (nitrates, sulfates, phosphates) are filtered out by the soil

    (Rezaei et al 2009).

    Landfills use soil for daily cover.

    2.12 IMPORTANCE OF SOIL

    Soil is one of the environments most important resources. Soil, along with

    sunlight and water, feeds plants, houses organisms, responsible for nutrient

    cycling, affects primary productivity and influences plant community diversity.

    Soil covers large parts of the dry-land surface of the globe; without it, the earth's

    surface would be barren rock and could not support life.

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    Soil is the biologically active zone where the atmosphere, water, sunlight, and the

    earth's crust mix and interact.

    Soil is one of the planet's most active regions of energy exchange, particularly

    through the decomposition of organic materials.

    Soil is obviously the medium necessary for terrestrial plant life. And since human

    beings live on plants and animals, which in turn nourish themselves on plants, it is

    easy to see why soil is the fundamental resource of civilization. It is in fact the

    fundamental resource of terrestrial life.

    Soil is constantly changing its composition in response to changing conditions. It

    supports a host of communities of living things which are interdependent and

    survive by endlessly exchanging energy and chemical resources. Consequently,

    soil is a resource that must be conserved. In order to be conserved it must beadequately studied, understood and preserver.

    2.13 SOIL TREATMENT

    Soil treatment is the science and act of treating contaminated soil with either a stationary

    or mobile facility, designed to reduce the level of contaminants- both organic and

    inorganic in a soil (FDEP, 2008).

    The various soil treatments are discussed below:

    Solidification/Stabilization - Environmental remediation processes by which waste

    contaminants in a host medium (soil) are rendered less mobile, less soluble, chemically

    inactive, and less toxic by the addition of properly selected and mixed additives and/or

    reagents. Solidification increases the compressive strength, decreases the permeability,

    and encapsulates toxic elements while stabilization converts hazardous elements into less

    soluble, mobile or toxic forms, particularly with respect to the action of water, frost and

    lime, either alone or in combination with other materials, can be used to treat a range of

    soil types. It helps in reducing contaminant solubility or reducing the transfer of (Entact,

    2010).

    Redox (reduction/oxidation reaction) is an environmental remediation processes for

    rendering chlorinated hydrocarbons, pesticides, herbicides, and heavy metals, chemically

    inert or neutral in their affect on the surrounding environment. Reduction refers to the

    gain of electrons by a molecule, atom, or ion. Oxidation refers to the loss of electrons by

    a molecule, atom, or ion. One or the other of these transformations might be used to

    change the chemical and/or physical attributes of soil contaminants so that they are

    environmentally acceptable and can remain in-situ and support beneficial use. Redox is

    initiated by the addition or injection of chemicals, reagents, microbes, enzymes, or

    bacteria designed to interact with and permanently change the targeted contaminant(Entact, 2010).

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    Bioremediation - Bioremediation is the use of biological mechanisms to destroy,

    transform, or immobilize environmental contaminants. Bioremediation of hydrocarbons

    can be accomplished by a variety of techniques. In all cases, breakdown of hydrocarbons

    is maximized by providing the best conditions for microbial activity, requiring a properbalance of moisture, nutrients, and soil oxygen (BT Texno and Servis, 2008).

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    CHAPTER THREE

    MATERIALS AND METHODS

    3.1 MATERIALS AND EQUIPMENT USE

    The materials and equipment used are described in the table below

    S/No MATERIALS/EQUIPMENTUSED

    GRADE/MODEL

    MANUFACTURER

    1.

    Beaker 300ml Bomax

    Sibata Scientific Technology

    Ltd. Usa

    2. Measuring Cylinder 500ml Silberland Inc W. Germany

    3. Weighing Balance Lever Griffin & Georg Ltd. Uk

    4. Plastic Filter Sunplast Nigeria

    5. Lubricating Oil SAE 40 Conoil Plc. Nigeria

    6. Diesel Warri Refinary. Nigeria

    7. Kerosene Warri Refinary. Nigeria9. Stop Watch digital

    10. Water type; bore hole Source: Ground Water

    11. Soil Auger mini Gamzen Plast Pvt India

    12 Plastic Bag medium black Sunplast Nigeria

    3.2 DESCRIPTION OF SAMPLE SITE

    Ogbe Avenue is a new developing area in Effurun, Uvwie Local Government Area, Delta State. It is a

    sparsely populated area; the soil formation is composed of three types randomly distributed within the

    area.

    3.3 METHOD OF SAMPLE COLLECTIONA reasonable quantity of soil samples were collected at surface and subsurface soil of the study area and

    conveyed in a plastic bag labelled A, B and C with a masking tape.

    Sample A is a Sandy Soil collected from a building construction site; Sample B a loamy soil collected at

    a few distance from a farm land; Sample C is a clay soil collected at a depth of about 20-25cm from an

    open field under the influence of erosion.

    3.4 ANALYTICAL PROCEDURE

    PARAMETER OF INTEREST

    DETERMINATION OF SOIL POROSITY

    Soil porosity (percent pore space) is the amount of pore space in a sample of soil. Pore spaces are foundbetween soil particles and are either filled with air or liquid (water). It is important, as it defines the

    volume of liquid that can be held in a given volume of a soil.

    It is generally the pore sizes and their connectivity that determines whether a soil has high or low

    permeability- the property that allows fluid to flow through (Horgan, 1999).

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    Direct method

    This method measures the amount of water it takes to fill the soil pores (percent

    porosity).

    Apparatus: Beaker, Graduated Cylinder.

    Reagent: Water

    Material: Soil

    PROCEDURE

    1. Put each soil sample into a beaker.

    2. Measure 250ml of water using a graduated cylinder.

    3. Slowly and steadily pour the measured 250ml of water into the soil filled beaker,

    care must be taken not to stir or shake the soil in the beaker.

    4. allow the soil in the beaker to stand for several minutes, until all the water soaks

    into the very small pores5. Calculate the amount of water used to fill the soil pore space in each beaker by

    subtracting the volume of water left in the cylinder from the initial volume of the water in

    the cylinder from the initial volume of the water in the cylinder before pouring it into the

    beaker.6. Record the result and make necessary calculations.

    Measurements

    Initial volume of water used vw1 250 mlVolume of water remaining in cylinder after all soil pores

    are filled. vw2

    ml

    volume of water filling soil pores (volume of all pores) vw3= vw1 - vw2

    ml

    total volume of soil (1 cm3 = 1 ml) 150 ml

    Percentage Porosity % =

    Volume of Pores cm 3 x 100

    Total Volume of the soil cm

    3.4 Determination of absorption of some liquid pollutant in soil

    Apparatus: Beaker, Measuring Cylinder, Plastic filter, Stop watch

    Material: Soil clay, loamy and Sandy, Some liquid pollutants

    Procedure

    1. Create a clean and organized are near a working sink in the laboratory.

    2. Place a beaker on top of a horizontal table and then place a plastic filter on top thebeaker, so that it remain firm.

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    3. Weigh 250g of soil sample A using weighing balance and carefully put it into the

    filter.

    4. Measure 250ml of Kerosene using a graduated cylinder.

    5. Slowly and steadily pour the measured 250ml of kerosene into soil sample A

    6. Immediately the kerosene is completely out of the graduated cylinder, begin timingfor 60 seconds.

    7. Stop the counting of the stop watch at the exact timing of 5minutes, measure and

    record the amount of kerosene that passes through the soil sample A

    8. The result, of the amount of kerosene absorb by the soil sample A, is calculated by

    taking the difference between the initial amount of the kerosene that is pour into

    soil sample A and the amount of the kerosene that passes through it.

    FormulaAmount of pollutant absorb by sample =Initial amount of pollutant amount of pollutant that passes through sample.

    9. Remove the plastic filter from the beaker, set it in the sink and wash both the

    plastic filter and beaker. Immediately clean up any spill found.

    10. Repeat step 1-9 with the same pollutant and soil sample B and C

    11. Repeat step 1-9 with diesel and soil sample A, B and C

    12. Repeat step 1-9 with lubricating soil and soil sample A, B and C.

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    Table 4

    Soil Sample C

    Pollutants

    initial amount of

    pollutant used(ml)

    amount of

    pollutant absorbby soil (ml)

    amount of pollutant that

    passes through soil (ml)

    Kerosene 250 146 54

    Diesel 250 150 50

    Lubricating oil 250 250 0

    0

    50

    100

    150

    200

    250

    Soil Sample A Soil Sample B Soil Sample C

    Kerosene

    Diesel

    Lubricating Oil

    A graph of pollutant against different Soil Sample Types

    Key

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    0

    5

    10

    15

    20

    25

    Different Soil Sample Types

    Soil Sample A

    Soil Sample B

    Soil Sample C

    A graph of percentage porosity against different soil sample types

    Key

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    4.2 DISCUSSION OF RESULTS

    Soil Sample AI found out that, the three pollutants used, travelled through it at a faster rate. It absorbs

    100ml of kerosene, 102ml of diesel and 175ml of lubricating oil. It has high percentage

    porosity than the rest of the other soil sample, which is gotten as 23%.

    Soil Sample B

    I found out that, the three pollutants travel through the soil, but not as fast as in soil

    sample A during the period of timing. The lubricating oil flows slowly, making it to bethe least to travel through the soil and the most absorbent. It absorbs 100ml of kerosene,

    110ml of diesel and 170ml of lubricating oil. It percentage porosity is 16%.

    Soil Sample C

    It took more timing for the pollutants kerosene and diesel to run through it. The

    lubricating oil was able to absorb, but did not travel through, during the period of timing.

    It percentage porosity is 3%. Making it, to have less air space than the rest of the other

    soil. It absorbs 120ml of kerosene, 127ml of diesel and 70ml of lubricating oil.

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    CHAPTER FIVE

    CONCLUSION AND RECOMMENDATIONS

    5.1 CONCLUSION

    Looking at the experiment carried out and with the consequent result obtained from it, itcan then be concluded that soil with less porosity and pollutant with more viscosity

    would be most absorbent.

    The continue disposal of pollutant into soil will result in depletion of the soil nutrient,

    which give rise to infertility of the soil and consequence, environmental degradation.

    5.2 RECOMMENDATIONS

    Having seen how far liquid pollutant can travel through soil and its negative impact on it.I like to recommend the following as ways to reduce such problems.

    1. A rapid oil spill response mechanism should be put in place by the government and

    oil companies, which must be committed to responding to distress call due to oil spillage.

    2. Developing of waste management procedures that properly treat waste product

    industrial wastes can be treated physically, chemically and biologically until they are less

    hazardous. Acidic and alkaline waste should first be neutralized. Then, the insoluble

    material of biodegradable should be allowed to degrade under controlled condition before

    being disposed.

    3. Reducing of chemical fertilizer and pesticide use - applying bio-fertilizers and

    manures can reduce chemical fertilizer and pesticide use. Biological methods of pest

    control can also reduce the use of pesticides and thereby minimize soil pollution.

    4. An insurance found against oil pollution be established by the government and oil

    companies. In this fund, all the socio-economic cost resulting from oil pollution can be

    charged and insured against.

    5. Special location should be selected for dumping of wastes product - as a last resort,

    new areas for storage of hazardous waste should be introduced such as deep well

    injection and more secure landfills. Burying the waste in locations situated away from

    residential areas is the simplest and most widely used technique of waste management.

    Environmental and aesthetic considerations must be taken into consideration before

    selecting the dumping sites.

    6. Excavating polluted soil for treatment or proper disposal, to curb it from spreadinginto different unaffected areas.

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    7. Government agencies, multinational companies, local authorities and communities

    should as a matter of utmost importance create pollution awareness programmes.

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