154437

Upload: james-paul

Post on 07-Apr-2018

217 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/4/2019 154437

    1/3

    HANSON PACKED PRODUCTS

    Health and Safety Data Sheet

    Silica Sands1. Description

    Silica Sand is an odourless, lime free, buff coloured

    washed sand. This data sheet applies to the following

    products:

    Playpit Sand Silver Sand

    Horticultural Silver Sand Kiln Dried Sand

    2. Supplier/Manufacturer

    Hanson Building Products

    Clifton House

    Butlers Leap

    RugbyCV21 3RQ

    Telephone: 08706 097095

    Facsimile: 01788 513590

    3. Composition/Information on Ingredients

    Predominantly silica with traces of many oxides such as

    alumina, potassium, sodium, chromium, titanium.

    Silica sand is used as a raw material for glass making

    and has many specialised industrial uses such as sand

    foundering, ceramic manufacture, as well as

    horticultural and play areas.

    3.1 Silica sand is subject to a recognised exposure limit.(see Exposure Controls, Section 9)

    3.2 There is currently no requirement under CHIP to

    label this product.

    3.3 Risk phrases appropriate to dust hazard - CAN BE

    HARMFUL BY INHALATION.

    POSSIBILITY OF SERIOUS DAMAGE TO HEALTH

    BY PROLONGED EXPOSURE THROUGH

    INHALATION.

    4. Hazard Identification

    Main Hazards. Not classified as hazardous unless dust is

    generated and released into the air. The dust will contain

    some respirable free crystalline silica that may be

    inhaled and remain lodged in the alveoli areas of the

    lungs. The long term effect of prolonged exposure can

    be silicosis.

    Eye Contact. Dust will cause irritation and discomfort

    by abrasion, as with grit in eye.

    Skin Contact. Prolonged or repeated contact may cause

    dryness and abrade the skin.

    5. First Aid Measures

    Eye Contact. Immediately irrigate with plenty of cleanwater to clear particles from the eye. Obtain medical

    assistance if discomfort persists.

    Skin Contact. Wash thoroughly with soap and

    water.

    Ingestion. Rinse out any particles from the mouth,

    give patient water to drink.

    Inhalation. Remove to fresh air.

    6. Fire Fighting Measures

    The product itself does not present a combustion

    risk.

    Extinguisher Type: General purpose for any

    packaging or pallets used for storage.

    7. Accidental Release Measures

    Personal Precautions. Wear respiratory protection

    where dust occurs (see Section 9).

    Environmental Precautions. There are no known

    environmental hazards, other than any significant

    release screening out light or air from plants or wild

    life.

    Methods for Cleaning. If practicable, spillages

    should be cleaned up using a vacuum system fitted

    with a HEPA (High Efficiency Particulate Air)

    Filter. Minimise generation of airborne dust by

    damping down. DO NOT DRY SWEEP.

    8. Handling and Storage

    Handling. Where possible use appropriate

    engineering controls and work practices to

    minimise dust generation.

    Where dust occurs use suitable respiratory

    protection.

    When handling bagged material, due regard should

    be paid to the risks outlined in the Manual

    Handling Operations Regulations 1992.

    Storage. Bulk dried product should be stored in

    silos and kept dry.

    Bagged product should be stored in a safe and

    stable manner in a dry place, away from heat thatmay damage packaging.

    Shelf Life. The shelf life of the product is unlimited

    if stored under the correct conditions.

    9. Exposure Controls/Personal Protection

    The EH40/98 Maximum Exposure Limit (MEL) for

    respirable crystalline silica 0.3mgm-3 (8 hour time

    weighted average TWA).

    Free silica containing respirable dusts, should also

    meet the 4mgm-3 Occupational Exposure Standard

    (OES) and 10mgm-3 for total inhalable dust.

    Engineering Measures - Dust control.Wherereasonably practicable, dust exposures should be

    15. Transport Information

  • 8/4/2019 154437

    2/3

    controlled by engineering methods or local exhaust

    ventilation (LEV).

    Personal Protective Equipment (PPE).

    Respiratory Protection - Where dust occurs, a suitable

    respirator should be worn.

    Hand Protection - Gloves are recommended for

    workers who suffer fromsensitive skin or dermatitis.

    Skin Protection - Overalls and safety footwear

    recommended.

    Eye Protection - Safety glasses or goggles are

    recommended in windy

    conditions or when the product

    is likely to enter the eye.

    10. Physical and Chemical Properties

    Appearance: Buff coloured grains.

    Odour: Odourless.

    pH: Neutral

    Boiling point/range: 22300C

    Melting point/range: 16100C

    Flash point (C): Not applicable (not flammable)

    Flammability (gas/solid): Not applicable (not

    flammable)

    Autoflammability: Not applicable

    Explosive properties: Not applicable (not explosive)

    Oxidising properties: Not applicable

    Vapour pressure: Not applicable

    Relative density: 2.65

    Solubility: Negligible in water.

    11. Stability and ReactivityThe product is stable under normal conditions.

    12. Toxicological Information

    Chronic effects (respirable crystalline silica)

    Long term exposure to respirable free crystalline silica

    can lead to the development of Silicosis. This involves

    changes to the innermost parts of the lungs and can lead

    to breathing difficulties and in some cases may be fatal.

    13. Ecological Information

    Possible effects: There is no known evidence that this

    product is harmful to the environment.

    Behaviour: Sand is subject to mobility in windyconditions, causing accumulative build-up.

    Environmental fate: Resistant to biodegradation.

    14. Disposal Considerations

    Dispose of in accordance with local regulations to

    approved landfill sites.

    Any introduction of substances or contaminants are

    outside the control of the vendor and must be disposed

    of appropriately.

    No special labelling or transport classification

    identified.

    16. Regulatory Information

    Not classified for labelling information.

    Recommended Risk phrase 20: Harmful by

    inhalation.Recommended Safety phrase 22: Do not breathe

    dust.

    17. Legislation and Other Information

    Training advice: People handling the product

    should be informed of the presence of crystalline

    silica and trained in its proper use and handling.

    Use restrictions:Silica sand should NOT be used

    for dry sand blasting.

    Further information: CAS No. 14808-60-7

    Health & Safety at Work Act 1974.

    Management of Health & Safety at Work

    Regulations 1992.

    Reporting of Injuries, Diseases and Dangerous

    Occurrences Regulations 1995.

    Control of Substances Hazardous to Health

    Regulations 1994.

    Chemicals (Hazard Identification and Packaging

    for Supply) Regulations 1994.

    HSE Guidance Note EH40 Occupational Exposure

    Limits (updated annually).

    HSE Guidance Note EH59 Crystalline silica.

    Health and Safety (First Aid) Regulations 1981.Manual Handling Operations Regulations 1992.

    Personal Protective Equipment at Work

    Regulations 1992.

    Environmental Protection Act 1990.

    This list is not exhaustive. The information

    contained in this Safety Data Sheet is, to the best of

    our knowledge, accurate and reliable.

    No guarantees can be made regarding accuracy or

    completeness and no liability can be accepted in

    respect of the use of our product in conjunction

    with other materials. This Safety Data Sheet is

    provided for the purpose of protecting the healthand safety of industrial and commercial users who

    are deemed capable of understanding and acting on

    the information provided.

    Please ensure that this Safety Data Sheet is passed

    to the appropriate responsible person(s) in your

    company, who are capable of acting on the

    information.

  • 8/4/2019 154437

    3/3