高分子学报...《高分子学报》编辑委员会顾问：曹镛程正迪蹇锡高...

高分子学报 2020 年 7 月

第 51 卷第 7 期

(GAOFENZI XUEBAO)

目次

研究亮点评述

“因材施教”式的可控逐步聚合新策略 ····················································································· 刘冬生 (679)

快报

一种新型含硅氧烷间隔基元的半芳香族共聚酰胺 ············ 龙家伟史小慧刘博文卢鹏陈力王玉忠 (681)

专论

巨型分子的黏弹性研究进展 ········································································ 罗锦添欧阳希凯刘庚鑫 (687)

力学功能蛋白生物合成及材料应用 ·········································· 刘凯李敬敬马俊柳柏梅马超 (698)

综述

用于锂二次电池的类三明治结构电解质的研究进展与展望 ······································································

························································· 刘亭亭张建军于喆吴瀚张津宁唐犇崔光磊 (710)

基于DNA纳米结构的分子间相互作用研究 ································ 李浩郝亚亚王飞王丽华刘刚 (728)

论文

基于Ugi多组分反应的赖氨酸与糠醛的直接聚合 ····································· 陶月陈金龙王士学陶友华 (738)

α-烯烃基甲基二氯硅烷调控丙烯多相共聚制备高熔体强度高抗冲聚丙烯 ····················································

····································································· 张志箭王莉祖凤华洪柳婷秦亚伟董金勇 (744)

聚乙二醇生物相容性与结合水关系的单分子力谱研究 ············································································

····································································· 许俊曹楠普肖尧鑫罗仲龙鲍雨崔树勋 (754)

高灵敏度二维光子晶体水凝胶Cu2+传感器 ···························································································

············································· 刘晨辉刘根起任宸锐史红凯薛珂曹云雷李欢欢刘建勋 (762)

含“Si―H”基团聚乙烯的合成及功能化研究 ········································ 林秀崇王胤然姜磊郭方 (771)

Acta Polymerica Sinica Vol. 51 No. 7 July 2020

Contents

Research Highlights

“Size-selective” Step-growth Polymerization ········································································ Dong-sheng Liu (679)

Rapid Communications

Semi-aromatic Polyamides Containing Siloxane Unit toward High Performance ··················································

················································· Jia-wei Long, Xiao-hui Shi, Bo-wen Liu, Peng Lu, Li Chen, Yu-zhong Wang (681)

Feature Articles

Progress in the Viscoelasticity Study of Giant Molecules ·························· Jin-tian Luo, Xi-kai Ouyang, Geng-xin Liu (687)

Biological Synthesis of Structural Proteins and Applications ········· Kai Liu, Jing-jing Li, Jun Ma, Bai-mei Liu, Chao Ma (698)

Reviews

Research Progress and Perspectives of Sandwich-structured Electrolytes for Rechargeable Lithium Batteries ················

······························· Ting-ting Liu, Jian-jun Zhang, Zhe Yu, Han Wu, Jin-ning Zhang, Ben Tang, Guang-lei Cui (710)

DNA Nanostructures in the Study of Molecular Interactions ········ Hao Li, Ya-ya Hao, Fei Wang, Li-hua Wang, Gang Liu (728)

Articles

Direct Polymerization of Lysine and Furfural via Ugi Reaction········ Yue Tao, Jin-long Chen, Shi-xue Wang, You-hua Tao (738)

Preparation of High-melt-strength, High-impact-strength Polypropylene by α-Alkenylmethyldichlorosilane-mediated

Heterophasic Copolymerization of Propylene ····················································································

········································ Zhi-jian Zhang, Li Wang, Feng-hua Zu, Liu-ting Hong, Ya-wei Qin, Jin-yong Dong (744)

Revealing the Relationship between the Biocompatibility and the Bound Water of Poly(ethylene glycol) by Single-

molecule Force Spectroscopy ·············· Jun Xu, Nan-pu Cao, Yao-xin Xiao, Zhong-long Luo, Yu Bao, Shu-xun Cui (754)

Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu2+ Sensor ························································

········· Chen-hui Liu, Gen-qi Liu, Chen-rui Ren, Hong-kai Shi, Ke Xue, Yun-lei Cao, Huan-huan Li, Jian-xun Liu (762)

Synthesis of“Si―H”Containing Polyethylene and Its Functionalization ·························································

············································································· Xiu-chong Lin, Yin-ran Wang, Lei Jiang, Fang Guo (771)

《高分子学报》编辑委员会

顾问：曹镛程正迪蹇锡高李永舫王佛松吴奇杨玉良

张俐娜周其凤

主编：张希

副主编：(以下以姓氏汉语拼音为序)

胡文兵黄飞李子臣(常务) 刘冬生宛新华王笃金王献红

委员：薄志山陈尔强陈国颂陈红陈全陈学思陈永明

董侠杜建忠傅强甘志华胡晓黄飞鹤黄维

江东林蒋锡群李光宪李宏斌李悦生李志波林嘉平

刘明杰刘世勇吕小兵马於光牛嘉乔金樑史林启

孙俊奇唐本忠唐传兵王健君王利祥王玉忠解孝林

徐志康杨柏杨万泰杨小牛杨振忠尤为余龙

张军张先正章明秋赵江赵彤郑强周永丰

朱美芳祝磊

编辑部主任：黄英娟

编辑部成员：郭舒月孟令艳孙一依赵华郑佳之

GAOFENZI XUEBAO （月刊，1957 年创刊）

第 51 卷第 7 期 2020 年 7 月 20 日

ACTA POLYMERICA SINICA (Monthly, Started in 1957)

Vol. 51 No. 7 July 20, 2020

编辑《高分子学报》编委会 Edited by Editorial Board of Acta Polymerica Sinica 地址：北京市海淀区中关村北一街 2 号 Add: Zhongguancun North First Street 2, 邮政编码：100190 Beijing 100190, China 电话：010-62588927 Tel: 010-62588927 http://www.gfzxb.org http://www.gfzxb.org E-mail: [email protected] E-mail: [email protected]

主编张希 Editor-in-Chief Xi Zhang 主管中国科学院 Administrated by Chinese Academy of Sciences 主办中国科学院化学研究所 Sponsored by Institute of Chemistry

中国化学会 Chinese Academy of Sciences Chinese Chemical Society

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i

Acta Polymerica Sinica Vol. 51 No. 7 July 2020 Cover Image

Biological Synthesis of Structural Proteins and Applications Kai Liu, Jing-jing Li, Jun Ma, Bai-mei Liu, Chao Ma

In this review, we summarized recent progress in the design and biosynthesis of artificial proteins based on spidroins and non-spider sequences.

The structures, compositions, mechanical modulation, and applications of protein-based fibers and adhesives were discussed. The

achievements in structural proteins driven by synthetic biology certainly will accelerate translational applications of the protein-based

mechanomaterials. Finally, perspectives and challenges of protein-based biomaterials were provided.

Acta Polymerica Sinica, 2020, 51(7), 698− 709

doi: 10.11777/j.issn1000-3304.2020.20074

Acta Polymerica Sinica Vol. 51 No. 7 July 2020 Contents

Research Highlights

“Size-selective” Step-growth Polymerization Dong-sheng Liu

By confining the polymerization in nano-sized reactors, Prof. Hu and coworkers from East China University of Science and Technology

demonstrated a novel strategy to control molecular weights with a narrow polydispersity.

Acta Polymerica Sinica, 2020, 51(7), 679 − 680

doi: 10.11777/j.issn1000-3304. 2020.20113

Vol. 51, No. 7 ACTA POLYMERICA SINICA 2020

ii

Rapid Communications

Semi-aromatic Polyamides Containing Siloxane Unit toward High Performance Jia-wei Long, Xiao-hui Shi, Bo-wen Liu, Peng Lu, Li Chen, Yu-zhong Wang

A novel kind of silicon-containing semi-aromatic polyamides were designed and prepared through the aromatic nucleophilic substitution

polycondensation. The introduction of siloxane units into polyamides not only significantly reduced the water absorption, but also greatly improved

the flame retardancy and maintained the excellent mechanical properties.


doi: 10.11777/j.issn1000-3304.2020.20125 Feature Articles

Progress in the Viscoelasticity Study of Giant Molecules Jin-tian Luo, Xi-kai Ouyang, Geng-xin Liu

We review the background and progress on the linear rheology of 3-dimensional giant molecules. They represent soft-cluster, a new kind of 3D

polymers. The critical diameter can be associated with glassy dynamics, thus we claim the existence of cooperative glass.


doi: 10.11777/j.issn1000-3304.2020.20056


iii

Biological Synthesis of Structural Proteins and Applications Kai Liu, Jing-jing Li, Jun Ma, Bai-mei Liu, Chao Ma

In this review, we outline the developments and challenges in the design

and synthesis of protein-based structural biomaterials. The structure,

composition, mechanical modulation, and applications are discussed.


doi: 10.11777/j.issn1000-3304.2020.20074

Reviews

Research Progress and Perspectives of Sandwich-structured Electrolytes for Rechargeable Lithium Batteries Ting-ting Liu, Jian-jun Zhang, Zhe Yu, Han Wu, Jin-ning Zhang, Ben Tang, Guang-lei Cui

Sandwich-structured electrolytes have proven to improve the comprehensive performance of high-

voltage lithium batteries, solid-state lithium batteries, lithium metal batteries and high-energy

lithium-sulfur batteries. Those advantages make it a promising application prospect.


doi: 10.11777/j.issn1000-3304.2019.19196

DNA Nanostructures in the Study of Molecular Interactions Hao Li, Ya-ya Hao, Fei Wang, Li-hua Wang, Gang Liu

The construction of DNA nanostructures as observing platforms and the applications of DNA nanostructures in the study of molecular interactions

are reviewed. The development of DNA nanotechnology in this field is summarized and prospected.


doi: 10.11777/j.issn1000-3304.2020.20055


iv

Articles

Direct Polymerization of Lysine and Furfural via Ugi Reaction Yue Tao, Jin-long Chen, Shi-xue Wang, You-hua Tao

Lysine and furfural are naturally available renewable resources, but their simple and

general polymerization still remains a key challenge. Herein, we demonstrate that

natural lysine and furfural monomers can be polymerized via Ugi reaction in a step-

growth fashion under mild conditions.

Acta Polymerica Sinica, 2020, 51(7), 738 −743

doi: 10.11777/j.issn1000-3304.2020.20025

Preparation of High-melt-strength, High-impact-strength Polypropylene by α-Alkenylmethyldichlorosilane-mediated Heterophasic Copolymerization of Propylene Zhi-jian Zhang, Li Wang, Feng-hua Zu, Liu-ting Hong, Ya-wei Qin, Jin-yong Dong

An α-alkenylmethyldichlorosilane was used to mediate heterophasic copolymerization of propylene, which synthesized PP impact copolymers

with long chain-branched structure and phase-separated morphology. The strategy provides a solution to simultaneously improve the melt strength

and impact resistance of PP, two notorious drawbacks undercutting PP as an important thermoplastic polymer.

Acta Polymerica Sinica, 2020, 51(7), 744− 753

doi: 10.11777/j.issn1000-3304.2020.20017

Revealing the Relationship between the Biocompatibility and the Bound Water of Poly(ethylene glycol) by Single-molecule Force Spectroscopy Jun Xu, Nan-pu Cao, Yao-xin Xiao, Zhong-long Luo, Yu Bao, Shu-xun Cui

The marked deviation between the F-E curves of PEG obtained in PBS and

nonane can be assigned to the bound water rearrangement of PEG in aqueous

solution. This additional energy cost (Ew) is ~1.59 kBT/unit (3.93 kJ/mol), which

is closed to those of biomacromolecules. It may be an important factor for the

excellent biocompatibility of PEG.


doi: 10.11777/j.issn1000-3304.2019.19219


v

Highly Sensitive Two-dimensional Photonic Crystal Hydrogel Cu2+ Sensor Chen-hui Liu, Gen-qi Liu, Chen-rui Ren, Hong-kai Shi, Ke Xue, Yun-lei Cao, Huan-huan Li, Jian-xun Liu

The PVA-SH 2DPCH prepared by our group can respond to Cu2+ with high sensitivity. It shows the adsorption equilibrium in Cu2+ solution with

different concentrations. It can be seen that the structural color of PVA-SH 2DPCH changes from orange red to blue green and then to blue, with

the increase of Cu2+ concentration.


doi: 10.11777/j.issn1000-3304.2020.20030

Synthesis of“Si―H”Containing Polyethylene and Its Functionalization Xiu-chong Lin, Yin-ran Wang, Lei Jiang, Fang Guo

The copolymerization of ethylene and 10-dimethylsilyl-1-decene (Decene-SiH) by (C5Me4SiMe3)Sc(CH2SiMe3)2(THF) has been successfully

achieved to afford ethylene/Decene-SiH copolymers with controllable compositions, high molecular weight and narrow molecular weight

distribution. By efficiently transforming the “Si―H” groups of the resulting copolymers into other polar groups, versatile functionalized

polyethylene with hydrophilic properties were obtained.


doi: 10.11777/j.issn1000-3304.2020.20023

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